A radical scavenging reaction of α-tocopherol with methyl radical

To study a radical scavenging reaction of α-tocopherol, it was reacted with methyl radical in dimethyl sulfoxide. Two main products, a geminal dimethyl cyclohexadienone and methyl ether of α-tocopherol, were obtained and these structures were determined by¹³C nuclear magnetic resonance spectroscopy. The radical methylation data of α-tocopherol suggested that a delocalized radical species would be an intermediate. TMIG-RI No. 3.     

k-NN classification of handwritten characters via accelerated GAT correlation

This paper addresses the problem of reinforcing the ability of the k-NN classification of handwritten characters via distortion-tolerant template matching techniques with a limited quantity of data. We compare three kinds of matching techniques: the conventional simple correlation, the tangent distance, and the global affine transformation (GAT) correlation. Although the k-NN classification method is straightforward and powerful, it consumes a lot of time. Therefore, to reduce the computational cost of matching in k-NN classification, we propose accelerating the GAT correlation method by reformulating its computational model and adopting efficient lookup tables. Recognition experiments performed on the IPTP CDROM1B handwritten numerical database show that the matching techniques of the simple correlation, the tangent distance, and the accelerated GAT correlation achieved recognition rates of 97.07%, 97.50%, and 98.70%, respectively. The computation time ratios of the tangent distance and the accelerated GAT correlation to the simple correlation are 26.3 and 36.5 to 1.0, respectively.     

Anodic Dissolution of Uranium Mononitride in Lithium Chloride-Potassium Chloride Eutectic Melt

Uranium-plutonium nitride is a candidate fuel for fast reactors, but its major drawback is ¹⁴C formation from natural nitrogen. One would probably have to use highly ¹⁵N-enriched nitrogen. A pyrochemical process with molten-salt electroreflning has been proposed as a means to increase the nuclear proliferation resistance of the fuel cycle. Molten-salt electroreflning could also be applied to nitride fuels to make possible the recycling of ¹⁵N. The anodic dissolution behavior of UN in LiCI-KCI melt was studied to provide the basis for a feasibility study of electroreflning of irradiated nitride fuels.     

Synthesis of fluorine-graphite intercalation compounds by elemental fluorine and high oxidation-state transition-metal fluorides

Fluorine-graphite intercalation compounds have been synthesized using high purity fluorine gas and high oxidation-state transition-metal fluorides, AgF₃ and NiF₃, at room temperature and at −78 °C. At room temperature, a mixture of stage 1 + 2 − 4 compounds with compositions, C_4.2F to C_14.6F were obtained. On the other hand, stage 2–4 compounds with compositions C_5.6F to C_14.2F were synthesized at −78 °C. The fluorinating ability of AgF₃ and NiF₃ has been shown more clearly at room temperature because a small amount of fluorine was intercalated/absorbed into graphite at −78 °C without catalysts. XPS spectra show that ionic, nearly ionic, semi-covalent and covalent fluorines coexist in the C_xF samples, and that the covalency of CF bonding increases with decreasing stage number.     

Experimental analyses for electronic structure of barium zirconate-strontium zirconate proton-conducting solid solution

In proton-conducting oxides, analyses for their electronic structure contribute to the understanding of interactions between defects in them. In this study, electronic band alignment of (1−x)BaZr_0.8Y_0.2O_3−δ(BZY)–xSrZr_0.95Y_0.05O_3−δ(SZY) proton-conducting solid-solution system (BSZY) which has high defect concentration and the deep valence band is experimentally investigated. By using thin-film specimens for optical absorption measurements, absorption edges derived from electron transition from the valence band to the conduction band which was insensitive to the proton incorporation were clearly observed in spite of the high defect concentration. The obtained optical band gap energy increased from 5.61 to 5.89 eV with increasing x, which was consistent with a composition dependence of Zr(Y)O₆ octahedral tilting. Ultraviolet photon-yield spectroscopy (UV-PYS) measurements under vacuum condition revealed that BZY and SZY had ionization energy of 6.98 and 7.31 eV, respectively, and thus the absolute energy levels of the valence band maximum and the conduction band minimum of BSZY were experimentally clarified. We propose that the combination of the optical absorption measurements using thin-film specimens and the UV-PYS measurements under vacuum condition is effective in evaluating fundamental electronic structures of proton-conducting oxides.     

Cost-Efficient Traffic Aggregation Employing Cross-Layer Shared Protection

Shared protection/restoration is a promising solution for reducing protection resources and is supported at each layer of the current multi-layer networks. Software-defined networking is expected to reduce equipment cost as well as operational cost by orchestrating these shared protection functionalities. However, although protection resource sharing improves link utilization, it sometimes increases the required equipment. Meanwhile, traffic re-aggregation at each layer is an important technique for low volume traffic to utilize the underlying link capacity more efficiently, but re-aggregation also makes it difficult to share protection resources with traffic at lower layers. In this paper, we present multi-layer network design strategy and method that reduce equipment cost by means of both traffic re-aggregation at each layer and protection resource sharing among multiple service traffic at different layers. The strategy first prioritizes traffic re-aggregation at each layer, and then maximally delegates shared protection to lower layers as long as it does not increase the required capacity at the lower layer. Evaluation results from the example three-layer networks confirm that the proposed method can effectively reduce equipment cost compared to the conventional design method. Cost reduction is achieved by leveraging shared protection functions at multiple layers.     

Ergonomics solution for crossing collisions based on field assessment of visual environment at urban intersections in Japan

This paper aims to assess quantitatively the actual visual environment of uncontrolled urban downtown intersections in Japan in relation to frequently occurring crossing collisions and to discuss the safety countermeasures for them. In Field Study 1 dealing with direct visibility, our ultra-wide-angle photograph analysis revealed that most of the right/left-ward visible range at 11 intersections were insufficient to check safety, and the quality of direct visibility was closely associated with causing crossing collisions. The countermeasures to reduce a blind area were determined to be a top priority. In Field Study 2 dealing with indirect visibility, more than half of the 25 traffic convex mirrors had marked shortcomings for preventive safety, and ergonomics guidelines ensuring indirect visibility were proposed for installing traffic convex mirrors. Low-cost/low-technology-oriented countermeasures are highly recommended to obtain clear/sufficient images of crucial information satisfying drivers' requirements on traffic convex mirrors in accordance with those ergonomics guidelines was highly recommended. Crossing collisions could be prevented by improvement of poor direct and indirect visibility.     

Patient with unusual Hutchinson-Gilford syndrome (progeria)

A patient with unusual Hutchinson-Gilford syndrome (progeria) is reported. This 7-year-old boy had all the characteristics of progeria, except for coxa valga and the "horse-riding" stance. A previous cerebral infarction was detected in the right putamen on cranial magnetic resonance imaging. During treadmill exercise test electrocardiography, ST depression suggested the existence of arteriosclerotic lesions. Skin fibroblast culture exhibited 76% DNA-repair capacity compared to normal. He has not manifested endocrinologic abnormalities. From these findings it is concluded that this patient has an incomplete case of Hutchinson-Gilford syndrome and that a correlation may exist between the clinical features and the degree of DNA-repair capacity.     

Development of an epileptic seizure prediction algorithm using R–R intervals with self-attentive autoencoder

Epilepsy is a neurological disorder that may affect the autonomic nervous system (ANS) from 15 to 20 min before seizure onset, and disturbances of ANS affect R–R intervals (RRI) on an electrocardiogram (ECG). This study aims to develop a machine learning algorithm for predicting focal epileptic seizures by monitoring R–R interval (RRI) data in real time. The developed algorithm adopts a self-attentive autoencoder (SA-AE), which is a neural network for time-series data. The results of applying the developed seizure prediction algorithm to clinical data demonstrated that it functioned well in most patients; however, false positives (FPs) occurred in specific participants. In a future work, we will investigate the causes of FPs and optimize the developing seizure prediction algorithm to further improve performance using newly added clinical data.

     

Ultra-fast microwave aided synthesis of gold nanocages and structural maneuver studies

Gold nanocages (AuNcgs) are well-studied,hollow,metallic nanostructures that have fascinated researchers in the fields of nanotechnology,materials science,photoelectronics,biotechnology,and medical science for the last decade.However,the time-consuming synthesis of AuNcgs has limited their widespread use in materials science and nano-biotechnology.A novel,ultra-fast,simple,and highly convenient method for the production of AuNcgs using microwave heating is demonstrated herein.This quick method of AuNcg synthesis requires mild laboratory conditions for large-scale production of AuNcgs.The microwave heating technique offers the advantage of precise mechanical control over the temperature and heating power,even for the shortest reaction period (i.e.,seconds).Microwave-synthesized AuNcgs were compared with conventionally synthesized AuNcgs.Structural maneuver studies employing the conventionally produced AuNcgs revealed the formation of screw dislocations and a shift in the lattice plane.Detailed characterization of the microwave-generated AuNcgs was performed using high resolution transmission electron microscopy (HRTEM),scanning electron microscopy (SEM),X-ray powder diffraction (XRD),and spectroscopic techniques.