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101.
Takeru Inoue Hiroaki Iwashita Jun Kawahara Shin-ichi Minato 《International Journal on Software Tools for Technology Transfer (STTT)》2016,18(1):57-66
Several graph libraries have been developed in the past few decades, and they were basically designed to work with a few graphs. However, there are many problems in which we have to consider all subgraphs satisfying certain constraints on a given graph. Since the number of subgraphs can increase exponentially with the graph size, explicitly representing these sets is infeasible. Hence, libraries concerned with efficiently representing a single graph instance are not suitable for such problems. In this paper, we develop Graphillion, a software library for very large sets of (vertex-)labeled graphs, based on zero-suppressed binary decision diagrams. Graphillion is not based on a traditional representation of graphs. Instead, a graph set is simply regarded as a “set of edge sets” ignoring vertices, which allows us to employ powerful tools of a “family of sets” (a set of sets) and permits large graph sets to be handled efficiently. We also utilize advanced graph enumeration algorithms, which enable the simple family tools to understand the graph structure. Graphillion is implemented as a Python library to encourage easy development of its applications, without introducing significant performance overheads. In experiments, we consider two case studies, a puzzle solver and a power network optimizer, in which several operations and heavy optimization have to be performed over very large sets of constrained graphs (i.e., cycles or forests with complicated conditions). The results show that Graphillion allows us to manage a huge number of graphs with very low development effort. 相似文献
102.
Yuichi Sawai Yuji Iwamoto Sachiko Okuzaki Yoshiyuki Yasutomi Koichi Kikuta Shin-ichi Hirano 《Journal of the American Ceramic Society》1999,82(8):2121-2125
A chemically modified polycarbosilane (PC) containing organofluoric groups (PCOCF) has been synthesized from PC and fluoroalkylmethyldimethoxysilane. PCOCF acts as an efficient compaction binder for SiC powders and as a coating material with excellent oxidation resistance in wet air. PCOCF-coated SiC powders also show excellent packing properties because of the organofluoric side chains, which give highly dense green compacts. PCOCF provides a high ceramic yield of 75% and highly dense SiC ceramics. Four-point bending strength increases and the scatter in strength values decreases significantly by PCOCF coating. 相似文献
103.
104.
Teruo Matsushita Shin-ichi Inoue Ryusuke Tanaka 《Journal of the American Oil Chemists' Society》2010,87(9):963-972
A method for the determination of the total lipid content in fish meat was established using a 2-thiobarbituric acid (TBA) reaction, which had previously been used for the determination of lipid peroxides in animal tissues. In this method, an unspecific peroxidation of fish oils was created by omitting the addition of antioxidant to the reaction mixture during the TBA reaction, because fish meat is more sensitive to the TBA reaction due to its higher concentration of polyunsaturated fatty acids, especially docosahexaenoic acid and eicosapentaenoic acid, which can easily react artificially with TBA in the absence of an antioxidant in the assay system. As for a practical application of this method, we tried to optimize the assay procedures in the sampling, reaction, and detection steps of this method, and finally proposed a new standard procedure recommended for determining the total lipid content of fish using a TBA reaction. In order to confirm the accuracy of the new procedure, comparative evaluations for the lipid contents of commercially available fish, i.e., chub mackerel (Scomber japonicus) and saury (Cololabis saira) were made between the conventional procedure and the recommended TBA method. The lipid contents obtained by the two methods coincided well with high correlation. This method is relevant for total lipid content analysis of fish meat under restricted laboratory conditions. 相似文献
105.
Yoshiro Tahara Satoshi Kosuge Shin-ichi Sawada Yoshihiro Sasaki Kazunari Akiyoshi 《Reactive and Functional Polymers》2013,73(7):958-964
Polysaccharide nanogels are one of the most attractive carriers for drug delivery systems. Nanogels encapsulate proteins in their hydrated polymer networks, and minimize the denaturation of proteins. In this study, we demonstrated the cross-linking of acryloyl group-modified polysaccharide nanogels via photopolymerization, which allowed the formation of novel hydrogel particles and macrogels. The mechanical properties of the resultant hydrogels depended on the concentrations of the nanogels and the cross-linkers. The most significant property of the nanogel-cross-linked hydrogel was the ability to encapsulate insulin via hydrophobic interactions. After incubation of the hydrogel containing insulin in water, the hydrogel was degraded by hydrolysis, and insulin was gradually released from the hydrogels over a period of 1 week. According to these results, this nanogel-cross-linked hydrogel prepared via photopolymerization has potential for innovative biomaterials. 相似文献
106.
Yu-Wei Wang Shin-ichi Sasaki Taojun Zhuang Hitoshi Tamiaki Jian-Ping Zhang Toshitaka Ikeuchi Ziruo Hong Junji Kido Xiao-Feng Wang 《Organic Electronics》2013,14(8):1972-1979
Two ambipolar chlorophyll derivatives, namely, 32,32-dicyano-pyropheophorbide-a (Chl-1) and methyl 131-deoxo-131-(dicyanomethylene) pyropheophorbide-a (Chl-2), were synthesized for use as either the electron acceptor or the electron donor in organic planar-heterojunction solar cells. Despite the higher electron mobilities of these chlorophyll derivatives compared with their hole mobilities, devices using them as the electron donor with fullerene C70 give much better photovoltaic performance than when they are used as the electron acceptor with copper phthalocyanine. In these Chl-based solar cells, the energy gap between the LUMO levels of the donor and acceptor molecules substantially affects the charge separation and resultant photocurrent and photovoltaic performance. The highest solar energy-to-electricity conversion efficiency of up to 2.3% has been achieved using the Chl-2/C70 solar cell, under AM1.5 solar illumination (100 mW/cm2) after thermal annealing of the device. It was also confirmed that the electron mobility of blend films containing Chls and fullerene derivative PC70BM was determined not only by the electron mobility of PC70BM but also by that of Chls. 相似文献
107.
Shunji Imai Yasuo Yoshioka Yuki Morishita Tokuyuki Yoshida Miyuki Uji Kazuya Nagano Yohei Mukai Haruhiko Kamada Shin-ichi Tsunoda Kazuma Higashisaka Yasuo Tsutsumi 《Nanoscale research letters》2014,9(1):651
Because of their useful chemical and physical properties, nanomaterials are widely used around the world - for example, as additives in food and medicines - and such uses are expected to become more prevalent in the future. Therefore, collecting information about the effects of nanomaterials on metabolic enzymes is important. Here, we examined the effects of amorphous silica particles with various sizes and surface modifications on cytochrome P450 3A4 (CYP3A4) activity by means of two different in vitro assays. Silica nanoparticles with diameters of 30 and 70 nm (nSP30 and nSP70, respectively) tended to inhibit CYP3A4 activity in human liver microsomes (HLMs), but the inhibitory activity of both types of nanoparticles was decreased by carboxyl modification. In contrast, amine-modified nSP70 activated CYP3A4 activity. In HepG2 cells, nSP30 inhibited CYP3A4 activity more strongly than the larger silica particles did. Taken together, these results suggest that the size and surface characteristics of the silica particles determined their effects on CYP3A4 activity and that it may be possible to develop silica particles that do not have undesirable effects on metabolic enzymes by altering their size and surface characteristics. 相似文献
108.
Motoki Nakajima Shin-ichi Komazaki Yutaka Kohno 《Transactions of the Indian Institute of Metals》2010,63(2-3):473-477
The instrumented indentation test was applied to the interrupted creep specimens of turbine rotor steel (Fe-10Cr-1Mo-1W-VNbN) to investigate the changes in contributions of matrix and block boundary strengths to macroscopic hardness during creep. The indentation tests were performed under the loads of 1 and 10 mN to determine the matrix strength and the block boundary strength, respectively. The matrix strength of the grip portion decreased gradually with increasing life fraction and, for the gauge portion, the decrease was more pronounced, particularly, at the latter half of the life. On the other hand, the experimental results revealed that the block boundary strength decreased significantly at the early stage of the creep life, but this decrease was no longer pronounced when the creep life fraction exceeded 20%. Additionally, there was a good correlation between the block boundary strength and the width of block boundary carbide and the carbide coarsening was considered to be closely associated with the decrease in block boundary strength. 相似文献
109.
The vinylidene structures in polypropylenes produced by ethylenebis(indenyl)zirconiumdichloride (En(Ind)2ZrCl2), 1, and isopropyl(cyclopentadienyl)(fluorenyl)zirconiumdichloride (iPr(Cp)(Flu)ZrCl2), 2, were analyzed by 1H NMR. The vinylidene group adjacent to the chain end was clearly distinguished from other internal vinylidene structures for the first time using 1,2-dichlorobenzene as solvent. The polypropylene produced by 2 had much internal vinylidene groups compared with one by 1. 相似文献
110.
Hasegawa T Matsumoto L Kitamura S Amino S Katada S Nishijo J 《Analytical chemistry》2002,74(23):6049-6054
A novel measurement technique of pure out-of-plane vibrational modes of thin films on a nonmetallic substrate has recently been proposed, which is named multiple-angle incidence resolution spectrometry (MAIRS). Since this technique could not be replaced by other conventional techniques, MAIRS was expected to be a promising tool for analysis of thin soft materials and surface adsorbates. Nevertheless, some experimental conditions have been found to be inappropriate for MAIRS, which yields incorrect results. In the present study, therefore, the problems in the technique have been investigated in terms of optics to improve the accomplishments of MAIRS. The problems have been found to have a strong relationship with optics in FT-IR, which is influenced by refractive index of the sample material and angle of incidence. In particular, optimization of the size matching of the detector surface and the infrared spot at the detector was a key to having MAIRS perform properly. It has been concluded that reliable MAIRS measurements require overfilling of the detector and a substrate with a high-refractive index. 相似文献