An integrated domain analysis approach for teleoperated systems

Teleoperated systems for ship hull maintenance (TOS) are robotic systems for ship maintenance tasks, such as cleaning or painting a ship’s hull. The product line paradigm has recently been applied to TOS, and a TOS reference architecture has thus been designed. However, TOS requirements specifications have not been developed in any rigorous way with reuse in mind. We therefore believe that an opportunity exists to increase the abstraction level at which stakeholders can reason about this product line. This paper reports an experience in which this TOS domain was analyzed, including the lessons learned in the construction and use of the TOS domain model. The experience is based on the application of extensions of well-known domain analysis techniques, together with the use of quality attribute templates traced to a feature model to deal with non-functional issues. A qualitative research method (action research) was used to carry out the experience.     

Some aspects of the electrochemistry of the flotation of pyrrhotite

The iron sulfide mineral, pyrrhotite (Fe_(1–x)S), has long been known to be more difficult to recover by flotation from alkaline slurries than many other base metal sulfide minerals. This paper summarizes the results of an electrochemical study of the surface reactions that occur during the flotation of nickeliferous pyrrhotite in the recovery of nickel and the platinum group metals. Mixed potential measurements conducted with natural pyrrhotite electrodes in various stages of an operating flotation plant showed that the mineral potential is positive to the equilibrium potential of the xanthate/dixanthogen couple. Similar results were obtained during batch flotation experiments and in synthetic solutions in the laboratory. Cyclic voltammetric and potentiostatic current/time transient experiments were used to investigate the oxidation of pyrrhotite under various conditions. In addition, the reduction of oxygen, the reaction of copper ions and the oxidation of xanthate ions at the mineral surface were investigated. The formation of dixanthogen on pyrrhotite surfaces is thermodynamically favourable in plant flotation slurries. However the interaction with xanthate at pH values above 7 is inhibited by a surface species formed during the conditioning prior to xanthate addition. In acidic solutions copper ions react readily with pyrrhotite to form a species, possibly CuS that can be oxidized at potentials above 0.4 V. At pH 9 this species does not form and there is no electrochemical reaction between pyrrhotite and copper ions. The beneficial effects of copper ions to flotation performance appear to be related to an enhancement of the oxidation of xanthate.     

Trickle Flow Multiplicity: The Influence of the Prewetting Procedure on Flow Hysteresis

The existence of multiple hydrodynamic studies (MHS) in trickle flow is a well-known phenomenon. It is also known that different prewetting procedures result in major differences in MHS when the hydrodynamic variables pressure drop, liquid holdup and gas–liquid mass transfer are considered. Given a certain prewetting procedure one still has the option to perform flow hysteresis cycles to achieve an even wider variety of MHS. Although numerous studies have been performed on trickle flow hysteresis, none have attempted to decouple the hysteresis behaviour from the prewetting procedure followed. Accordingly there are numerous hysteresis possibilities that have not been investigated. In this work a single liquid and gas cycle were performed for four distinct prewetting procedures described here as a dry bed, a Levec type prewetted bed, Kan prewetted bed (achieved by increasing either the liquid or the gas flow rate until the pulsing flow regime is reached) and a Super prewetted bed. Pressure drop, liquid holdup and gas–liquid mass transfer are the hydrodynamic parameters studied to quantify the various MHS. It is shown that the shape and extent of the hysteresis cycle are strongly dependant on the prewetting procedure. In terms of flow structure, similar hysteresis trends on the Kan Liquid and Super prewetting modes indicate that these modes are hydrodynamically similar. The additional measurement of the hysteresis behaviour of gas–liquid mass transfer proofs that neither holdup nor pressure drop can be used as an indicator of the distribution uniformity.     

Trickle flow hydrodynamic multiplicity: Experimental observations and pore-scale capillary mechanism

Trickle bed reactors are encountered throughout the process industry. Considerable attention has been given to the study of the hydrodynamics of this type reactor. It has been identified that, in the trickle flow regime, the hydrodynamic parameters (e.g. pressure drop and liquid holdup) are not unique functions of the operating and system conditions, but depend on the flow history. This study reviews the experimental trends identified in literature on the basis of a limiting cases framework and then evaluates the three-dimensional pore-scale liquid distribution using computed tomography (CT) data. This leads to the identification of 20 phenomenological trends that characterize hydrodynamic multiplicity, including hydrodynamic flow hysteresis as well as the effects of pre-wetting. The CT study yields additional experimental insight into the role of capillary pressure and ultimately leads to the proposal of a capillary gate mechanism based on contact angle hysteresis as the root cause of multiplicity. The mechanism is incorporated into a simple pore-network model. It is shown that the qualitative performance of the model corresponds closely to the majority of phenomenological trends and is capable of explaining the observed experimental behaviour.     

Constructing ensembles of classifiers using supervised projection methods based on misclassified instances

In this paper, we propose an approach for ensemble construction based on the use of supervised projections, both linear and non-linear, to achieve both accuracy and diversity of individual classifiers. The proposed approach uses the philosophy of boosting, putting more effort on difficult instances, but instead of learning the classifier on a biased distribution of the training set, it uses misclassified instances to find a supervised projection that favors their correct classification. We show that supervised projection algorithms can be used for this task. We try several known supervised projections, both linear and non-linear, in order to test their ability in the present framework. Additionally, the method is further improved introducing concepts from oversampling for imbalance datasets. The introduced method counteracts the negative effect of a low number of instances for constructing the supervised projections.The method is compared with AdaBoost showing an improved performance on a large set of 45 problems from the UCI Machine Learning Repository. Also, the method shows better robustness in presence of noise with respect to AdaBoost.     

An algorithm to represent occupant use of windows and fans including situation-specific motivations and constraints

A theoretical model of the interaction between a building and its occupants is developed based on field survey data; the role of the model in building performance simulation is illustrated. If free to do so, people adjust their clothing or available building controls (windows, blinds, doors, fans, and thermostats) with the aim of achieving or restoring comfort and reducing discomfort. Initially responses to thermal conditions are considered. Trigger temperatures are established where responses to warm or cold thermal discomfort may occur. These trigger-temperatures depend on (among other things) clothing (which may depend on season and social conditions) and air movement (e.g., fan setting). Trigger-temperatures differ from person to person and from time to time. If several controls are available people will use those that are most user-friendly, effective and free from undesirable consequences, and this is represented in the model by a constraint assigned to each control option. The concept of constraints is then expanded to capture non-thermal stimuli for control use (e.g., fresh-air). Using datasets from surveys in Europe and Pakistan, estimates are made of the parameters used in the model: the comfort temperature in relation to the prevailing outdoor temperature, the extent of inter-personal variation of trigger temperature, the effect of a fan on the comfort temperature, and the values of constraints that affect the use of windows and fans in the surveyed buildings. The incorporation of the new model, including constraints, into building simulation code is illustrated. Some limitations or unknowns in the current model are identified and possible approaches for future research to fill these gaps suggested. The application of the model in building performance analysis and building design is discussed.     

Catalytic combustion of polycyclic aromatic hydrocarbons (PAHs) over zeolite type catalysts: Effect of water and PAHs concentration

The catalytic combustion of 1-methylnaphthalene (1-MN), a PAH representative molecule, was carried out over USHY and 0.8%PtUSHY catalysts in presence of steam. These catalysts are able to transform low concentration of 1-MN into carbon dioxide at 300 °C over USHY catalyst and at 200 °C over PtUSHY, without by-products formation. The presence of platinum on the USHY increases the catalytic activity, hence the reaction rate. The influence of platinum content showed that 0.5% of platinum deposited on the zeolite was sufficient to oxidize 900 ppm of 1-MN at 300 °C.The influence of water content in the feed was investigated and several assumptions were put forth to explain our results. The carbon dioxide yield decreases in the 0–12% range of relative humidity (RH). When RH increases up to 12% the carbon dioxide yield increases. Over USHY catalyst and for low water content (RH < 12%), water could be adsorbed over strong hydrophylic sites of USHY zeolite or via H₂O dimer (neutral complex form) formation. Over PtUSHY catalysts, water adsorption over the PtO phase could be considered. For high water content (RH > 12%), water cluster formation via H₂O dimer (ion-pair complex form) is proposed on both catalysts. This form of H₂O dimer (ion-pair complex) could generate an acidity, which facilitates the formation of oxygenated compounds easily degradable into carbon dioxide.     

Atomically Thin Mica Flakes and Their Application as Ultrathin Insulating Substrates for Graphene

By mechanical exfoliation, it is possible to deposit atomically thin mica flakes down to single‐monolayer thickness on SiO₂/Si wafers. The optical contrast of these mica flakes on top of a SiO₂/Si substrate depends on their thickness, the illumination wavelength, and the SiO₂ substrate thickness, and can be quantitatively accounted for by a Fresnel‐law‐based model. The preparation of atomically thin insulating crystalline sheets will enable the fabrication of ultrathin, defect‐free insulating substrates, dielectric barriers, or planar electron‐tunneling junctions. Additionally, it is shown that few‐layer graphene flakes can be deposited on top of a previously transferred mica flake. Our transfer method relies on viscoelastic stamps, as used for soft lithography. A Raman spectroscopy study shows that such an all‐dry deposition technique yields cleaner and higher‐quality flakes than conventional wet‐transfer procedures based on lithographic resists.