Progress and challenges in sustainability,compatibility, and production of eco-composites: A state-of-art review

Owing to economic and environmental benefits, new generations of materials/commodities follow “from waste to wealth” strategy. Recently, there has been a huge upsurge in research on the development of eco-composites using recycled plastic polymers and agro-residues because the eco-composites satisfy the stringent environment regulations and are cost-effective. Herein, we present a detailed review on the potential use of several types of natural fillers as an efficient reinforcement for recycled plastic polymers. In particular, the characterization of different categories of eco-composites according to their morphological, physical, thermal, and mechanical properties is extensively reviewed and their results are analyzed, compared, and highlighted. Furthermore, a framework to produce functional eco-composites, which includes functionalization of ingredients, critical issues on microstructural parameters, processing, and fabrication methods, is outlined and supported with sufficient data from the literature. Finally, the review outlines the emerging challenges and future prospects of eco-composites to be addressed by interested researchers to bridge the gap between research and commercialization of such a class of material. Overall, the acquired knowledge will guide researchers, scientists, and manufacturers to plan, select, and develop various forms of eco-composites with enhanced properties and optimized production processes.     

Enhanced anti-biofilm activity of facile synthesized silver oxide nanoparticles against K. pneumoniae

Journal of Inorganic and Organometallic Polymers and Materials - The silver oxide nanoparticle was successfully synthesized using floral waste by simple one pot, cost effective method. The complete...     

Strain mediated enhancement in magnetoelectric properties of sonochemically synthesized piezoelectric and piezomagnetic composites

Materials with magneto-electric (ME) properties are of great importance because of their demand in electronic industries. Three dimensional nano-particles of the ME-composites having the general formula (1-x)CoCr_0.3Fe_1.7O₄(CCFO)+(x)BaTiO₃(BTO) (x = 0.0, 0.2, 0.4, 0.6, 0.8 and 1.0) were obtained by comprising the piezoelectric-BTO and piezomagnetic-CCFO phases. The individual phases of CCFO and BTO were synthesized separately by ultrasonic irradiation assisted sonochemical and sol-gel routs. X-ray diffraction patterns (XRD) confirmed the well-crystalline nature of both the phases. BTO and CCFO phases were under tensile strain as confirmed by the variation in lattice constants with varying proportion of BTO and CCFO. An energy-dispersive X-ray spectroscopy spectrum confirmed the phase purity of the samples and stoichiometric concentration of elements. Magnetic properties were investigated by M ? H loop measurements and dielectric properties by using RF impedance analyzer. Dielectric constant increased with the increasing percentage of BTO. The maximum value of ME coefficient (24.7 mV/cm?Oe) is observed for the 60%CCFO+40%BTO sample. The obtained results were discussed in the light of grain size, strain and the basic properties of the individual phases. The prepared materials can be applicable in electronic devices where high magneto-electric coefficient is desirable.     

CuxNi1-xO nanostructures and their nanocomposites with reduced graphene oxide: Synthesis,characterization, and photocatalytic applications

NiO nanostructure was synthesized using a simple co-precipitation method and was embedded on reduced graphene oxide surface via ultrasonication. Structural investigations were made through X-ray diffraction (XRD) and functional groups were confirmed by Fourier transform infrared spectroscopy (FTIR). XRD analysis revealed the grain size reduction with doping. Fourier transform infrared spectroscopy confirmed the presence of metal-oxygen bond in pristine and doped NiO nanostructure as well as the presence of carbon containing groups. Scanning electron microscopy (SEM) indicated that the particle size decreased when NiO nanostructure was doped with copper. BET surface area was found to increase almost up to 43 m²/g for Cu doped NiO nanostructure/rGO composite. Current-voltage measurements were performed using two probe method. UV–Visible spectroscopic profiles showed the blue and red shift for Cu doped NiO nanostructure and Cu doped NiO Nanostructure/rGO composite respectively. Rate constant for Cu doped NiO nanostructure/rGO composite found to increase 4.4 times than pristine NiO nanostructure.     

Developing a stochastic model to predict the strength and crack path of random composites

We characterize fracture and effective stress–strain graphs in 2D random composites subjected to a uniaxial in-plane uniform strain. The fibers are arranged randomly in the matrix. Both fibers and matrix are isotropic and elastic–brittle. We conduct this analysis numerically using a very fine two-dimensional triangular spring network and simulate the crack initiation and propagation by sequentially removing bonds which exceed a local fracture criterion. In particular, we focus on effect of geometric randomness on crack path of random composites. Based on that two stochastic micro-mechanic models are presented that can predict with confidence the failure probability of random matrix–inclusion composites.     

Antifungal activity of films and solutions based on chitosan against typical seed fungi

The use of eco-freindly polymers as antimicrobial materials is in growth due to the need to reduce the negative impact of conventional treatments on the environment and the human health. The purpose of the present study was to assess the antifungal properties of films and solutions based on chitosan with different molecular weight at different concentrations. Surfactants were added to the formulation to assess their impact on treatment efficiency. The antifungal activity was conducted against tree fungi, Aspergillus niger, Alternaria alternata and Rhizopus oryzae. Results indicated important and significant differences of the antifungal activity between chitosan based solutions and chitosan based films. Furthermore, the antifungal activity of the different treatment depended on the type of fungus treated. Thus, chitosan film treatments were significantly more effective on A. niger than solution treatments. On the other hand, solution treatments resulted in higher radial inhibition when applied against A. alternata or R. oryzae. The highest radial inhibition was observed against A. alternata (97%) using a chitosan solution. The influence of the other parameters (concentration, molecular weight and surfactant type) on treatment efficiency was not as important and their significance depended on treatment type and fungus nature.     

Hydrochloric acid extractable minerals and phytate and polyphenols contents of sprouted faba and white bean cultivars

Two faba bean (Hudieba-72 and Bsabir) and three white bean (Serge, Giza and RO21) cultivars were sprouted for 6 days. The sprouted grains were dried and milled. Phytic acid and polyphenols contents and hydrochloric acid (HCl) extractability of minerals from the malt flours were determined at intervals of 2 days during sprouting. Phytic acid and polyphenols contents decreased significantly (P ? 0.01) with increase in sprouting time with concomitant increase in HCl extractable major and trace minerals. The contents of both major and trace minerals were slightly increased with sprouting time. When faba bean seeds were sprouted for 6 days, Bsabir had higher extractable Ca, while Hudieba-72 had higher P, whereas Fe and Mn recorded high level in Hudieba-72. When white bean seeds were sprouted for 6 days, RO21 cultivar had higher extractable Ca, while Giza-3 cultivar had higher P, whereas Fe and Mn recorded high levels in Serge and RO21 cultivars, respectively. There was a good correlation between phytate and polyphenols reduction and increase in extractable minerals with increase in sprouting time for all cultivars.     

Drift demand of the outer‐skin curtain wall system of the Shanghai Tower

As a drift‐sensitive nonstructural component, the in‐plane deformation ability of the curtain wall (CW) in a tall building is critical to the seismic performance. The immediate earthquake excitation of the CW system is the floor response where the CW is located. To evaluate the drift demand of the outer‐skin CW system of the Shanghai Tower, floor responses of the reinforced stories of each vertical zone are analyzed. Drift demands, including the interzone drift ratio (IDR) and interzone drift response spectrum (IDRS), are obtained to define the engineering demand parameters related to the in‐plane relative displacement of the CW system. The results show that the 3‐dimensional ground motion (GM) excitations generate larger heightwise IDR distribution profiles and larger IDRSs than the 1‐dimensional GMs. The obtained IDR demands are shown to be 1/250, 1/150, and 1/100 for 3 key earthquake intensity levels. These values are different from those given by the current code provisions of China and other countries. The IDR distribution profiles of each vertical zone increase with height. The mean IDRSs of all 8 main vertical zones under selected GM excitations are determined as the representative drift spectra for each earthquake intensity level. Based on these mean spectra, simplified bilinear drift spectra are constructed for seismic design and analysis of the outer‐skin CW system of the Shanghai Tower.     

Acceleration demand of the outer‐skin curtain wall system of the Shanghai Tower

The unique complexities of the outer‐skin curtain wall (CW) system of the Shanghai Tower increase the difficulty in evaluating its seismic performance. To assess such seismic performance, it is important to understand the floor acceleration demand under expected earthquake actions. Acceleration demand of the CW system consists of floor acceleration amplification (FAA) and floor response spectrum (FRS), which are closely related to the equivalent static seismic design force and the dynamic properties of the CW system. For estimating the FAA and FRS, code spectra compatible ground motions are selected and input to a finite element model of the building structure. The floor responses of key stories are analyzed. Normalized distribution of the horizontal FAA demand is estimated and shows that the obtained values exceed those proposed by current code provisions for low‐intensity earthquake excitations. It is noted that the vertical FAA demand has a different distribution profile than the horizontal one. The results indicate that FAA demand under three‐dimensional earthquake excitation is larger than that for 1D excitation. Moreover, the prime period range is up to 4.0 s for the horizontal FRS and up to 1.0 s for the vertical FRS. Horizontal and vertical FRS is proposed for dynamic analysis of the outer‐skin CW system of the Shanghai Tower.