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1.
D. A. Mirzaev N. I. Vorob’ev O. K. Tokovi D. V. Shaburov E. A. Fominykh 《Russian Metallurgy (Metally)》2006,(1):38-41
The solutions to a differential equation for the problem of heating of a cylinder in a medium with a fixed temperature are used to obtain equations for estimating the change in the hydrogen concentration in forgings from data on the hydrogen concentration at the cylinder axis or on the average bulk hydrogen concentration. Similar equations are also obtained for forgings having square cross sections. The calculation demonstrates that, for the case of a twofold decrease in the hydrogen concentration in a forging, the calculated times of annealing of a cylindrical forging differ by three times. 相似文献
2.
P. B. Lovyrev A. I. Lavrov V. A. Babkin A. N. Aminov S. M. Melekhin Yu. P. Kazantsev P. M. Korol’kov 《Metallurgist》2006,50(3-4):152-157
Specifications require that all the welds in 12-m-diam. decomposers with a capacity of 3600 m3 be subjected to high-temperature tempering before going into service in order to alleviate the stresses from the welding
operation. Specialists at the organizations VNIIPTkhimnefteapparatury and VNIImontazhspetsstroi have proposed out-of-furnace
volumetric (complete) of the assembled decomposer with the use of special heaters. The use of this heating method has shortened
assembly operations while providing the welds with a highquality heat treatment and reducing the stresses overall (including
welding stresses, stresses from assembly of the decomposer, etc.) The technology ensures uniform heating of the housing of
the decomposer and provides for close control over the process. The experience gained in heat-treating decomposers can also
be used in the construction of other containers that come into contact with corrosive media.
__________
Translated from Metallurg, No. 3, pp. 61–64, March, 2006. 相似文献
3.
Polycrystalline Cu(In,Ga)Se2 (CIGS) films with various ratios of Cu, In, and Ga were grown by codeposition of all elements in vacuum. The X-ray diffraction
study showed that the films are single-phase and possess a chalcopyrite structure with predominant [112] orientation. The
films exhibited a mirror smooth surface and had a close-packed structure composed of crystallites with clear faceting and
a transverse size of 0.1–0.3 μm. Related surface barrier structures of the (In,Ag)/Cu(In,Ga)Se2 type were obtained and their spectra of the quantum efficiency of photoconversion were studied. The obtained structures can
be used for optimization of the CIGS film technology. 相似文献
4.
The state of the surface of n-GaAs crystals upon high-vacuum microwave plasmachemical (HVMWPC) etching in various gas mixtures and the influence of the semiconductor surface condition on the photoelectric characteristics of related metal-semiconductor-metal structures with double Schottky barrier (MSMDSB structures) are investigated. Dependence of the HVMWPC etching rate of the GaAs surface on the gas mixture composition and substrate temperature is determined. It is shown that the HVMWPC etching regime strongly influences the photoelectric properties of MSMDSB structures: the treatment can lead to either growth or drop in photosensitivity of the samples. Optimum etching regimes are established for which good semiconductor surface quality and high photosensitivity of the MSMDSB structures are retained at a high etching rate. 相似文献
5.
N. A. Sivov A. I. Martynenko G. N. Bondarenko M. P. Filatova E. Yu. Kabanova N. I. Popova A. N. Sivov E. B. Kruts’ko 《Petroleum Chemistry》2006,46(1):41-59
Structures and compositions of the monomers guanidine acrylate and guanidine methacrylate, their homopolymers, and copolymers with diallyldimethylammonium chloride enriched in acrylate comonomer units were determined. It was shown that ampholytic copolymers, owing to their ionic nature, contained comonomeric guanidine acrylate or methacrylate units and diallyldimethylammonium chloride units, as well as the acrylate comonomer with the diallyl counterion and polymeric acrylate and diallyl ion pairs. It follows from IR and 1H NMR data that guanidine methacrylate has the same structure (with two hydrogen bonds) in the solid state and in solutions. Guanidine acrylate structures in the solid state and in dimethylsulfoxide are identical and analogous to guanidine methacrylate structure in this solvent. In water, the guanidine acrylate structure has another type of hydrogen bonding (with one hydrogen bond, where the proton is shifted toward the guanidine group). These features of hydrogen bonding of guanidine acrylate and guanidine methacrylate are also retained in their homopolymers and copolymers with diallyldimethylammonium chloride. It was shown that the thermal stability of the copolymers was higher than that of their homopolymers, confirming the formation of intramolecular ion pairs of oppositely charged units of ampholytic copolymers. Moreover, the thermal stability of guanidine methacrylate-diallyldimethylammonium chloride copolymers is higher than that of guanidine acrylate-diallyldimethylammonium chloride copolymers. 相似文献
6.
A. M. Kut’in V. S. Polyakov M. F. Churbanov G. E. Snopatin 《Inorganic Materials》2007,43(9):1018-1023
Using a flow method, we have measured the vapor pressure of tellurium tetraiodide, an attractive reagent for chemical vapor deposition technology. The results, combined with earlier tensimetric data, have been used to evaluate the basic thermodynamic functions of TeI4 and its thermolysis products. 相似文献
7.
A. D. Pogrebnyak M. V. Il’yashenko V. S. Kshnyakin V. V. Ponaryadov Sh. M. Ruzimov Yu. N. Tyurin 《Technical Physics Letters》2003,29(12):1028-1030
Chromium carbide-nickel coatings were deposited onto a technical grade copper substrate by means of a high-velocity plasma
jet of a plasmatron operating in specially selected regimes. An analysis of the coatings showed evidence of the formation
of a Ni-based solid solution, a complex chromium carbide (Cr7C3), and an fcc crystal phase with a lattice parameter of 3.614 Å. The surface of the coatings exhibits a characteristic relief
resulting from a dynamic interaction between melted and fused particles of the initial powder. The local hardness on some
areas of the surface and in depth of the coating reaches 66±4.5 HRC, while the coating adhesion strength varies from 25 to
300 MPa. 相似文献
8.
I. A. Ovid’ko 《Journal of Materials Science》2007,42(5):1694-1708
An overview of experimental study, computer simulations and theoretical models of fracture of nanocrystalline materials is
presented. The key experimentally detected facts on ductile and brittle fracture processes are discussed. Special attention
is paid to computer simulations and theoretical models of nucleation and growth of nanocracks and nanopores in deformed nanocrystalline
materials. Also, we discuss mechanisms for fracture suppression in such materials showing good ductility or superplasticity. 相似文献
9.
Carbon Black (CB)-containing immiscible polymer blends based on high-impact polystyrene/thermoplastic polyurethane (HIPS/TPU) were studied as sensing materials for an homologous series of alcohols, including, methanol, ethanol and 1-propanol. The studied immiscible blend was designed to exhibit a double-continuity structure i.e., the CB particles form chain-like network structures within the TPU phase, which forms a continuous phase within the HIPS matrix. Extruded HIPS/TPU/CB filaments produced by a capillary rheometer process at various shear rate levels were used for the sensing experiments. All filaments displayed a selective resistance changes upon exposure to the various alcohols combined with reproducibility and recovery behaviour. An attempt is made to identify the dominant mechanisms controlling the sensing process in a CB-containing immiscible polymer blend characterized by a double-continuity structure. The distinct structure and composition of the HIPS/TPU interphase region were found to have a crucial role in the sensing mechanism, determining the selectivity of the filaments toward the studied alcohols. Additionally, the sensing performance of HIPS/TPU/CB system is compared to recent results for TPU/CB compounds, polypropylene/TPU/CB and HIPS/ethylene vinyl acetate/CB immiscible polymer blends. 相似文献
10.
V. N. Perevezentsev M. Yu. Shcherban’ M. Yu. Murashkin R. Z. Valiev 《Technical Physics Letters》2007,33(8):648-650
The structure and mechanical properties of nanocrystalline aluminum alloy 1570 obtained by means of severe plastic deformation have been studied. Being tested in a temperature range from 300 to 400°C, the alloy exhibits high-strain-rate superplasticity. At 400°C, the superplasticity is manifested in a very broad range of strain rates, extending from 5 × 10?3 to 1 s?1. 相似文献