Deactivation of metal catalysts in liquid phase organic reactions

The paper gives a general survey of the factors contributing to the deactivation of metal catalysts employed in liquid phase reactions for the synthesis of fine or intermediate chemicals. The main causes of catalyst deactivation are particle sintering, metal and support leaching, deposition of inactive metal layers or polymeric species, and poisoning by strongly adsorbed species. Weakly adsorbed species, poisons at low surface coverage and solvents, may act as selectivity promoters or modifiers. Three examples of long term stability studies carried out in trickle-bed reactor (glucose to sorbitol hydrogenation on Ru/C catalysts, hydroxypropanal to 1,3-propanediol hydrogenation on Ru/TiO₂ catalysts, and wet air oxidation of paper pulp effluents on Ru/TiO₂) are discussed.     

Fiber-optic array algebraic processing architectures

A high-accuracy fiber-optic array processor (FOAP) based on the algorithm of digital multiplication by analog convolution is proposed. The FOAP architecture is a local regularly interconnected processor that utilizes an array of identical all-optical elemental-processing lattice units, namely, an optical splitter, an optical combiner, and a binary programmable fiber-optic transversal filter. Various FOAP matrix multipliers are proposed for nonnegative and twos-complement binary arithmetic matrix-vector, matrix-matrix, triple-matrix, and high-order matrix operations. The overall performances of the FOAP matrix multipliers are compared with the time-integrating and space-integrating architectures and with the digital multipliers. Extension of the digital-multiplication-by-analog-convolution algorithm is also considered.     

A network approach to the French system of legal codes—part I: analysis of a dense network

We explore one aspect of the structure of a codified legal system at the national level using a new type of representation to understand the strong or weak dependencies between the various fields of law. In Part I of this study, we analyze the graph associated with the network in which each French legal code is a vertex and an edge is produced between two vertices when a code cites another code at least one time. We show that this network distinguishes from many other real networks from a high density, giving it a particular structure that we call concentrated world and that differentiates a national legal system (as considered with a resolution at the code level) from small-world graphs identified in many social networks. Our analysis then shows that a few communities (groups of highly wired vertices) of codes covering large domains of regulation are structuring the whole system. Indeed we mainly find a central group of influent codes, a group of codes related to social issues and a group of codes dealing with territories and natural resources. The study of this codified legal system is also of interest in the field of the analysis of real networks. In particular we examine the impact of the high density on the structural characteristics of the graph and on the ways communities are searched for. Finally we provide an original visualization of this graph on an hemicyle-like plot, this representation being based on a statistical reduction of dissimilarity measures between vertices. In Part II (a following paper) we show how the consideration of the weights attributed to each edge in the network in proportion to the number of citations between two vertices (codes) allows deepening the analysis of the French legal system.     

A modular system for global and local abnormal event detection and categorization in videos

This paper presents a modular system for both abnormal event detection and categorization in videos. Complementary normalcy models are built both globally at the image level and locally within pixels blocks. Three features are analyzed: (1) spatio-temporal evolution of binary motion where foreground pixels are detected using an enhanced background subtraction method that keeps track of temporarily static pixels; (2) optical flow, using a robust pyramidal KLT technique; and (3) motion temporal derivatives. At the local level, a normalcy MOG model is built for each block and for each flow feature and is made more compact using PCA. Then, the activity is analyzed qualitatively using a set of compact hybrid histograms embedding both optical flow orientation (or temporal gradient orientation) and foreground statistics. A compact binary signature of maximal size 13 bits is extracted from these different features for event characterization. The performance of the system is illustrated on different datasets of videos recorded on static cameras. The experiments show that the anomalies are well detected even if the method is not dedicated to one of the addressed scenarios.     

一种改进的GA变异算子及其数学分析

提出了一种改进的GA变异算子,并对其有效性作了数学分析。实例表明,该算子能改善GA的收敛性能。     

Rayonnement en ondes métriques et décimétriques des orages

This article presents the result of the current knowledge on the very high frequency electromagnetic radiation of lightning. A phenomenology analysis of the new results obtained from the study of triggered lightning in New Mexico (TRIP 82) and at Saint-Privat-d’ Allier in Haute-Loire, France (1983) is first described. The authors then present the spectral and temporal characteristics of the VHF/UHF radiation which can be applied to the electromagnetic compatibility of systems. From a synthesis of the experimental and theoretical contributions, they propose a reflection on the lightning initiation process and on the mechanisms generating lightning radiation.     

Vehicle routing concepts in the closed-loop container network of ARN—a case study

In this paper we discuss a real-life case study to optimize the logistics network for the collection of containers from end-of-life vehicle dismantlers in the Netherlands. Advanced planning concepts, such as dynamic assignment of dismantlers to logistic service providers, are analyzed using a simulation model. Based on this model, we periodically solve a vehicle routing problem to gain insight into the long-term performance of the system. The vehicle routing problem considered is a multi-depot pickup and delivery problem with alternative delivery locations. A special characteristic of the problem is the limited vehicle capacity of two containers. We solve this problem with a heuristic based on route generation and set partitioning.     

Maintenance of Response Readiness in Patients With Parkinson's Disease: Evidence From a Simple Reaction Time Task.

The authors explored the effect of Parkinson's disease (PD) on the generation and maintenance of response readiness in a simple reaction time task. They compared performance of idiopathic PD patients without dementia, age-matched controls, and younger controls over short (1-, 3-, and 6-s) and long (12- and 18-s) foreperiod intervals. After each trial, the authors probed memory for visual information that also had to be maintained during the trial interval. Patients and controls did not differ overall in their ability to maintain readiness over long delays. However, within the PD group only, errors in maintaining visual information were correlated with difficulty in maintaining readiness, suggesting that systems impaired in PD may facilitate the maintenance of processing in both motor and cognitive domains. (PsycINFO Database Record (c) 2010 APA, all rights reserved)