用尿素作为基本成分的无吡啶卡尔—费休试剂

<正>本文提出的尿素、二氧化硫和水扬酸钠的甲醇液作卡尔—费休的滴定溶剂,用碘溶液作滴定剂,这对于含胺样品的测定来说,这种溶剂的性能较之某些商业卡尔—费休试剂有更明显的优点。 自从Verhoef和Barendrecht阐明了卡尔—费休滴定的反应机理以后,人们提出了许多化合物如醋酸钠,二乙醇胺和眯唑,来取代经典的卡尔—费休试剂中的吡啶。这些化合物像吡啶一样,对滴定介质的PH起     

Meeting approval

Each of the five conference centers featured here displays the best its parent organization has to offer. Take a tour through Herman Miller, Inc.'s Marigold Lodge; UCLA Conference Center/Bruin Woods Family Resort, S.C. Johnson & Son, Inc.'s The Council House; Aetna Institute for Corporate Education; & Eastwood (Medical Center) Conference Center & discover conference dining's multifaceted mission.     

A new technique to study transient conductivity under pulsed monochromatic light in Cr-doped GaAs using acoustoelectric voltage measurement

The transient conductivity of high-resistivity, Bridgman grown, Cr-doped GaAs under pulsed monochromatic light is monitored using transverse acoustoelectric voltage (TAV) at 83 K. Keeping the photon flux constant, the height and transient time constant at the TAV are used to calculate the energy dependence of the trap density and its cross section, respectively. Two prominent trap profiles with peak trap densities of approximately 10(17) cm(-3) eV(-1 ) near the valence and the conduction bands are detected. These traps have very small capture cross sections in the range of 10(-23 )-10(-21 )cm(2). A phenomenon similar to the persistent photoconductivity with transient time constants in excess of a few seconds (in some cases, a few hundred seconds) in high-resistivity GaAs at T=83 K is also detected using this technique. These long relaxation times are readily explained by the spatial separation of the photo-excited electron-hole pairs and the small capture cross section and large density of trap distribution near the conduction band. The technique is nondestructive and, because of the dependence of the polarity of the acoustoelectric voltage on the carrier type, it yields information about the charge of the transient carriers and the type of deep traps involved in the release or trapping of these carriers.     

Electric cadavers, 'metiphor,' and other medical software marvels

"Grateful Med," "Fluids," "Metiphor," virtual reality, and electric cadavers are just some of the programs and buzzwords in the futuristic world of medical software affecting many areas of health care.     

Characterization of piezoceramics

A 3-D approach to piezoelectric material characterization, based on the assumption that the coordinate axes are pure mode propagation directions, is described. In this case the general equations simplify and an analytical solution can be achieved. For two geometrical shapes (rectangular and cylindrical), stress and strain tensor components and the electrical impedance of the sample are obtained. These 3-D equations show that the wave velocities and permittivity are intrinsic parameters of the medium and do not depend on either the sample geometry or the mode that is considered. This was not true for the 1-D models where the wave velocities and permittivity are different for each of the modes or geometries.     

Lifecare

Foodservice has become a major attraction in lifecare communities, the fastest growing segment of the senior citizens housing market.     

Polybrominated Diphenyl Ethers in Surface Sediment from Songhua River Basin, Northeast of China

Sixty sediment samples were collected from the main Songhua River in three years. Twelve polybrominated diphenyl ether ( PBDE) congeners ( BDE17, 28, 47, 66, 99, 100, 153, 154, 138, 183, and BDE?209) w...     

从复杂硫化精矿中浸取金和银 1.氰化浸取动力学的研究

报导了从含铜硫化金精矿中氰化浸取金和银的动力学。实验考察了室温下氰化过程中精矿粒度、矿浆搅拌强度、初始氰浓度和氧分压等过程参量对金和银溶解动力学的影响。其实验数据以末反应核收缩模型进行数学处理,得到一个关联初始氰浓度和氧分压的溶解速度常数表达式。速率模型和贵金属氧化溶解的电化学机理相符,并表明氰离子和溶解氧分子扩散通过金粒表面的多孔层是速率控制步骤。     

电热流态床渗碳动力学

在石墨流态粒子炉中,在直接电阻加热的影响下,强化了表面过程和加速了碳在奥氏体中的扩散,因而渗碳速度比在常规的气体炉中快得多,作者利用一台在设计时消除了第二影响因素的流态床炉探讨了前一因素对阿姆柯铁试样渗碳动力学的影响。