New trends in solar photovoltaics: From physics to chemistry

The paper briefly discusses the current situation in the field of traditional and unconventional photovoltaic materials and solar cells. It emphasizes the fact that the main basic achievements in the field of solid-state solar photovoltaics were gained at least two decades ago and the further progress focused on the improvement of cell parameters and technological aspects. Finally, the article concludes that this scientific area has nearly fulfilled its historical task. Indeed, the last decade has brought many new achievements in the field of the alternative, molecular-based materials. The future of solar energy conversion seems to be mainly connected with chemistry, chemical physics and chemical engineering but not with solid-state physics as in the twentieth century. The paper gives also a short over-view of some promising organic semiconductors, fullerenes and TiO₂ nanocrystalline structures used now in a new generation of molecular solar cells. Presented at the Int’l Symp. on Chem. Eng. (Cheju, Feb. 8–10, 2001), dedicated to Prof. H. S. Chun on the occasion of his retirement from Korea University     

Tailoring the diameter of single-walled carbon nanotubes for optical applications

Single-walled carbon nanotubes (SWCNTs) with specific diameters are required for various applications particularly in electronics and photonics, since the diameter is an essential characteristic determining their electronic and optical properties. In this work, the selective growth of SWCNTs with a certain mean diameter is achieved by the addition of appropriate amounts of CO₂ mixed with the carbon source (CO) into the aerosol (floating catalyst) chemical vapor deposition reactor. The noticeable shift of the peaks in the absorption spectra reveals that the mean diameters of the as-deposited SWCNTs are efficiently altered from 1.2 to 1.9 nm with increasing CO₂ concentration. It is believed that CO₂ acts as an etching agent and can selectively etch small diameter tubes due to their highly curved carbon surfaces. Polymer-free as-deposited SWCNT films with the desired diameters are used as saturable absorbers after stamping onto a highly reflecting Ag-mirror using a simple dry-transfer technique. Sub-picosecond mode-locked fiber laser operations at ∼1.56 μm and ∼2 μm are demonstrated, showing improvements in the performance after the optimization of the SWCNT properties.      

The adaptive algorithm of information unmistakable embedding into digital images based on the discrete Fourier transformation

Multimedia Tools and Applications - Many effective methods of the data embedding into digital images are based on the frequency transformations. However use of similar transformations is connected...     

Verformungsanalyse elektrisch leitender metallischer Bauteile bei Magnetimpulsbearbeitung

In the present study the deformation of conductive metallic systems under the action of electromagnetic fields is investigated. For this purpose, a variational formulation is introduced. The coupling of the propagation of electromagnetic fields and the deformation is taken into account by the introduction of electromagnetic forces. The suggested model allows the numerical analysis of the deformation of electrically conductive metallic systems under magnetic pulse processing.     

Cobalt based nanostructured alloys: Versatile high performance robust hydrogen evolution reaction electro-catalysts for electrolytic and photo-electrochemical water splitting

Engineering reduced noble metal containing electro-catalysts exhibiting superior electrochemical performance is important for efficient and economic production of hydrogen from electrolytic and photoelectrochemical (PEC) water splitting reactions. In this study, nanostructured Co–Ir solid solution alloys, Co_1?x(Ir_x) (x = 0.2, 0.3, 0.4) have been studied as electro-catalysts for hydrogen evolution reaction (HER). Co_1?x(Ir_x) (x = 0.3, 0.4) exhibit similar onset over-potential to Pt/C and lower over-potential required for Co_1?x(Ir_x) (x = 0.3, 0.4) than Pt/C in acidic, neutral as well as basic media, suggesting excellent electrochemical activity of Co–Ir alloys, further studied using theoretical first principles density functional theory calculations. Co_1?x(Ir_x) exhibit excellent electrochemical stability in acidic media similar to that of Pt/C. The applied bias photon-to-current efficiency obtained using Co_1?x(Ir_x) (x = 0.3, 0.4) electro-catalysts and (Sn_0.95Nb_0.05)O₂:N-600 NTs as photoanode in H-type cell is ～5.74% and ～7.92%, respectively which is ～40% and ～93% higher than Pt/C (～4.1%) indicating considerable promise of the system.     

Degradation of dicarboxylic acids (C2-C9) upon liquid-phase reactions with O3 and its atmospheric implications

Aerosols are considered major players in climate change and represent health hazards. Dicarboxylic acids are among a major class of components that form secondary organic atmospheric aerosols. To understand the atmospheric transformation of these compounds, kinetic studies on the ozonolysis and the photoinduced ozonolysis (lambda > or = 250 nm) of aqueous solutions of seven (C2-C9) dicarboxylic acids, which have been identified in atmospheric aerosols, were performed using Fourier transform infrared and ultraviolet-visible spectroscopy. The measured apparent rate constants for dicarboxylic acids in 0.1 mol L(-1) aqueous solutions at 298 +/- 2 K are as follows: oxalic, (2.7 +/- 0.1) x 10(-2); malonic, (5.5 +/- 0.1); succinic, (6.7 +/- 0.4) x 10(-4); glutaric, (1.3 +/- 0.2) x 10(-3); adipic, (1.7 +/- 0.1) x 10(-3); pimelic, (4.4 +/- 0.1) x 10(-3); and pinic, (2.5 +/- 0.1) x 10(-2) (L mol(-1) s(-1)). An empirical equation is provided to estimate the ozonolysis rate constant of dicarboxylic acids containing more than three carbon atoms for which no experimental data exists. A mechanism for malonic acid ozonolysis, which explains its fast ozonolysis rate constant, is also suggested. The implications of our results to atmospheric chemistry indicate that ozonolysis and photoinduced ozonolysis are not significant removal pathways for dicarboxylic acids.     

The Story of the GeoToolKit—An Object-Oriented Geodatabase Kernel System

The quickly increasing number of spatio-temporal applications in fields like environmental monitoring, geology and mobile communication is a new challenge to the development of geodatabases. However, the query functionality of today's geo-information systems is still limited to the thematic attributes of spatial objects and to spatial 2-D objects. This article reports on GeoToolKit, an object-oriented geo-database kernel system developed at Bonn University to support 3-D/4-D geological applications. GeoToolKit is not a GIS-in-a-box package, but rather a library of C ++ classes that allows the incorporation of spatio-temporal functionality within an application. Being a component toolkit, it encourages the development and deployment of re-usable and open software. The history, concepts and implementation of GeoToolKit are discussed in detail. Performance tests underline the practicability of the concepts. Extensions to and experiences with GeoToolKit applications like GeoStore, GeoWeb and WellStore are presented. Finally, we give an outlook on our future research introducing GeoToolKit as a 3-D/4-D database component within a network of distributed and mobile geo-information services.     

Document skew estimation without angle range restriction

The existing skew estimation techniques usually assume that the input image is of high resolution and that the detectable angle range is limited. We present a more generic solution for this task that overcomes these restrictions. Our method is based on determination of the first eigenvector of the data covariance matrix. The solution comprises image resolution reduction, connected component analysis, component classification using a fuzzy approach, and skew estimation. Experiments on a large set of various document images and performance comparison with two Hough transform-based methods show a good accuracy and robustness for our method. Received October 10, 1998 / Revised version September 9, 1999     

Practical implementation of 2D HPLC scheme with accurate peptide retention prediction in both dimensions for high-throughput bottom-up proteomics

We describe the practical implementation of a new RP (pH 10 - pH 2) 2D HPLC-ESI/MS scheme for large-scale bottom-up analysis in proteomics. When compared to the common SCX-RP approach, it provides a higher separation efficiency in the first dimension and increases the number of identified peptides/proteins. We also employed the methodology of our sequence-specific retention calculator (SSRCalc) and developed peptide retention prediction algorithms for both LC dimensions. A diverse set of approximately 10,000 tryptic peptides from the soluble protein fraction of whole NK-type cells gave retention time versus hydrophobicity correlations, with R (2) values of 0.95 for pH 10 and 0.945 for pH 2 (formic acid) separation modes. The superior separation efficiency and the ability to use retention prediction to filter out false-positive MS/MS identifications gives promise that this approach will be a method of choice for large-scale proteomics analyses in the future. Finally, the "semi-orthogonal" separation selectivity permits the concatenation of fractions in the first dimension of separation before the final LC-ESI MS step, effectively cutting the analysis time in half, while resulting in a minimal reduction in protein identification.     

Complex radioelectronic equipment restoration cost optimization

The restoration system considered includes complex radioelectronic equipment, repair body and spares kit. The problem considered is how to optimize the total cost of the repair body and spares kit while maintaining the predetermined reliability of the radioelectronic equipment.