Asymmetric membrane fiber-based carbon dioxide removal devices for ion chromatography

The application of hollow and filament-filled single asymmetric membrane fibers, consisting of a thin silicone layer on a tubular microporous support, for removing CO(2) in suppressed ion chromatography effluents is described. With appropriate choice of the removal device and operating conditions, the CO(2) can be essentially quantitatively (99+%) removed. For carbonate-based eluents, the use of such devices greatly reduces or eliminates the water dip, permitting better quantitation of poorly retained anions that elute close to the dip, allows practical gradient chromatography, and improves noise levels and attainable detection limits. In hydroxide eluent chromatography, the device largely removes the response from CO(2) present in the samples; this greatly aids atmospheric trace gas analysis by IC. Device dimensions are such that the dispersion introduced by the device is small.     

Gel permeation chromatography for characterization of graft copolymer

Summary The present paper describes the grafting of vinyl monomers onto cellulose nitrate in non-aqueous medium using benzoyl peroxide as a catalyst. The complete separation of the homopolymers and graft copolymer was carried out by selective solvent extraction. The graft copolymer was characterized by IR spectra. The GPC was used as a technique to differentiate between homopolymer, polymer mixture, polyblend, and graft copolymer.     

Evaluating different NDVI composite techniques using NOAA-14 AVHRR data

Normalized Difference Vegetation Index (NDVI) data derived from Advanced Very High Resolution Radiometer (AVHRR) data are influenced by cloud contamination, which is common in individual AVHRR scenes. Maximum value compositing (MVC) of NDVI data has been employed to minimize cloud contamination. Two types of weekly NDVI composites were built for crop seasons in summer: one from all available AVHRR data (named the traditional NDVI composite) and the other from solely cloud-free AVHRR data (named the conditional NDVI composite). The MVC method was applied to both composites. The main objective of this study was to compare the two types of NDVI composites using Texas data. The NDVI seasonal profiles produced from the conditional NDVI composites agreed with the field measured leaf area index (LAI) data, reaching maximum values at similar times. However, the traditional NDVI composites showed irregular patterns, primarily due to cloud contamination. These study results suggest that cloud detection for individual AVHRR scenes should be strongly recommended before producing weekly NDVI composites. Appropriate AVHRR data pre-processing is important for composite products to be used for short-term vegetation condition and biomass studies, where the traditional NDVI composite data do not eliminate cloud-contaminated pixels. In addition, this study showed that atmosphere composition affected near-infrared reflectance more than visible reflectance. The near-infrared reflectance was increasingly adjusted through atmospheric correction.     

Factors affecting bulk to total bacteria ratio in drinking water distribution systems

Bacteria in drinking water systems can grow in bulk water and as biofilms attached to pipe walls, both causing regrowth problems in the distribution system. While studies have focused on evaluating the factors influencing the bacteria in bulk water and in biofilms separately, there is a need for understanding biofilm characteristics relative to the bulk water phase. The current study evaluated the effects of chlorine and residence time on the presence of culturable bacteria in biofilms relative to that in bulk water. The results showed that when no chlorine residual was present in the system, the median ratio of bulk to total bacteria was 0.81, indicating that 81% of the bacteria were present in bulk water, whereas only 19% were present in the biofilm. As chlorine concentration increased to 0.2, 0.5, and 0.7 mg/L, the median percentage of bacteria present in bulk water decreased to 37, 28, and 31, respectively. On the other hand, as the residence times increased to 8.2, 12, 24, and 48h, the median percentage of bacteria present in bulk water increased to 7, 37, 58, and 88, respectively, in the presence of a 0.2mg/L chlorine residual. The common notion that biofilms dominate the distribution system is not true under all conditions. These findings suggest that bulk water bacteria may dominate in portions of a distribution system that have a low chlorine residual.     

Entanglement in two-site Bose–Hubbard model with non-linear dissipation

In this paper, we study the decoherence and entanglement properties for the two-site Bose–Hubbard model in the presence of a non-linear damping. We apply the techniques of thermo field dynamics and then use Hartree-Fock approximation to solve the corresponding master equation. The expectation values of the approximated field operators appearing in the solution of master equation are computed self-consistently. We solve this master equation for a small time t so that we get the analytical solution, thereby we compute the decoherence and entanglement properties of the solution of the two-mode bosonic system. We have found that for a small initial time t, the entanglement of the system increases but at the same time the system decoheres exponentially.     

Preparation of TEM foils from Nb-10 a/o Si.

Ductile phase toughened composites contain phases with significantly different physical properties. Consequently, these phases thin at different rates depending on the sample preparation procedure. A new TEM foil preparation method for the ductile phase toughened Nb-10 a/o Si material has been developed. The method involves chemical thinning in a 70% nitric acid/30% hydrofluoric acid solution followed by electropolishing in a 12.5% sulfuric acid/87.5% methanol electrolyte at -40 degrees C. This procedure for making TEM foils results in large thin areas with the minimum of artifacts. Mechanical grinding of a sample followed by either ion milling, dimpling, or electropolishing produced foils with large electron transparent areas, but with uncharacteristic features of the original Nb-10 a/o Si alloy microstructure. These artifacts were identified as dislocations, surface mottling, and antiphase domains.     

Seasonal performance of a central air conditioner in Dhahran, Saudi Arabia. A computer simulation study

Seasonal performance of four standard, residential-sized, central air conditioners in a typical hot and humid climate of Gulf environment was measured. A computer model was developed to stimulate the residential building cooling loads and the resulting seasonal energy consumption. For an average 100 m² residence located in Dhahran, equipped with a 17.6 kW air conditioner, simulations show a consumption of ≈22200 kWh of electricity for space cooling over 2600 operation hours, this being within 13% of the measured value. The seasonal performance of three lower capacity (10.5, 12.3 and 14.0 kW) air conditioners for the same duty was also predicted. With the 14.0 kW capacity unit the electricity consumption is reduced by ≈ kWh and can satisfy the load for 96.6% of the time. The smallest (10.5kW) of the four systems can supply the house cooling load for only ≈78% of the time with a seasonal energy consumption of 17 350 kWh.     

Studies on the reduction of hematite by carbon

Single pellet experiments have been carried out in a nitrogen atmosphere to study the reduction of hematite by graphite in the temperature range 925 to 1060°C. The effect of variables such as c/Fe₂O₃ molar ratio, pellet size, and so forth, has been investigated. Gas analysis data show a continuous decrease in CO₂/CO ratio during reduction, the values being far away from Fe/FeO equilibrium for wustite reduction by CO. The activation energies associated with different degrees of reduction appear to be widely different suggesting a possible changeover in reaction mechanism during the progress of reduction. X-ray diffraction studies confirm the stepwise nature of hematite reduction. Formerly Research Scholar in the Department of Metallurgy, Indian Institute of Science, Bangalore-560012, India,