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51.
Silva VH Martins MP de Oliveira HC Camargo AJ 《Journal of molecular graphics & modelling》2011,29(6):777-783
Nitric oxide (NO) is an extremely toxic compound formed during combustion, predominantly at high temperatures, and it is among the most important atmospheric pollutants. However, this compound has interesting biological activities, since it can control important biological processes in living organisms. With the aim of developing new materials that can be used as selective chemical sensors or as biomedical NO delivery agents we carried out a quantum mechanical study of the interaction of NO with aluminum phthalocyanine (AlPc) at B3LYP/6-31G* level. The calculation results show clearly that the complexation of NO with AlPc depends on the latter's oxidation state. NO is more strongly bonded to AlPc in the reduced state (-33.77 kcal/mol) than in the oxidized state (-4.96 kcal/mol). By applying the Fukui function and analysis of the Frontier molecular orbital, it was possible to explain the situation within which nitric oxide interacts with AlPc. 相似文献
52.
Valter Castelvetro Francesco Ciardelli Hartmut Fischer Frank E. Karasz 《Polymer International》1996,39(1):37-46
The phase behaviour of two classes of side chain polysiloxanes, containing respectively 4-cyano- and 4-alkoxy-4′-stilbene-ether mesogens, was studied over a wide temperature range by differential scanning calorimetry and wide angle X-ray diffraction, with special attention devoted to the characterisation of the microdomain phase morphology. Room temperature X-ray diffraction studies suggest for certain polymers with cyanostilbene mesogens the occurrence of microphase separation; this effect becomes significant as the amount of polysiloxane backbone versus the side chains increases. The onset of electrical conductivity was followed upon exposure of the polymeric films to various doping agents; conductivities up to 2 × 10−1 S cm−1 were measured when cyanostilbene-containing polymers were exposed to strong Lewis acids such as SO3 or SbF5. However, occurrence of some chemical degradation upon heavy doping and of electrode polarisation during DC conductivity measurements indicate that the observed electroconductivity is not purely electronic. 相似文献
53.
Jérôme Chevalier Aléthéa Liens Helen Reveron Fei Zhang Pascal Reynaud Thierry Douillard Laura Preiss Valter Sergo Vanni Lughi Mike Swain Nicolas Courtois 《Journal of the American Ceramic Society》2020,103(3):1482-1513
Forty years ago, Garvie and his Australian co-workers reported that the stress-induced transformation of metastable tetragonal zirconia grains to the monoclinic symmetry could give rise to a powerful toughening mechanism. Their results even led them to consider zirconia systems as analogues of certain steels. This seminal paper generated extraordinary excitement in the ceramic community and it is still the subject of extensive research. Transformation toughening is widely used in zirconia materials and results in an increase in strength and toughness when compared to nontransformable ceramics, but the implementation into strong, tough, and sufficiently stable materials has not been fully reached. Zirconia ceramics generally fail at low strains with a much larger scatter in the strength values than metals and require statistical approaches to failure. Here we describe in detail the mechanical behavior laws of ceria-doped zirconia composites exhibiting a high degree of stress-induced transformation. They present, to some extent, mechanical behavior analogous to a metal, displaying, (a) significant amount of transformation-induced plasticity without damage, (b) very high flaw tolerance and (c) almost no dispersion in strength data. They potentially open new application avenues in situations where the advantages of ceramics were dampened by their brittle failure behavior. In particular, the consequences of such behavior for dental implants and additive-manufactured structures are highlighted. 相似文献
54.
G. Ramogida G. Calabro V. Cocilovo F. Crisanti A. Cucchiaro M. Marinucci A. Pizzuto C. Rita F. Zonca R. Albanese G. Artaserse F. Maviglia M. Mattei 《Fusion Engineering and Design》2009,84(7-11):1562-1569
The Fusion Advanced Studies Torus (FAST) conceptual study has been proposed [A. Pizzuto on behalf of the Italian Association, The Fusion Advanced Studies Torus (FAST): a proposal for an ITER Satellite facility in support of the development of fusion energy, in: Proceedings of 22nd IAEA Fusion Energy Conference, Geneva, Switzerland, October 13–18, 2008; Nucl. Fusion, submitted for publication] as possible European ITER Satellite facility with the aim of preparing ITER operation scenarios and helping DEMO design and R&D. Insights into ITER regimes of operation in deuterium plasmas can be obtained from investigations of non linear dynamics that are relevant for the understanding of alpha particle behaviours in burning plasmas by using fast ions accelerated by heating and current drive systems.FAST equilibrium configurations have been designed in order to reproduce those of ITER with scaled plasma current, but still suitable to fulfil plasma conditions for studying burning plasma physics issues in an integrated framework. In this paper we report the plasma scenarios that can be studied on FAST, with emphasis on the aspect of its flexibility in terms of both performance and physics that can be investigated. All plasma equilibria satisfy the following constraints: (a) minimum distance of 3 energy e-folding length (assumed to be 1 cm on the equatorial plane) between plasma and first wall to avoid interaction between plasma and main chamber; (b) maximum current density in the poloidal field coils, transiently, up to around 30 MA/m2. The discharge duration is always limited by the heating of the toroidal field coils that are inertially cooled by helium gas at 30 K. The location of the poloidal field coils has been optimized in order to: minimize the magnetic energy; produce enough magnetic flux (up to 35 Wb stored) for the formation and sustainment of each scenario; produce a good field null at the plasma break-down (BP/BT < 2 × 10−4 at low field, i.e. BT = 4 T and ET = 2 V/m for at least 40 ms).Plasma position and shape control studies will also be presented. The optimization of the passive shell position slows the vertical stability growth time down to 100 ms. 相似文献
55.
56.
Claudio Minero Paolo Pellizzari Valter Maurino Ezio Pelizzetti Davide Vione 《Applied catalysis. B, Environmental》2008,77(3-4):308-316
The sonochemical degradation rate of the charged substrates Acid Blue 40 (AB40) and methylene blue (MB) is enhanced by scavengers of hydroxyl radicals such as bicarbonate, carbonate, bromide, iodide and (only in the case of AB40) nitrite. No rate variation was observed with chloride, nitrate or sulphate, excluding a mere ionic strength effect. Oxidation of bicarbonate, carbonate, bromide, iodide and nitrite yields the corresponding radicals CO3−, Br2−, I2− and NO2, reactive but less than OH. Degradation enhancement can occur if these radicals are sonochemically formed on the surface of the collapsing cavitation bubbles and undergo there radical–radical recombination at a lesser extent than OH. In this way the radicals would be more available than OH for substrate degradation, both at the bubble surface and in the solution bulk, which could more than compensate for their lower intrinsic reactivity. The varied reactivity toward different substrates of the sonochemically formed radical species could then explain why nitrite inhibits MB degradation while enhancing that of AB40. The sonochemical formation of Br2−, I2− and NO2 can give rise to halogenation and nitration in addition to oxidation processes. In fact bromo-, iodo- and nitrophenols were detected upon sonication of phenol in the presence of the corresponding anions, but only at quite elevated concentration values of nitrite, bromide or iodide (above 10 mM). Formation of harmful halogeno- and nitroderivatives could therefore take place on sonication of some wastewater rather than of typical natural waters. 相似文献
57.
We describe a computational algorithm for the evaluation of error probabilities of multilevel modulation codes. This is based on the derivation of a trellis cataloging the words of the component codes and of a suitable set of branch labels depending on the channel on which the transmission takes place (additive white Gaussian noise channel, fading channel with or without channel state information). The error probability is upper bounded by the transfer function of this trellis, which is derived in closed form. 相似文献
58.
Marta Tarkanovskaja Raul Välbe Kaija Põhako-Esko Uno Mäeorg Valter Reedo Andres Hoop Kristjan Saal Andres Krumme Ilmar Kink Ivo Heinmaa Ants Lõhmus 《Ceramics International》2014
The preparation of ionogels by sol–gel processing has attracted much attention, because the final ceramic materials combine properties of both inorganic matrix (thermal and mechanical stability) and the ionic liquid (ionic conductivity). The aim of this study was to combine different imidazolium based ionic liquids (1-ethyl-3-methylimidazolium tetrafluoroborate [EMIM][BF4], 1-butyl-3-methyl imidazolium tetrafluoroborate [BMIM][BF4], 1-decyl-3-methylimidazolium tetrafluoroborate [DMIM][BF4] and 1-methyl-3-[3′-(triethoxysilyl)propyl]imidazolium chloride MTICl) with titanium(IV) butoxide to prepare homogenous hybrid fibers through aqueous sol–gel reaction. The study showed that ionic liquid miscibility with metal alkoxide plays an important role in the preparation of homogenous fibers. Unlike simple imidazolium salts functionalized ionic liquid was dispersed homogenously in fibers, but the main advantage is derived from its chemical structure. New stable ionic liquid can be involved in sol–gel processes through ethoxy groups and as a result it associates with titanium alkoxide network by covalent bonding providing non-leaking ceramic hybrid material. Indirect and direct characterization studies of the product were carried out by energy-dispersive X-ray spectroscopy (EDX), silicon-29 nuclear magnetic resonance spectroscopy (29Si NMR), scanning electron microscopy (SEM) and optical microscopies; also infrared spectra (IR) were recorded. Thermal analyses were performed by differential scanning calorimetry (DSC). 相似文献
59.
Masciopinto C La Mantia R Levantesi C Tandoi V Divizia M Donia D Gabrieli R Petrinca AR 《Environmental science & technology》2011,45(2):636-642
We propose an analytical solution in order to explain the processes that determine the fate and behavior of the viruses during transport in a fractured aquifer at Salento (Italy). The calculations yield the efficiency of filtration in fractures at a site near Nardo? (Southern Italy) in reducing the numbers of enteric viruses (i.e., Enteroviruses and Norovirus) in secondary municipal effluents that have been injected in the aquifer over the period 2006-2007. The model predicted, by a theoretical expression, the time-dependent rate of virus reduction, which was in good agreement with field data. The analytical solution yields the achievable "Log reduction credits" for virus reduction in wells located at the setback distances that are usually adopted in local drinking water regulations. The resulting new analytical formula for the time-dependent reduction of viruses during subsurface transport can easily be applied in health risk-based models used to forecast the spread of waterborne diseases and provides appropriate criteria (i.e., distances) needed to meet standards for the quality of drinking water derived from undisinfected groundwater. 相似文献
60.
Geraldo E. Luz Jr. Anne G.D. SantosAna C.R. Melo Ricardo M. OliveiraAntonio S. Araujo Valter J. Fernandes Jr. 《Fuel Processing Technology》2011,92(10):2099-2104
In order to obtain a fuel with properties similar to diesel, the thermal catalytic cracking (TCC) of buriti oil was accomplished over LaSBA-15 mesoporous materials. In function of the Lewis acid sites and the unidirectional pore system of the LaSBA-15, this material presented good deoxygenating activity for TCC of the oil, resulting in a reduction of the oxygenate content in the organic liquid (OL) collected above 190 °C, obtaining as main product, a mixture of hydrocarbons similar to mineral diesel, called green diesel. 相似文献