HIGHER PLANT BIOMARKERS IN PALEOGENE CRUDE OILS FROM THE YUFUTSU OIL-AND GASFIELD AND OFFSHORE WILDCATS, JAPAN

Geochemical investigation of Paleogene oils from the onshore Yufutsu oil- and gasfield, southern Hokkaido, and from two nearby offshore wells, revealed the presence of numerous biomarkers of higher plant origin. Biomarkers in the oils belong to different groups of both angiosperm and gymnosperm origin; they include bicyclic sesquiterpanes, diterpanes, and triterpanes and their aromatized counterparts, which suggests a terrestrial origin for the oils. The oils were characterized as having a high wax content, a low content of organosulphur compounds, a high pristane/phytane ratio, and a low C₂₇/(C₂₇+C₂₉) sterane ratio.
Although the oils from on- and offshore Southern Hokkaido are similar in their geochemical composition, notable differences were observed in the biomarker signature of both saturate and aromatic fractions. The oils from the offshore wells appeared to have a greater abundance of higher plant biomarkers compared to those from the Yufutsu field, suggesting an enrichment in higher plant components. Differences in biomarker fingerprint could not be linked to the maturity effect, since the oils appeared to be of similar maturity levels, corresponding to the late stage of the oil window (0.9–1.2%, Rc). The differences in the biomarker signatures between the oils from the Yufutsu field and the offshore wells are likely to be due to facies variations in source organic matter, resulting from differences in the quantity and quality of land plant input.     

THE ORIGIN OF DOLOMITE IN THE ASMARI FORMATION (OLIGOCENE-LOWER MIOCENE), DEZFUL EMBAYMENT, SW IRAN

Dolomitisation is an important factor controlling reservoir quality in the Asmari Formation in many producing fields in SW Iran. Dolostones have higher average porosities than limestones. Petrographic and geochemical studies have been used to determine the causes of Asmari dolomitisation at the Bibi Hakimeh and Marun fields and at the Khaviz anticline. The formation is generally characterized by a large‐scale trend of upward‐decreasing accommodation. Basal strata were deposited under relatively open‐marine, high‐energy conditions, whereas the Middle to Upper Asmari succession was deposited in relatively protected settings with more frequent evidence of exposure and evaporitic conditions. There is a general upward increase in the abundance of both anhydrite (occurring as nodules and cement) and dolomite. Two main types of dolomite fabric are recognised, reflecting the textures of the precursor limestones: (1) finely crystalline pervasive dolomite (commonly <20μ) replacing mud‐rich facies; and (2) combinations of finely crystalline replacive dolomite and surrounding areas of coarser dolomite cement (crystals up to 100μ) in grain‐supported facies. Fluid inclusion data indicate that finely crystalline dolomites formed at low temperatures (ca. <50°C), while the coarser dolomite formed at higher temperatures (50–;140°C). Whole rock‐carbonate oxygen and carbon isotope analyses of pure dolostone samples show no apparent correlation with either depositional or diagenetic textures: δ¹⁸O is generally 0 to 2.7‰ PDB, and δ¹³C is ?1 to 4‰ PDB. The importance of evaporated seawater to Asmari dolomitisation is indicated by the ubiquitous occurrence of felty‐textured anhydrite nodules in dolostone beds and the presence of high‐salinity fluid inclusions in dolomite. The derivation of dolomitising fluids from contemporaneous seawater is supported by the general correspondence between age estimates derived from the strontium isotope composition of anhydrites and dolomites and those derived from stratigraphic considerations. This suggested synsedimentary dolomitisation. Dolomitisation of the upper half of the Asmari Formation may have occurred as a result of two syn‐sedimentary mechanisms: (1) by the reflux of evaporative brines concentrated in shallow lagoons or sabkhas, through immediately underlying strata (mainly during highstands); and (2) by the flushing of platform‐top carbonates by basinal evaporated waters during lowstand/early transgression. Continued dolomitisation during deeper burial is supported by the presence of high‐temperature fluid inclusions and iron‐rich crystal rims. Dolomite within the lower part of the Asmari Formation probably mostly formed during burial as a result of compaction of, and fluid exclusion from, the underlying Pabdeh marls and shales.     

Control of reactive distillation production of high-purity isopropanol

The process characteristics and control strategy of a high-purity IPA reactive distillation column were investigated. A robust nominal operation was found by maintaining an excess of propylene feed to the column and recycling the unreacted propylene to the feed instead of the top stage. Stage temperature and propylene composition with one-to-one relationship with reboiler duty and propylene feed are selected as controlled variables for maintaining bottom purity and feed ratio in the presence of possible measurement bias respectively. High nonlinearity between selected input–output pair was reduced by using variable transformation. Dynamic simulations demonstrated that such a control scheme with nonlinear transformed variable was capable of providing much superior control performance than the one using natural variable.     

Dissociating uncertainty responses and reinforcement signals in the comparative study of uncertainty monitoring.

Although researchers are exploring animals' capacity for monitoring their states of uncertainty, the use of some paradigms allows the criticism that animals map avoidance responses to error-causing stimuli not because of uncertainty monitored but because of feedback signals and stimulus aversion. The authors addressed this criticism with an uncertainty-monitoring task in which participants completed blocks of trials with feedback deferred so that they could not associate reinforcement signals to particular stimuli or stimulus-response pairs. Humans and 1 of 2 monkeys were able to make cognitive, decisional uncertainty responses that were independent of feedback or reinforcement history within a task. This finding unifies the comparative literature on uncertainty monitoring. The dissociation of performance from reinforcement has theoretical implications, and the deferred-feedback technique has many applications. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Strain hardening due to deformation twinning in α-titanium: Mechanisms

Novel experiments were conducted to elucidate the effect of deformation twinning on the mechanical response of high-purity α-titanium deformed at room temperature. Orientation-imaging microscopy (OIM), microhardness, and nanohardness evaluations were employed in conjunction with optical microscopy and quasi-static compression testing to obtain insight into the deformation mechanisms. Hardness measurements revealed that the newly formed deformation twins were harder than the matrix. This observation is perhaps the first experimental evidence for the Basinski mechanism for hardening associated with twinning, arising from the transition of glissile dislocations to a sessile configuration upon the lattice reorientation by twinning shear. This work also provided direct evidence for two competing effects of deformation twinning on the overall stress-strain response: (1) hardening via both a reduction of the effective slip length (Hall-Petch effect) and an increase in the hardness of twinned regions (Basinski mechanism) and (2) softening due to the lattice reorientation of the twinned regions.     

Optimizing the tapping regime on a blast furnace operating at variable speed

The main factors that determine the uniformity with which smelting products are tapped from a blast furnace are the rate of accumulation of the products in the hearth and the tapping rate. The first parameter is in turn determined by the stability of the furnace’s operation and can vary significantly even over the course of 24 h. The second parameter is determined mainly by the condition of the iron notch, the maintenance it receives, any changes that occur in the diameter of the channel of the notch, and the quality of the materials used to form the notch. Recommendations are presented to optimize tapping of the smelting products.     

Recent-onset ecstasy use: Association with deviant behaviors and psychiatric comorbidity.

Background: Despite increases in ecstasy (MDMA) use in the United States, little is known about characteristics linked with recent-onset ecstasy use, especially psychiatric symptoms and deviant behaviors. Aims: To test whether individuals with high levels of other drug use are more likely to be recent-onset ecstasy users; to test whether psychiatric symptoms in adults are associated with recent-onset ecstasy use; to explore the association between recent-onset ecstasy use and concomitant deviant behaviors in adolescents and adults. Methods: Data from the 2001 National Survey on Drug Use and Health. Findings: Recent-onset ecstasy use was significantly more likely to occur among adolescents and adults (18-34 years old) who engaged in deviant behaviors during the past year as compared with those who did not engage in deviant behaviors during the past year. Higher levels of deviancy indicated a higher likelihood of being a recent-onset ecstasy user, and associations were strongest with nonviolent deviant behaviors such as selling illegal drugs and stealing. Associations between deviant behaviors and recent-onset ecstasy use were similar in strength to associations between deviant behaviors and recent-onset cocaine and marijuana use, respectively. Adults who had past-year psychiatric symptoms (both depressive and panic symptoms) were twice as likely to be recent-onset ecstasy users as compared with those without past-year psychiatric symptoms. Greater levels of drug involvement increased the odds of being a recent-onset ecstasy user. Conclusion: Recent-onset ecstasy use seems to be associated with a range of other behavioral problems and may reflect one aspect of a larger problem behavior syndrome. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Volumetric out-of-furnace heat treatment of 3600-M3 decomposers

Specifications require that all the welds in 12-m-diam. decomposers with a capacity of 3600 m³ be subjected to high-temperature tempering before going into service in order to alleviate the stresses from the welding operation. Specialists at the organizations VNIIPTkhimnefteapparatury and VNIImontazhspetsstroi have proposed out-of-furnace volumetric (complete) of the assembled decomposer with the use of special heaters. The use of this heating method has shortened assembly operations while providing the welds with a highquality heat treatment and reducing the stresses overall (including welding stresses, stresses from assembly of the decomposer, etc.) The technology ensures uniform heating of the housing of the decomposer and provides for close control over the process. The experience gained in heat-treating decomposers can also be used in the construction of other containers that come into contact with corrosive media. __________ Translated from Metallurg, No. 3, pp. 61–64, March, 2006.     

Atomistic simulations of grain boundary migration in copper

While the motion of twist boundaries can be readily studied by atomistic simulations with molecular dynamics (MD) under the action of an elastic driving force, the approach fails for tilt boundaries. This is due to the interaction of the elastic stress with the grain boundary (GB) structure, which causes plastic strain by GB sliding. A novel concept, the orientation correlated driving force, is introduced to circumvent this problem. It is shown that this concept can be successfully applied to the study of the migration of tilt boundaries. The migration behavior of several twist and tilt GBs was investigated. The transition from low-to high-angle boundaries can be captured, and a structural transition of tilt boundaries was found at high temperatures, which also affected the migration behavior. The results compare well with experimental results of the motion high-angle boundaries, but for low-angle boundaries, the agreement is poor. This article is based on a presentation made in the “Hillert Symposium on Thermodynamics & Kinetics of Migrating Interfaces in Steels and Other Complex Alloys,” December 2–3, 2004, organized by The Royal Institute of Technology in Stockholm, Sweden.     

OFDM peak power reduction with simple amplitude predistortion

In this paper, we propose a new peak-to-average power ratio (PAPR) reduction algorithm for OFDM transmission. The algorithm is based on simple amplitude predistortion of a subset of the input symbol blocks, the predistorted symbols being selected according to a metric which measures their contribution to the output signal samples of large. magnitude. This metric-based algorithm is simple, highly flexible, and can be implemented as a one-shot process, although its performance can be further improved by iterating the process one or more times.