全文获取类型
收费全文 | 1289篇 |
免费 | 17篇 |
国内免费 | 4篇 |
专业分类
电工技术 | 98篇 |
化学工业 | 380篇 |
金属工艺 | 24篇 |
机械仪表 | 35篇 |
建筑科学 | 26篇 |
矿业工程 | 1篇 |
能源动力 | 58篇 |
轻工业 | 89篇 |
水利工程 | 1篇 |
石油天然气 | 1篇 |
无线电 | 75篇 |
一般工业技术 | 293篇 |
冶金工业 | 46篇 |
原子能技术 | 38篇 |
自动化技术 | 145篇 |
出版年
2022年 | 22篇 |
2021年 | 21篇 |
2020年 | 7篇 |
2019年 | 9篇 |
2018年 | 7篇 |
2017年 | 13篇 |
2016年 | 23篇 |
2015年 | 13篇 |
2014年 | 31篇 |
2013年 | 62篇 |
2012年 | 50篇 |
2011年 | 84篇 |
2010年 | 47篇 |
2009年 | 48篇 |
2008年 | 72篇 |
2007年 | 70篇 |
2006年 | 55篇 |
2005年 | 47篇 |
2004年 | 43篇 |
2003年 | 51篇 |
2002年 | 48篇 |
2001年 | 33篇 |
2000年 | 26篇 |
1999年 | 32篇 |
1998年 | 47篇 |
1997年 | 31篇 |
1996年 | 23篇 |
1995年 | 22篇 |
1994年 | 17篇 |
1993年 | 25篇 |
1992年 | 15篇 |
1991年 | 20篇 |
1990年 | 15篇 |
1989年 | 13篇 |
1988年 | 19篇 |
1987年 | 11篇 |
1986年 | 14篇 |
1985年 | 17篇 |
1984年 | 18篇 |
1983年 | 9篇 |
1982年 | 9篇 |
1981年 | 8篇 |
1980年 | 9篇 |
1979年 | 16篇 |
1978年 | 12篇 |
1976年 | 6篇 |
1974年 | 4篇 |
1973年 | 4篇 |
1970年 | 2篇 |
1968年 | 3篇 |
排序方式: 共有1310条查询结果,搜索用时 0 毫秒
51.
Meso-porous Al2O3-supported Ni catalysts exhibited the highest activity, stability and excellent coke-resistance ability for CH4 reforming with CO2 among several oxide-supported Ni catalysts (meso-porous Al2O3 (Yas1-2, Yas3-8), -Al2O3, -Al2O3, SiO2, MgO, La2O3, CeO2 and ZrO2). The properties of deposited carbons depended on the properties of the supports, and on the meso-porous Al2O3-supported Ni catalyst, only the intermediate carbon of the reforming reaction formed. XRD and H2-TPR analysis found that mainly spinel NiAl2O4 formed in meso-porous Al2O3 and -Al2O3-supported catalysts, while only NiO was detected in -Al2O3, SiO2, CeO2, La2O3 and ZrO2 supports. The strong interaction between Ni and meso-porous Al2O3 improved the dispersion of Ni, retarded its sintering and improved the activated adsorption of CO2. The coking reaction via CH4 temperature-programed decomposition indicated that meso-porous Al2O3-supported Ni catalysts were less active for carbon formation by CH4 decomposition than Ni/-Al2O3 and Ni/-Al2O3. 相似文献
52.
Phase Relations and Volume Changes of Hafnia under High Pressure and High Temperature 总被引:1,自引:0,他引:1
Osamu Ohtaka Hiroshi Fukui Taichi Kunisada Tomoyuki Fujisawa Kenichi Funakoshi Wataru Utsumi Tetsuo Irifune Koji Kuroda Takumi Kikegawa 《Journal of the American Ceramic Society》2001,84(6):1369-1373
Using multi-anvil high-pressure devices and synchrotron radiation, X-ray in situ observations of HfO2 under high pressure and high temperature have been performed to investigate its phase relations and compression behavior. An orthorhombic phase (orthoI) is stable from 4 to 14.5 GPa below 1250°–1400°C and transforms to a tetragonal phase, which is one of the high-temperature forms of HfO2 , above these temperatures. Another orthorhombic phase (orthoII) with a cotunnite-type structure appears above 14.5 GPa. OrthoII is stable up to 1800°C at 21 GPa. OrthoII is quenchable to ambient conditions. The orthoI-to-orthoII transition is accompanied by ∼8 vol% decrease. The bulk moduli of orthoI and orthoII at room temperature are 220 and 312 GPa, respectively. This low compressibility of orthoII indicates that it is a potential candidate for very hard materials. 相似文献
53.
Telechelically bis(hydrodimethylsilyl)-functionalized oligo(dimethylsiloxane)s or aromatics were found to give polymers constituting
of alternating disilylene and oligodimethylsiloxane or 4,4′-diylaromatics as repeating units by dehydrogenative coupling reaction
in the presence of palladium dibenzylideneacetone complex. The same catalyst gave polysilylenes with trisiloxane pendant from
1,1-dihydro-1,3,3,5,5,7,7,7-octamethyltetrasiloxane.
Received: 18 October 1996/Accepted: 31 October 1996 相似文献
54.
Hisayuki Suematsu Mamoru Mitomo Terence E. Mitchell John J. Petrovic Osamu Fukunaga Naoki Ohashi 《Journal of the American Ceramic Society》1997,80(3):615-620
Single crystals of α-Si3 N4 were annealed at 2000°–2150°C. The β phase was detected after annealing at 2150°C only when the crystals were surrounded by MgO·3Al2 O3 or Y2 O3 powders. On the other hand, no evidence of the α–β transformation was found when the crystals were annealed without additives. The solution–precipitation mechanism was concluded to be the dominant factor in the α–β transformation of Si3 N4 . 相似文献
55.
Kenji Arata Nobutaka Takeuchi Masaru Yoshinaka Ken Hirota Osamu Yamaguchi 《Journal of the American Ceramic Society》1997,80(8):2168-2170
Continuously graded MoSi2 -ZrO2 (2Y) materials with high density (97.5% of theoretical) have been fabricated by uniaxial wet-molding, followed by hot pressing (1000°C/1 h/30 MPa) and hot isostatic pressing (1400°C/2 h/196 MPa). Their composition profiles are greatly influenced by the viscosity of mixed solutions of glycerin and ethanol used as a dispersion medium; a linear compositional gradient from MoSi2 /ZrO2 (2Y) 70/30 to 20/80 mol% is obtained from the solution (50/50 vol%) with a viscosity of 20 mPa s. Vickers hardness (Hv) and fracture toughness (KIC) increase from 9.7 to 12.4 GPa and from 5.1 to 12.5 MPa m1/2, respectively, with increasing ZrO2 (2Y) composition. 相似文献
56.
The characteristics of pattern replication and releasing in a roll-to-roll ultraviolet- (UV) curing embossing process were investigated. The roll embossing system was designed for large-area continuous embossing, with employment of a fast curing resin, a heat damage protector, and a surface energy reducing coating. A 60° V-groove pattern with a groove period of 30 µm was embossed. It was found that the replication quality was profoundly influenced by the pattern geometry, the pattern direction, and the mold surface energy. In particular, the pattern direction significantly affected the edge sharpness and the surface topography of replicated features. In the parallel groove mode, a significant amount of tearing and sliding occurred, whereas in the transverse groove mode, biting marks were observed on the side wall of the V-groove. A simple mechanical model was used to explain the difference in pattern releasing with different pattern layouts. The replication quality was found to be significantly improved with the application of a fluorinated coating on the roll mold. 相似文献
57.
The synergistic effect of methyltrioctylammonium chloride (QCI) on the extraction of Np(V) by 1-phenyl-3-methyl-4-benzoyl-pyrazolone(HP) in benzene is studied over the pH range 2-6. This system extracts Np(V) better than any previously reported. The interaction of the extractants and monomer-dimer equilibria affect the distribution behavior of Np(V) in a complicated manner. Analysis of the results suggests that NpO2 + (M+) is extracted as mixed dimers, (QMP2QCl)o and (QMP2QP)o. 相似文献
58.
Osamu Nishikawa Kazuo Doyama Hiroyuki Uchida Masahiro Watanabe 《Electrochimica acta》2005,50(13):2719-2723
We have prepared novel gas diffusion electrodes for polymer electrolyte fuel cells (PEFC) using new organic/inorganic hybrid electrolytes. The catalyst layers were prepared by mixing 3-(trihydroxysilyl)-1-propanesulfonic acid [(THS)Pro-SO3H], 1,8-bis(triethoxysilyl) octane (TES-Oct), Pt loaded carbon black (Pt-CB) and water, followed by a sol-gel reaction. It was found that addition of uncatalyzed carbon black (u-CB) into the cathode catalyst layer enhanced the performance at high current density region, due to an increase in the gas diffusion rate. The optimum volume ratio of u-CB/Pt-CB was found to be 0.1, at which the gas diffusivity and the catalyst utilization are well balanced. 相似文献
59.
Hiroya Nakata Takayoshi Kiguchi Osamu Hino 《Journal of the American Ceramic Society》2022,105(4):2791-2803
To understand the role of phosphate ester dispersant, we investigated the rheology of a BaTiO slurry. For the model case, a coarse-grain molecular dynamics (CGMD) simulation was performed with the butyral polymer didodecyl hydrogen phosphate (DHP) in the toluene/ethanol solvent. By systematically analyzing the effect of DHP from an atomic-scale first principle and from all-atom MD to microscale CGMD simulation, we investigated how the adsorption of a DHP dispersant on a BaTiO surface affects the microstructure rheology of a BaTiO slurry. The first-principle and all-atom MD simulation suggests that DHP molecules prefer to locate near the BaTiO surface. CGMD simulation shows a reduction in viscosity with an increase in dispersants, suggesting that the dispersant population near the BaTiO surface plays a key role in controlling the rheology of the BaTiO slurry. In this study, we propose an approach for understanding the BaTiO slurry with molecular-level simulations, which would be a useful tool for efficient optimization of slurry preparation. 相似文献
60.
In this study, a new marine oil that contains 45% docosahexaenoic acid (DHA, 22∶6n−3) and 13% docosapentaenoic acid (DPA,
22∶5n−6) was administered to rats. The metabolism and distribution of DPA in rats was investigated. In experiment 1, the effects
of DHA and n−6 fatty acids (linoleic acid, I A; arachidonic acid, AA; and DPA) on AA contents were investigated in vivo. LA group: LA 25%, DHA 30%; LA-DPA group: LA 15%, DPA 10%, DHA 35%; LA-AA-DPA group: LA 10%, AA 5%, DPA 10%, DHA 35% were
administered to rats for 4 wk. In the liver, the AA content in the LA-DPA and LA-AA-DPA groups was significantly higher than
in the LA group. The decreased AA contents in the LA group might be caused by DHA administration. Although DHA also was administered
in the LA-DPA and LA-AA-DPA groups, the AA contents in these two groups did not decrease. These results suggested that DPA
retroconverted to AA, blunting the decrease in AA content caused by DHA administration. To conduct a detailed investigation
on DPA metabolism and its relation with AA and DHA, rat hepatocytes were cultured with pruified DPA and DHA for 24 h. We discovered
the retroconversion of DPA to AA occurred only when AA content was decreased by a high DHA administration; it did not occur
when AA content was maintained at a normal level. 相似文献