Gewinnung von Öl durch Schwelen von Ölschiefer und Teersand als Beitrag zur Energieversorgung

The contribution to energy supply of oil recovered by distillation of oil shale and tar sands . Following a world-wide survey of the most important deposits of oil shale and tar sands, the current activities in the USSR, China and Canada in the field of the industrial recovery of shale oil and bitumen from tar sand are described in broad terms. Thereafter, the current large-scale projects for the production of synthesis oil from these feedstocks are dealt with. The operating method and development status of modern processes for distilling oil shale are covered, as is the working principle of the hot water extraction of tar sand which is already commercially in application. The LR-Process method of operation and its especial feature of circulating the distilled residue as solid heat carrier are discussed in more detail. This is followed by information on the throughput potential of this process. The characteristic reactions influencing the quality of the LR products (oil, gas, residue, flue gas) are handled. Typical quality data for oil and gas obtained from oil shale and tar sands are given. A route is indicated for further processing of the condensate streams from the Lurgi-Ruhrgas Process. This consists of precipitation of solids, distillative separations and one hydrogenation step for the naphtha and oil fraction. These process steps produce a ?syncrude”? which can be further processed together with crude oil in conventional refineries. Examples are given for the independent further processing of syncrude to end-products customary on the market.     

基于动态Copula的风光联合出力建模及动态相关性分析

准确描述风力发电和光伏发电的动态相关性及联合出力的波动性,对风光互补系统的出力预测和经济调度具有重要意义。针对现行静态相关系数无法准确描述风光出力相依关系的问题,研究了风光出力的动态相关性,提出了基于动态Copula函数的风光联合出力模型构建方法。结合实测数据建立了8组动态与静态的风光联合出力Copula模型,用动态相关系数描述风光出力的相关性。运用拟合优度检验方法验证了动态Copula模型对比其静态模型的优越性,选出最优模型。最后将该模型应用在数据驱动的风光联合系统中,验证了其合理性与正确性。     

Degradation of monomethylmercury chloride by hydroxyl radicals in simulated natural waters

The degradation of methylmercury chloride by hydroxyl radicals (*OH) has been investigated using nitrate photolysis from 285 to 800 nm with a 450 W Xenon lamp as the (*OH source. The identified products are Hg(2+), Hg(0), CHCl(3) and formaldehyde. The second-order rate constant at pH of 5 at room temperature was determined to be 9.83(+-0.66)x10(9) M(-1) x s(-1)using benzoic acid as the *OH scavenger. The effects of chloride concentration and methylmercury speciation have also been investigated. A mechanism of the CH(3)HgCl-*OH reaction has been proposed. The calculated methylmercury degradation rates in natural waters using the above rate constant were comparable to the in situ photodegradation rates reported previously, indicating that degradation by (*)OH may be one of the important pathways of methylmercury degradation in sunlit surface waters.     

Finite element analysis of the stability of multilayer elastomeric bearings

The stability of multilayer elastomeric bearings is considered within the framework of two-dimensional finite elasticity. For this purpose, simple constitutive equations which generalize those of a transversally isotropic linear elastic solid are considered. A finite element formulation is discussed which is capable of accounting for very general boundary conditions. For moderate deflections and classical boundary conditions this formulation leads to numerical results in close correspondence with those obtained by Haringx's one-dimensional treatment. It is shown that the presence of boundary conditions in the form of unilateral constraints explains a softening effect which has been experimentally observed during the testing of this type of composite column. Experimental results are also presented which indicate that this softening effect is not produced by a form of material instability. These experimental results provide further justification for the simple constitutive model adopted.     

Probabilistic simulation of cable performance and water based protection in cable tunnel fires

Nuclear power plants contain a significant amount of fire load in form of electrical cables. The performance of the cables is interesting both from the fire development and system failure viewpoints. In this work, cable tunnel fires are studied using numerical simulations, focusing on the fire spreading along power cables and the efficiency of the water suppression in preventing the cable failures. Probabilistic simulations are performed using Monte Carlo technique and the Fire Dynamics Simulator (FDS) as the deterministic fire model. The primary fire load, i.e. the power cables are modelled using the one-dimensional pyrolysis model, for which the material parameters are estimated from the experimental data. Two different water suppression systems are studied. The simulation results indicate that using either suppression system decreased the heat release rate in the tunnel to less than 10% of the non-suppressed case. Without water suppression, the cables of the second sub-system were damaged in almost all fires, but when either of the studied water suppression systems was used, the probability of the cable failures was decreased to less than 1%. This result indicates that in current scenario, the probability of losing both sub-systems is determined directly by the suppression system unavailability.     

Malolactic fermentation in four varieties of sea buckthorn (Hippophaë rhamnoides L.)

Malolactic fermentation (MLF) used in winemaking was applied to four varieties of sea buckthorn (Hippophaë rhamnoides L.). Sensory properties and chemical components of fermented and unfermented juices were studied in order to see whether the MLF can have an effect on sensory quality of sea buckthorn and if there are differences between varieties. The juices were inoculated with unadapted Oenococcus oeni at a cell density of 10⁹ CFU/mL and the fermentation was performed over 18 h at 28 °C. The fermentation decreased sourness and astringency in the samples, and fruity flavor as well as fermented flavor were increased. However, the ML reaction was different between the varieties. The size of the reaction was not proportional to the initial pH or malic acid content of the juice. Larger the ML reaction, more changes were observed in the sensory properties.     

高校课表编排质量问题研究

课表编排是一门学问,是一门艺术．科学地编排课表,对提高教学质量极为有利．从课表编排存在的问题以及课表编排基本流程着手进行分析研究,得出课表编排所需遵循的原则;贯彻课表编排“以人为本”的管理思想;有利于优化学校教学资源、提高教师教学效果及学生的学习效率,实现高校教学管理的“高标准、精细化”．     

Consistent tangent operators for rate-independent elastoplasticity

It is shown that for problems involving rate constitutive equations, such as rate-independent elastoplasticity, the notion of consistency between the tangent (stiffness) operator and the integration algorithm employed in the solution of the incremental problem, plays a crucial role in preserving the quadratic rate of asymptotic convergence of iterative solution schemes based upon Newton's method. Within the framework of closest-point-projection algorithms, a methodology is presented whereby tangent operators consistent with this class of algorithms may be systematically developed. To wit, associative J₂ flow rules with general nonlinear kinematic and isotropic hardening rules, as well as a class of non-associative flow rules are considered. The resulting iterative solution scheme preserves the asymptotic quadratic convergence characteristic of Newton's method, whereas use of the socalled elastoplastic tangent in conjunction with a radial return integration algorithm, a procedure often employed, results in Newton type of algorithms with suboptimal rate of convergence. Application is made to a set of numerical examples which include saturation hardening laws of exponential type.     

On the computational significance of the intermediate configuration and hyperelastic stress relations in finite deformation elastoplasticity

Incremental formulations directly based on an additive decomposition of the rate of deformation tensor, with instantaneous elastic response directly characterized by a rate constitutive equation, have often been regarded as the most convenient ones from a computational standpoint. By contrast, it is shown that a direct characterization of the elastic response in terms of a potential in conjunction with the notion of intermediate configuration provides a simpler and more convenient computational framework. In particular, objective rates play no role, neither in the basic formulation nor in the integration procedure. Within this framework, issues concerning the treatment of volume constraints, the formulation of return mapping algorithms and consistent linearization procedures are addressed.