Stability of wood fast pyrolysis oil

This study evaluates the effects of storage conditions on physical and chemical properties of biomass fast pyrolysis oils exposed to elevated temperatures over extended periods of time. It was performed on oak pyrolysis oil generated in the NREL vortex reactor. Oil samples were stored at three temperatures: 37, 60 and 90°C in glass vessels. Properties of the oils were measured after hours of storage at 90°C, and after days or weeks at lower temperatures. Chemical changes in the oils were measured using GPC (molecular weight distribution) and FTIR spectroscopy. The oil remained a single phase throughout the studied conditions. Its pH was not affected by storage. The water content, viscosity and molecular weight of the oil increased with the time and temperature of storage. First-order reaction kinetics were successfully used to predict changes in molecular weight of the stored oil. FTIR provided evidence that etherification or esterification are mechanisms for condensation of the oil during storage.     

High‐Efficiency InP‐Based Photocathode for Hydrogen Production by Interface Energetics Design and Photon Management

The solar energy conversion efficiency of photoelectrochemical (PEC) devices is usually limited by poor interface energetics, limiting the onset potential, and light reflection losses. Here, a three‐pronged approach to obtain excellent performance of an InP‐based photoelectrode for water reduction is presented. First, a buried p–n⁺ junction is fabricated, which shifts the valence band edge favorably with respect to the hydrogen redox potential. Photoelectron spectroscopy substantiates that the shift of the surface photovoltage is mainly determined by the buried junction. Second, a periodic array of InP nanopillars is created at the surface of the photoelectrode to substantially reduce the optical reflection losses. This device displays an unprecedented photocathodic power‐saved efficiency of 15.8% for single junction water reduction. Third, a thin TiO₂ protection layer significantly increases the stability of the InP‐based photoelectrode. Careful design of the interface energetics based on surface photovoltage spectroscopy allows obtaining a PEC cell with stable record performance in water reduction.     

Effect of length on the fundamental resonance frequency of arterial models having radial dilatation

The pressure wave moving along an elastic artery filled with blood was examined as a moving Windkessel having a natural oscillation angular frequency nu 0 and a damping coefficient b. The radial directional motion for an element of the wall segment and the adherent fluid was considered. This equation was solved with conditions at both ends of an artery of length L. An external impulse force was applied at one end and a static pressure Po at the other. Analytic solution allowed only certain oscillation modes of resonance frequencies fn, where fn2 = a + cnL-2 with [formula: see text] and V infinity is the high frequency phase velocity. The relationship between f0 and L was examined experimentally for tubes constructed of latex, rubber, or dissected aorta. The effect of raising the static pressure P0 or increasing the tension in the tube was consistent with the prediction. The hypertension that accompanies an augmentation in arterial wall and the association between the heart rate and the mean blood pressure were discussed.     

Superradiant Emission from Coherent Excitons in van Der Waals Heterostructures

Recent advancements in isolation and stacking of layered van der Waals materials have created an unprecedented paradigm for demonstrating varieties of 2D quantum materials. Rationally designed van der Waals heterostructures composed of monolayer transition-metal dichalcogenides (TMDs) and few-layer hBN show several unique optoelectronic features driven by correlations. However, entangled superradiant excitonic species in such systems have not been observed before. In this report, it is demonstrated that strong suppression of phonon population at low temperature results in a formation of a coherent excitonic-dipoles ensemble in the heterostructure, and the collective oscillation of those dipoles stimulates a robust phase synchronized ultra-narrow band superradiant emission even at extremely low pumping intensity. Such emitters are in high demand for a multitude of applications, including fundamental research on many-body correlations and other state-of-the-art technologies. This timely demonstration paves the way for further exploration of ultralow-threshold quantum-emitting devices with unmatched design freedom and spectral tunability.     

A unified approach to superresolution and multichannel blind deconvolution.

This paper presents a new approach to the blind deconvolution and superresolution problem of multiple degraded low-resolution frames of the original scene. We do not assume any prior information about the shape of degradation blurs. The proposed approach consists of building a regularized energy function and minimizing it with respect to the original image and blurs, where regularization is carried out in both the image and blur domains. The image regularization based on variational principles maintains stable performance under severe noise corruption. The blur regularization guarantees consistency of the solution by exploiting differences among the acquired low-resolution images. Several experiments on synthetic and real data illustrate the robustness and utilization of the proposed technique in real applications.     

Standby supply voltage minimization for deep sub-micron SRAM

Suppressing the leakage current in memories is critical in low-power design. By reducing the standby supply voltage (V_DD) to its limit, which is the data retention voltage (DRV), leakage power can be substantially reduced. This paper models the DRV of a standard low leakage SRAM module as a function of process and design parameters, and analyzes the SRAM cell stability when V_DD approaches DRV. The DRV model is verified using simulations as well as measurements from a 4 KB SRAM chip in a 0.13 μm technology. Due to a large on-chip variation, DRV of the 4 KB SRAM module ranges between 60 and 390 mV. Measurements taken at 100 mV above the worst-case DRV show that reducing the SRAM standby V_DD to a safe level of 490 mV saves 85% leakage power. Further savings can be achieved by applying DRV-aware SRAM optimization techniques, which are discussed at the end of this paper.     

The Role of Test Protocols in Automated Test Generation for Embedded-Core-Based System ICs

Modular testing is an attractive approach to testing large system ICs, especially if they are built from pre-designed reusable embedded cores. This paper describes an automated modular test development approach. The basis of this approach is that a core or module test is dissected into a test protocol and a test pattern list. A test protocol describes in detail how to apply one test pattern to the core, while abstracting from the specific test pattern stimulus and response values. Subsequent automation tasks, such as the expansion from core-level tests to system-chip-level tests and test scheduling, all work on test protocols, thereby greatly reducing the amount of compute time and data involved. Finally, an SOC-level test is assembled from the expanded and scheduled test protocols and the (so far untouched) test patterns. This paper describes and formalizes the notion of test protocols and the algorithms for test protocol expansion and scheduling. A running example is featured throughout the paper. We also elaborate on the industrial usage of the concepts described.     

Gallium gradients in Cu(In,Ga)Se2 thin‐film solar cells

The gallium gradient in Cu(In,Ga)Se₂ (CIGS) layers, which forms during the two industrially relevant deposition routes, the sequential and co‐evaporation processes, plays a key role in the device performance of CIGS thin‐film modules. In this contribution, we present a comprehensive study on the formation, nature, and consequences of gallium gradients in CIGS solar cells. The formation of gallium gradients is analyzed in real time during a rapid selenization process by in situ X‐ray measurements. In addition, the gallium grading of a CIGS layer grown with an in‐line co‐evaporation process is analyzed by means of depth profiling with mass spectrometry. This gallium gradient of a real solar cell served as input data for device simulations. Depth‐dependent occurrence of lateral inhomogeneities on the µm scale in CIGS deposited by the co‐evaporation process was investigated by highly spatially resolved luminescence measurements on etched CIGS samples, which revealed a dependence of the optical bandgap, the quasi‐Fermi level splitting, transition levels, and the vertical gallium gradient. Transmission electron microscopy analyses of CIGS cross‐sections point to a difference in gallium content in the near surface region of neighboring grains. Migration barriers for a copper‐vacancy‐mediated indium and gallium diffusion in CuInSe₂ and CuGaSe₂ were calculated using density functional theory. The migration barrier for the In_Cu antisite in CuGaSe₂ is significantly lower compared with the Ga_Cu antisite in CuInSe₂, which is in accordance with the experimentally observed Ga gradients in CIGS layers grown by co‐evaporation and selenization processes. Copyright © 2014 John Wiley & Sons, Ltd.     

ATM‐based wireless broadband access in the local loop

Broadband networks using wireless transmission techniques are a quick and flexible means of implementing subscriber access. Unoccupied frequency bands with sufficient bandwidth to allow the transmission of digital signals at very high bit rates are found only in the microwave bands. Because the path loss is fairly high at these frequencies, the diameter of radio cells is limited to a maximum of a few kilometres. This results in a microcellular system, which is best implemented in the form of a point‐to‐multipoint system, where one radio‐base station serves all subscribers registered in that radio cell. An interactive, broadband, ATM‐based radio local loop has undergone successful trials in Munich. Copyright © 2001 John Wiley & Sons, Ltd.     

Optical Interconnects on and in Printed Circuit Boards

Two types of short distance optical interconnects for on-board applications are presented: Small diameter plastic optical fibre (POF) links and multimode polymer waveguide layers integrated in multilayer printed circuit boards (PCB). POF links with fibre numbers up to 128 and link lengths up to 50 cm are realized with total transmission loss values below 2 dB at 660 nm. First tests of 10 cm long temperature stable multimode polymer waveguides laminated into standard multilayer PCBs demonstrate the capabilities of combined electrical-optical circuit boards.