Copper accumulation in soils from two different‐aged apricot orchards in Central Otago,New Zealand

In recent years there has been a move in New Zealand to convert small, uneconomic orchards to other agricultural uses. Overseas research has demonstrated that copper from fungicide sprays often accumulates in the soils of orchards and can cause certain problems for plant growth and livestock. To date, no assessments appear to have been made of the degree of copper accumulation in such older orchards in New Zealand. This study presents the results of an assessment of two well‐established apricot orchards in the Central Otago region of South Island, New Zealand.

Two aspects of the results are surprising. The first is the relatively low levels of copper in the soil when compared with results from another orchard in the region. That orchard is 18 years old and mean soil copper has already reached 100.0 μg/g, indicating a much faster rate of accumulation than in the two orchards in the current study. The second unexpected result is that the younger orchard has a significantly higher level of copper than the older orchard. Reasons for these findings are discussed in relation to apparent differences in soil properties.     

Crosslinking-property relationships in PMR polyimide composites. Part I

This study examines for the first time how matrix crosslinking affects the composite physical and mechanical properties of a graphite fiber reinforced PMR polyimide composite during long-term isothermal aging. Unidirectional composite specimens of Celion 6000/PMR-P1 were isothermally exposed at 288°C in air for various time periods up to 5000 h. The matrix crosslink densities were estimated from the kinetic theory of rubber elasticity and shifts in the glass transition temperatures (T_gs). The T_g, coefficient of thermal expansion, density, weight loss, moisture absorption, and elevated temperature flexural and interlaminar shear properties were also determined. Several linear relationships were found between the matrix crosslink density and composite physical and mechanical properties. The T_g, initial weight loss and density, and elevated temperature interlaminar shear strength increase with an increase in crosslink density. Conversely, the initial moisture absorption and coefficient of thermal expansion decrease with increasing crosslink density. As expected, the elevated temperature flexural strength and modulus show no direct correlations with crosslink density. Further, after achieving the highest matrix crosslink density, several of the composite properties begin to decrease rapidly. These findings suggest that time-temperature dependent nature of attaining the maximum matrix crosslinking is closely linked to the onset of the composite property degradation. Though much more work is needed, a fundamental understanding of the relationships between matrix crosslinking and composite physical and mechanical property can provide a scientific basis for the prediction of the extent of composite service life not only for PMR polyimides but also for other thermosetting matrix resins, such as epoxies and bismaleimides.     

Metabolic Syndrome: Updates on Pathophysiology and Management in 2021

Metabolic syndrome (MetS) forms a cluster of metabolic dysregulations including insulin resistance, atherogenic dyslipidemia, central obesity, and hypertension. The pathogenesis of MetS encompasses multiple genetic and acquired entities that fall under the umbrella of insulin resistance and chronic low-grade inflammation. If left untreated, MetS is significantly associated with an increased risk of developing diabetes and cardiovascular diseases (CVDs). Given that CVDs constitute by far the leading cause of morbidity and mortality worldwide, it has become essential to investigate the role played by MetS in this context to reduce the heavy burden of the disease. As such, and while MetS relatively constitutes a novel clinical entity, the extent of research about the disease has been exponentially growing in the past few decades. However, many aspects of this clinical entity are still not completely understood, and many questions remain unanswered to date. In this review, we provide a historical background and highlight the epidemiology of MetS. We also discuss the current and latest knowledge about the histopathology and pathophysiology of the disease. Finally, we summarize the most recent updates about the management and the prevention of this clinical syndrome.     

Development and demonstration of a deployable apparatus for generating hydrogen from the hydrolysis of aluminum via sodium hydroxide

Emergency and backup power is often enabled through the use of petrochemical based fuels and combustion-based generator systems, and while reliable, these backup power systems fail when petrochemical supplies are disrupted due to refinery, oil outages, or transportation delays. Fuel cells in some cases can serve as a backup to these traditional generators, but they also are fuel-limited to supplies of available energy sources. Recent work conducted in our laboratories focused on the development of a “backup” emergency hydrogen generation system that could be employed when existing energy stockpiles have failed or depleted. Specifically, aluminum metal can be used to generate hydrogen for fuel cells via hydrolysis with sodium hydroxide. In this paper, we summarize the engineering work to produce a deployable aluminum to hydrogen generator which is capable of producing 3.75 kg of hydrogen per day from scrap aluminum feedstocks. The generator was built upon an aircraft deployable pallet, allowing for hydrogen to be generated remotely in cases of power and fuel outages.     

The perinatal mortality rate as an indicator of quality of care in international comparisons

Priming and recollection are expressions of human memory mediated by different brain events. These brain events were monitored while people discriminated words from nonwords. Mean response latencies were shorter for words that appeared in an earlier study phase than for new words. This priming effect was reduced when the letters of words in study-phase presentations were presented individually in succession as opposed to together as complete words. Based on this outcome, visual word-form priming was linked to a brain potential recorded from the scalp over the occipital lobe about 450 ms after word onset. This potential differed from another potential previously associated with recollection, suggesting that distinct operations associated with these two types of memory can be monitored at the precise time that they occur in the human brain.     

Distinct annexin subfamilies in plants and protists diverged prior to animal annexins and from a common ancestor

Annexin homologues in the kingdoms of Planta and Protista were characterized by molecular sequence analysis to determine their phylogenetic and structural relationship with annexins of Animalia. Sequence fragments from 19 plant annexins were identified in sequence databases and composite sequences were also assembled from expressed sequence tags for Arabidopsis thaliana. Length differences in protein aminotermini and evidence for unique exon splice sites indicated that plant annexins were distinct from those of animals. A third annexin gene of Giardia lamblia (Anx21-Gla) was identified as a distant relative to other protist annexins and to those of higher eukaryotes, thus providing a suitable outgroup for evolutionary reconstruction of the family tree. Rooted evolutionary trees portrayed protist, plant, and Dictyostelium annexins as early, monophyletic ramifications prior to the appearance of closely related animal annexin XIII. Molecular phylogenetic analyses of DNA and protein sequence alignments revealed at least seven separate plant subfamilies, represented by Anx18 (alfalfa, previously classified), Anx22 (thale cress), Anx23 (thale cress, cotton, rape and cabbage), Anx24 (bell pepper and tomato p34), Anx25 (strawberry, horseradish, pea, soybean, and castor bean), Anx26-Zma, and Anx27-Zma (maize). Other unique subfamilies may exist for rice, tomato p35, apple, and celery annexins. Consensus sequences compiled for each eukaryotic kingdom showed some breakdown of the "annexin-fold" motif in repeats 2 and 3 of protist and plant annexins and a conserved codon deletion in repeat 3 of plants. The characterization of distinct annexin genes in plants and protists reflects their comparable diversity among animal species and offers alternative models for the comparative study of structure-function relationships within this important gene family.     

Synthesis and evaluation of tetra(2,7-octadienyl) titanate as a reactive diluent for air-drying alkyd paints

Environmental regulations are forcing the reformulation of many decorative and protective coatings systems. In particular, air-drying solventborne alkyd paints need to meet increasingly stringent emission limits and often must be reformulated with suitable exempt solvents or reactive diluents to achieve volatile organic compound (VOC) reduction. In the research summarized in this article, a new reactive diluent, tetra(2,7-octadienyl) titanate, was synthesized and evaluated in alkyd formulations for VOC reduction and property enhancement. A soy-based long-oil alkyd resin; a soy-based high-solids, long-oil alkyd resin; and a linseed-based, high-solids long-oil alkyd resin were evaluated in combination with the new reactive diluent at weight percentages ranging from 10% to 50%. Characterization included measuring viscosity, film dry times, and film performance of the reactive diluent formulations in comparison to neat alkyd resins used as control. The tetra(2,7-octadienyl) titanate formulations consistently exhibited reduced viscosities and dry times as a function of concentration. The resulting films were harder and more thoroughly cured than the control systems.