A quarter century of wine pigment discovery

The red grape berry pigments, anthocyanins, were characterized in the early 20th century, but investigations of wine pigments were stymied during that era. The question of their identity was a major challenge for wine chemists. A number of techniques showed that the pigments were polymeric in nature. Some structures were postulated by mid-century based on reactions between anthocyanins and condensed tannin, and later postulated wine pigments were observed in model reactions. Some related compounds were then observed in wine. By the end of the 20th century, the ionization of non-volatiles for mass spectrometry opened the door to these compounds. In addition, a new class of compounds was observed, the pyranoanthocyanins, a product of fermentation and aging metabolites with anthocyanins. These compounds possess the pigment stability to SO₂ and pH change that is characteristic of aged red wine. Aging experiments show a dynamic situation with shifts in the population of pigment classes over time. The very large number of diverse pigments explains why it has been so difficult to answer the century-old question of the structure of wine pigments. Our current understanding is founded on the use of mass spectral analysis using electrospray and related ionization techniques over the last 25 years. Future progress will rely on more sophisticated analysis of this very complex mixture of substances. © 2019 Society of Chemical Industry     

Ni,Cr, and Fe surfaces corroded by molten ZnCl2

Understanding the corrosion of molten ZnCl₂ on metal surfaces is significant for the corrosion protection of metals, sustainable use of molten salts, preparation of ZnO coatings, and so on. In this paper, surfaces of pure Ni, Cr, and Fe corroded by molten ZnCl₂ were investigated. The results show that Ni suffered very slight corrosion, while Cr experienced more serious corrosion than Ni, but lighter corrosion than Fe. The morphology of the corrosion of Cr and Fe, respectively, presented pitting and intergranular corrosion characteristics. Furthermore, nanostructured ZnO coatings were obtained on the surfaces of Ni and Fe, but not on the surface of Cr. The ZnO coating on the Ni surface was doped with a small amount of Zn₅(OH)₈Cl₂, and the ZnO coating on the Fe surface was doped with ZnFe₂O₄ and Zn₂OCl₂. The coatings on the Ni and Fe surfaces had an average thickness of 1.5 and 50 μm, respectively.     

面源红外诱饵对抗红外制导导弹干扰策略研究

面源红外诱饵使用的过程中,合理有效的干扰策略是干扰红外制导导弹的关键,针对这一问题,通过理论分析与仿真模拟相结合得到面源红外诱饵对抗红外制导导弹的干扰策略。首先以红外成像制导导弹为例,介绍红外制导导弹的仿真模型,然后将攻击过程分为锁定前与锁定后,以命中率为评价指标,得到两个阶段下的最佳干扰策略,包括诱饵的最佳释放时机、释放间隔以及载机应采取的机动动作等。     

铝合金热轧板锭熔铸技术及设备

本文概述了近年来铝合金热轧板锭的熔铸设备和熔铸技术的发展和最新成就，重点介绍晶粒细化、熔体净化、检测及铸造新技术，为国内铝板带企业跟踪国际铝合金板锭熔铸技术、开展技术攻关和进行技术创新提供有益的参考。     

四川盆地上三叠统划分对比研究

四川盆地上三叠统对比长期存在混乱，给盆地整体评价带来困难。通过岩石地层、地震地层、事件地层及高分辨率旋回地层等多种方法讨论了须家河组与香溪群各岩性段的对比关系，得出了全盆地上三叠统的对比关系；指出须四段底可近似看成等时界面；须家河组下部地层自西向东、向南逐层超覆在雷口坡组之上，上部地层在盆地西北部自东南向西北方向剥蚀层位渐次变老。文章建议四川盆地上三叠统废除“香溪群”，统一使用“须家河组”，以利于对全盆地上三叠统进行油气资源整体评价与深化研究。     

扭臂式静电微驱动器的pulli-n现象分析

从扭臂式微驱动器模型出发,分析了器件在静电驱动条件下pulli-n现象的产生条件,并给出公式化结果。讨论了器件的几何结构参数对于pulli-n现象的影响,并对具体结构的器件给出了pulli-n角度和pulli-n电压等方面的分析结果。对于特定的扭臂结构,pulli-n角度为悬臂梁最大扭转角度的44.04%,且与扭臂的结构参数无关。     

基于ASP.NET技术的新闻发布系统的设计与实现

完整描述了一种在部队师旅级单位通用的新闻发布系统。首先根据用户的特点,对系统进行了需求分析与功能模块划分,然后在此基础上从系统架构、系统流程和数据库设计等3个方面阐述了系统设计中的关键点,并以设计用户登录界面为例写出了部分功能的实现程序,最后对其在中小型企业建站中的应用进行了展望。     

纳米AlN粉末的制备与烧结

利用低温燃烧合成前驱物制备出平均粒度为100 nm的AlN陶瓷粉末,比较了该粉末的常压烧结和放电等离子烧结的特性.实验表明:以合成的AlN粉末为原料,添加5%(质量比)Y2O3作为烧结助剂,在常压、流动N2气氛下1600℃保温3 h,制备出平均晶粒尺寸为4～8 μm、密度为3.28 g·cm-3的AlN陶瓷;将同样的粉末不加任何烧结助剂,采用SPS技术在1600℃保温4 min,得到密度为3.26 g·cm-3的AlN陶瓷,晶粒度约为1～2μm.     

一种压力容器设计的优化方法

当压力容器内体积一定时,利用给出的内体积公式,在一定范围内改变壳体内径及筒体长度(筒体与两封头焊缝间距离),按照GB 150-1998《钢制压力容器》有关规定可得到壳体壁厚一定但内径和筒体长度不同时相应的壳体质量。根据壳体质量的大小并综合考虑其它因素,是选择最佳设计方案的有效途径。     

Study on Hydrocracking of VGO Derived from Kazakhstan-Russian Mixed Crude

1 Introduction With the successful completion of the construction of the China-Kazakhstan oil pipeline the refinery at Dushanzi Pet- rochemical Company will process the Kazakhstan-Russian mixed crude at full steam starting 2007. The high sulfur, nitro- gen and heavy metals contents in the Kazakhstan-Russian mixed crude would have a serious impact on the secondary processing units of the Dushanzi refinery, in particular on the distillate hydrocracking unit, which mainly operates on vacuum g…