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21.
Heterogeneous Catalysis   总被引:4,自引:0,他引:4  
  相似文献   
22.
We propose a novel solar cell structure with photonic nanocrystals coupled to quantum dots (QDs) for advanced management of photons and carriers. The photonic nanocrystals at the surface create an extra interaction between the photons and the QDs, which promotes light trapping. Photo-generated carriers can be efficiently transported by preparing vertically aligned QDs with electronic coupling. Implementation of the proposed structure was realized in crystalline Si solar cells with Ge QDs by development of a simple and practical formation method based on a wet chemical process without any lithography techniques. The wet process utilizes a periodically modulated etching rate induced by self-organized Ge QDs. The effectiveness of the proposed solar cell was demonstrated by the marked increase of the absolute conversion efficiency when compared with the control crystalline Si solar cells. It is found that light trapping by the photonic nanocrystals has a larger contribution to the efficiency improvement than the contributions from the carrier transport of the vertically aligned QDs.  相似文献   
23.
Transient liquid phase (TLP) bonding enables joining at lower temperatures than traditional bonding techniques and preserves the potential for high-temperature applications, making it particularly attractive for joining ultra-high-temperature ceramics (UHTCs) such as carbides and borides. The feasibility of a TLP joint between “pure” carbides has been recently demonstrated. The present study examines the interactions that occur between undoped HfC or MoSi2-doped HfC and a Ni/Nb/Ni multilayer interlayer during TLP bonding. Bonding is performed at 1400 °C for 30 min in a high-vacuum furnace. SEM–EDS characterization shows that the reaction layer formed at the interlayer/ceramic interface contains mixed carbides and depending upon the ceramic, Ni–Nb–Hf, or Ni–Nb–Hf–Si, or Ni–Nb–Si alloys. Nanoindentation tests traversing the reaction layer between the bulk ceramic and Nb foil midplane also show a clear transition zone across which the indentation modulus and hardness vary. Crack-free joints have been obtained with undoped HfC. The addition of 5 vol% MoSi2 introduces small (<5 μm long) isolated cracks within the reaction layer, whereas with 15 vol% MoSi2 added, cracking was pervasive within the reaction layer. When the reaction layer exceeds a critical thickness, as in the case of the bond obtained with HfC doped with 15 vol% MoSi2, residual stresses become sufficiently large to cause extensive cracking and bond failure. The results suggest a need to characterize and balance the positive role of additives on sintering with the potentially deleterious role they may have on joining.  相似文献   
24.
We have investigated a nanostructured electrode from the viewpoint of improving the performance of FETs. The nanostructured gold layer acted as a positive factor contributing to an increase in the photocurrent, while maintaining low levels of photo-voltage (photo-Voc) of the gold electrode itself and the FET performance (photo-Ids). Such negative effects of the nanostructured gold layer were attributed to the low-surface coverage of molecules and high interactive ability between the electrode and the electro-active species in the enlarged diffusion layer of the electrolyte solution around the nanostructured gold electrode.  相似文献   
25.
A thin beam of wave usually diverges due to diffraction, which is a limitation of any device using such waves. However, a surface acoustic wave (SAW) on a sphere with an appropriate aperture does not diverge but is naturally collimated, realizing ultramultiple roundtrips along an equator of the sphere. This effect is caused by the balance between diffraction and focusing on a spherical surface, and it enables realization of high-performance ball SAW sensors. The advantage of ball SAW is most fully appreciated when applied to a very thin sensitive film for which the multiple-roundtrip enhances the sensitivity, but the attenuation loss is not very large. It is exemplified in a hydrogen gas sensor that realizes a wide sensing range of 10 ppm to 100% for the first time, and realizes relatively fast response time of 20 s without heating the sensitive film.  相似文献   
26.
Recently, a data processing and retrieval algorithm (version 2) for ozone, aerosol, and temperature lidar measurements was developed for an ozone lidar system at the National Institute for Environmental Studies (NIES) in Tsukuba (36 degrees N,140 degrees E), Japan. A method for obtaining the aerosol boundary altitude and the aerosol extinction-to-backscatter ratio in the version 2 algorithm enables a more accurate determination of the vertical profiles of aerosols and a more accurate correction of the systematic errors caused by aerosols in the vertical profile of ozone. Improvements in signal processing are incorporated for the correction of systematic errors such as the signal-induced noise and the dead-time effect. The mean vertical ozone profiles of the NIES ozone lidar were compared with those of the Stratospheric Aerosol and Gas Experiment II (SAGE II); they agreed well within a 5% relative difference in the 20-40 km altitude range and within 10% up to 45 km. The long-term variations in the NIES ozone lidar also showed good coincidence with the ozonesonde and SAGE II at 20, 25, 30, and 35 km. The temperatures retrieved from the NIES ozone lidar and those given by the National Center for Environmental Prediction agreed within 7 K in the 35-50 km range.  相似文献   
27.
Two patients with polymyositis (PM) or dermatomyositis (DM) complicated with massive pleural effusion are reported here. Both patients presented a high-grade fever, pleural effusion prominent on the right, and good response to steroid therapy. In a 50-year-old woman with PM, combined process of pleural inflammation, cardiomyopathy and coexisting hypothyroidism were considered to be responsible for the accumulation of the massive pleural effusion. However, in a 34-year-old man with DM, pleural inflammation associated with interstitial pneumonia or pleural microvasculopathy in DM was considered to be responsible for the accumulation of the massive pleural effusion.  相似文献   
28.
29.
A thin beam of waves usually diverges due to diffraction, which is a limitation of any device using such waves. However, a surface acoustic wave (SAW) on a sphere with an appropriate aperture does not diverge but is collimated, realizing ultra‐multiple roundtrips along an equator of the sphere. This effect is caused by the balance between diffraction and focusing on a spherical surface, and it enables realization of high‐performance ball SAW sensors. © 2009 Wiley Periodicals, Inc. Electr Eng Jpn, 168(1): 41–51, 2009; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20817  相似文献   
30.
This study evaluates the numerical modeling of stress corrosion cracks from the viewpoint of eddy current simulations. Five stress corrosion cracks are artificially introduced into austenitic stainless steel plates measuring 25 mm in thickness, and then eddy current inspections are conducted to gather eddy current signals and destructive tests performed to confirm the true profiles of the cracks. The cracks are carefully introduced so as not to cluster, and the data obtained enables discussion of the modeling of a single crack quantitatively. Subsequent numerical simulations model each crack as a rectangular region with a fixed width and uniform conductivity, and evaluate the equivalent width and conductivity suitable for modeling the crack. The evaluation reveals that it is not reasonable to correlate the size of a crack and only its width or conductivity, and larger cracks tend to have greater resistance, which is defined as the width divided by conductivity. Furthermore, the values of width and conductivity depend also on the exciting frequency and probe used; however, the resistance remains almost unchanged by the experimental condition.  相似文献   
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