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81.
This paper presents a method that can estimate the critical power of boiling water reactors, BWRs, with regard to spacer geometry. The current experimental method for estimating the critical power for BWR design requires many trained experts and expensive facilities to conduct the experiments. In the present method, the liquid film flow rate of adiabatic gas‐liquid two‐phase flow and a subchannel analysis of the actual BWR flow condition are measured experimentally and analyzed. In the experiment, deposition enhancement coefficients of three spacer geometries—a ferrule, an egg‐crate, and a ferrule spacer with twisted tape (CYCLONE spacer)—were estimated by measuring the liquid film flow rate of air‐water two‐phase flow flowing up in a vertical square (4 × 4) rod bundle that simulated the rod bundle of a BWR. Using these coefficients, the critical powers for bundles using each type of spacer geometry were calculated in the subchannel analysis. This method was validated using previous critical power data in the actual BWR flow condition. The critical powers predicted by this method agreed well with those of the experimental data. The result confirmed the effectiveness of this experiment‐simulation combined method, as well as the advantage over current experimental methods in terms of human and facility costs. © 2005 Wiley Periodicals, Inc. Heat Trans Asian Res, 34(5): 309–323, 2005; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.20069 相似文献
82.
Micro-flowers of poly(p-phenylene pyromelliteimide) crystals 总被引:1,自引:0,他引:1
Morphology control of poly(p-phenylene pyromelliteimide) (PPPI) crystals was examined using reaction-induced crystallization of oligomers during solution polymerization of self-polymerizable N-(4′-aminophenyl)-3-carboxyl-4-alkoxycarbonylphthalimide. Micro-flowers of the PPPI needle-like crystals were formed in which the needle-like crystals grew radially from the center part as petals. The molecules aligned regularly along the long axis of the needle-like crystal. The structure of alkoxy group in the monomer and the monomer concentration influenced the size of the needle-like crystals, and their average length and width were changeable from 640 nm to 1.69 μm and from 110 nm to 210 nm, respectively. The average thickness was 20 nm. The obtained micro-flowers possessed high crystallinity and exhibited excellent thermal stability. 相似文献
83.
84.
Shinichi Kitade Kazuo Asuka Isamu Akiba Yusuke Sanada Kazuo Sakurai Hiroyasu Masunaga 《Polymer》2013,54(1):246-257
Shear-induced crystallization of a long chain hyper-branched polypropylene (LCB-PP, denoted PP-3) was carried out at a relatively high temperature of 170 °C, close to its melting temperature of 158 °C. Small-angle X-ray scattering (SAXS) showed that the intensity ratio of the normal to the perpendicular to the shear (V/H) was always larger than 1 for PP-3, indicating that shish-like structures were predominately formed and further growth to kebab was suppressed in PP-3. The crystallization behavior of PP-3 can be explained by the nature of PP-3 that there were a large amount of crystallization nuclei due to their branching points, and the point-like precursors formed from these nuclei were arrayed linearly along the shear direction and transformed into thread-like precursors or premature shishs; however, owing to the large amount of branching, further progress in crystallization was suppressed. 相似文献
85.
86.
Yoshiyuki Sakamoto Hitoshi Kumagai Shinichi Matsunaga 《Journal of Applied Electrochemistry》2013,43(9):967-973
A novel electrochemical ionic liquid membrane reactor capable of separating NO from a mixture of NO and oxygen with high current efficiency at low temperatures was designed and tested. This reactor consists of a combination of an ionic liquid and a thin film of anodised alumina with two platinum electrodes. During operation of the reactor, NO is electrically transported from the cathode side to the anode side. 相似文献
87.
Effect of silver content on thermal fatigue life of Sn-xAg-0.5Cu flip-chip interconnects 总被引:5,自引:0,他引:5
Shinichi Terashima Yoshiharu Kariya Takuya Hosoi Masamoto Tanaka 《Journal of Electronic Materials》2003,32(12):1527-1533
The thermal fatigue properties of Sn-xAg-0.5Cu (x=1, 2, 3, and 4 in mass%) flip-chip interconnects were investigated to study
the effect of silver content on thermal fatigue endurance. The solder joints with lower silver context (x=1 and 2) had a greater
failure rate compared to those with higher silver content (x=3 and 4) in thermal fatigue testing. Cracks developed in the
solders near the solder/chip interface for all joints tested. This crack propagation may be mainly governed by the nature
of the solders themselves because the strain-concentrated area was similar for tested alloys independent of the silver content.
From the microstructural observation, the fracture was a mixed mode, transgranular and intergranular, independent of the silver
content. Higher silver content alloys (x=3 and 4) had finer Sn grains before thermal cycling according to the dispersion of
the Ag3Sn intermetallic compound, and even after the cycling, they suppressed microstructural coarsening, which degrades the fatigue
resistance. The fatigue endurance of the solder joints was strongly correlated to the silver content, and solder joints with
higher silver content had better fatigue resistance. 相似文献
88.
Shunji Yunoki Toshiyuki Ikoma Akira Monkawa Kazushi Ohta Junzo Tanaka Shinichi Sotome Kenichi Shinomiya 《Journal of the American Ceramic Society》2006,89(9):2977-2979
Gamma irradiation treatment (GIT) is the most widely used sterilization method for biomaterials in spite of the potential to degrade polymers. The adverse effects of GIT on the mechanical properties and biological stabilities of porous hydroxyapatite/collagen (HAp/Col) composites were investigated in this study. Those properties of a porous HAp/Col composite stabilized by dehydrothermal treatment (DHT) drastically decreased by GIT in the same manner as conventional pure Col materials. DHT after GIT could partially eliminate the adverse effects, due to the introduction of cross-linkage among the degraded Col molecules. 相似文献
89.
H. Adachi S. Kamiyama I. Kidoguchi T. Uenoyama 《Photonics Technology Letters, IEEE》1995,7(12):1406-1408
650-nm band self-sustained-pulsing AlGaInP laser diodes having very low intensity noise characteristics were successfully demonstrated by adopting novel structure, which has highly doped saturable absorbing layer for the first time. Short carrier lifetime, which is indispensable for self-sustained pulsation, was realized by applying high doping to the absorbing layer. 500-/spl mu/m-long devices with the lasing wavelength of 656 mm were fabricated, resulting in the threshold current of 65 mA at room temperature. The relative intensity noise (RIN) was below -138 dB/Hz in the temperature ranging from 20-50/spl deg/C at 5 mW. 相似文献
90.
Thermal properties by DSC, stiffness, melt viscosity, tensile properties, and dynamic mechanical properties were measured for the Na+, K+, Mg2+, Zn2+, Cu2+, Mn2+, and Co2+ salts of poly(ethylene-co-methacrylic acid) (EMAA). The changes in the structure and properties with increasing neutralization are larger in the alkaline and alkaline earth metal salts than in the transition metal salts. The stiffness shows a maximum at 33% neutralization in both the alkaline and alkaline earth metal salts, while no maxima are found up to 60% neutralization in the transition metal salts. The microphase separation of salt group aggregates is observed in both the alkaline and alkaline earth metal salts, but is not seen in the transition metal salts. These differences were attributed to both the stronger ionic interactions and the larger number of carboxyl groups associated with the alkaline and alkaline earth metal salts in the ordered structure of ionic salt groups (ionic crystallites). The mechanical properties measured at low strain, such as stiffness and yield stress, strongly depend on the degree of the crystalline order of the ionic crystallites. The high-strain properties, such as tensile strength and elongation at break, depend on the strength of the ionic interactions and the valence of the cation. 相似文献