全文获取类型
收费全文 | 2704篇 |
免费 | 25篇 |
国内免费 | 11篇 |
专业分类
电工技术 | 88篇 |
综合类 | 3篇 |
化学工业 | 525篇 |
金属工艺 | 93篇 |
机械仪表 | 77篇 |
建筑科学 | 34篇 |
能源动力 | 141篇 |
轻工业 | 122篇 |
水利工程 | 11篇 |
石油天然气 | 6篇 |
无线电 | 346篇 |
一般工业技术 | 437篇 |
冶金工业 | 661篇 |
原子能技术 | 45篇 |
自动化技术 | 151篇 |
出版年
2023年 | 15篇 |
2022年 | 17篇 |
2021年 | 41篇 |
2020年 | 16篇 |
2019年 | 17篇 |
2018年 | 17篇 |
2017年 | 23篇 |
2016年 | 29篇 |
2015年 | 28篇 |
2014年 | 47篇 |
2013年 | 115篇 |
2012年 | 71篇 |
2011年 | 106篇 |
2010年 | 89篇 |
2009年 | 88篇 |
2008年 | 98篇 |
2007年 | 96篇 |
2006年 | 74篇 |
2005年 | 59篇 |
2004年 | 61篇 |
2003年 | 101篇 |
2002年 | 71篇 |
2001年 | 63篇 |
2000年 | 44篇 |
1999年 | 82篇 |
1998年 | 310篇 |
1997年 | 173篇 |
1996年 | 108篇 |
1995年 | 69篇 |
1994年 | 82篇 |
1993年 | 70篇 |
1992年 | 38篇 |
1991年 | 34篇 |
1990年 | 45篇 |
1989年 | 33篇 |
1988年 | 23篇 |
1987年 | 26篇 |
1986年 | 25篇 |
1985年 | 31篇 |
1984年 | 23篇 |
1983年 | 30篇 |
1982年 | 16篇 |
1981年 | 14篇 |
1980年 | 23篇 |
1979年 | 13篇 |
1978年 | 11篇 |
1977年 | 12篇 |
1976年 | 21篇 |
1975年 | 10篇 |
1974年 | 10篇 |
排序方式: 共有2740条查询结果,搜索用时 0 毫秒
81.
Kenji Arata Nobutaka Takeuchi Masaru Yoshinaka Ken Hirota Osamu Yamaguchi 《Journal of the American Ceramic Society》1997,80(8):2168-2170
Continuously graded MoSi2 -ZrO2 (2Y) materials with high density (97.5% of theoretical) have been fabricated by uniaxial wet-molding, followed by hot pressing (1000°C/1 h/30 MPa) and hot isostatic pressing (1400°C/2 h/196 MPa). Their composition profiles are greatly influenced by the viscosity of mixed solutions of glycerin and ethanol used as a dispersion medium; a linear compositional gradient from MoSi2 /ZrO2 (2Y) 70/30 to 20/80 mol% is obtained from the solution (50/50 vol%) with a viscosity of 20 mPa s. Vickers hardness (Hv) and fracture toughness (KIC) increase from 9.7 to 12.4 GPa and from 5.1 to 12.5 MPa m1/2, respectively, with increasing ZrO2 (2Y) composition. 相似文献
82.
M. Kawase K. Sato R. Mitsui H. Asonuma M. Kageyama K. Yamaguchi G. Inoue 《American Institute of Chemical Engineers》2017,63(1):249-256
Although fuel cells can be considered as a type of reactor, methods of kinetic analysis and reactor modeling from the viewpoint of chemical reaction engineering have not yet been established. The rate of an electrochemical reaction is a function of concentration, temperature, and interfacial potential difference (or electromotive force). This study examined the cathode reaction in a polymer electrolyte fuel cell, in which oxygen and protons react over platinum in the catalyst layer (CL). The effects of the oxygen partial pressure and the cathode electromotive force on the reaction rate were assessed. Resistance to proton transport increases the electromotive force and reducing the reaction rate. It was established that the effectiveness factor of the cathode CL is determined by competition between the reaction and mass transport of oxygen and protons. Two dimensionless moduli that govern the cathode behavior are proposed as a means of depicting the processes in the cell. © 2016 American Institute of Chemical Engineers AIChE J, 63: 249–256, 2017 相似文献
83.
Sudu Siqing Hui Wu Hiroki Yamaguchi Takamichi Shinohara Osami Sakata Atsushi Takahara 《Polymer Bulletin》2013,70(1):105-115
Nanoimprint lithography (NIL) was carried out on precursor of polyimide (PI), poly(amic acid) film, and then hard baking to obtain imprinted PI film. The molecular aggregation states of imprinted PI films before and after hard baking were investigated by grazing-incidence wide-angle X-ray diffraction comparing with the one of flat PI film. It was found that NIL and hard baking can strongly affect the molecular aggregation states of PI film. Before hard baking, PI chain is aligned parallel to the line direction on the line. After hard baking, the alignment in ordered domain was changed to that the PI molecule of which chain axis is perpendicular to the line direction is significantly increased, while, PI molecule of which chain axis is parallel to the line direction is decreased after hard baking. Through comparing with the flat PI, crystallinity of imprinted PI film has been significantly enhanced. 相似文献
84.
Blending a crosslinked high‐density polyethylene (xHDPE) enhances melt strength and strain hardening behavior in elongational viscosity of high‐density polyethylene (HDPE) to a great degree. Gel fraction of xHDPE has a stronger effect on the strain hardening than sol fraction, although sol fraction also enhances the strain hardening to some degree. Further, the xHDPE crosslinked by peroxide in a compression mold exhibits more pronounced effect than xHDPE by radiation, which is attributed to the difference in the amount of the gel fraction. The xHDPE, which enhances the strain hardening, has sparse crosslink points in the network. Moreover, it was found from linear viscoelastic measurements, such as oscillatory modulus and relaxation modulus, that the xHDPE is characterized as a critical gel, which was also supported by the result of tensile testing. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 73–78, 2002 相似文献
85.
MicroRNA-331-3p Suppresses Cervical Cancer Cell Proliferation and E6/E7 Expression by Targeting NRP2
Tomomi Fujii Keiji Shimada Aya Asano Yoshihiro Tatsumi Naoko Yamaguchi Masaharu Yamazaki Noboru Konishi 《International journal of molecular sciences》2016,17(8)
Aberrant expression of microRNAs (miRNAs) is involved in the development and progression of various types of cancers. In this study, we investigated the role of miR-331-3p in cell proliferation and the expression of keratinocyte differentiation markers of uterine cervical cancer cells. Moreover, we evaluated whether neuropilin 2 (NRP2) are putative target molecules that regulate the human papillomavirus (HPV) related oncoproteins E6 and E7. Cell proliferation in the human cervical cancer cell lines SKG-II, HCS-2, and HeLa was assessed using the 3-(4,5-dimethylthiazol-2-yl)-5-(3-carboxymethoxyphenyl)-2-(4-sulfophenyl)-2H-tetrazolium, inner salt (MTS) assay. Cellular apoptosis was measured using the TdT-mediated dUTP nick end labeling (TUNEL) and Annexin V assays. Quantitative RT-PCR was used to measure the messenger RNA (mRNA) expression of the NRP2, E6, E7, p63, and involucrin (IVL) genes. A functional assay for cell growth was performed using cell cycle analyses. Overexpression of miR-331-3p inhibited cell proliferation, and induced G2/M phase arrest and apoptosis in SKG-II, HCS-2 and HeLa cells. The luciferase reporter assay of the NRP2 3′-untranslated region revealed the direct regulation of NRP2 by miR-331-3p. Gene expression analyses using quantitative RT-PCR in SKG-II, HCS-2, and HeLa cells overexpressing miR-331-3p or suppressing NRP2 revealed down-regulation of E6, E7, and p63 mRNA and up-regulation of IVL mRNA. Moreover, miR-331-3p overexpression was suppressed NRP2 expression in protein level. We showed that miR-331-3p and NRP2 were key effectors of cell proliferation by regulating the cell cycle, apoptosis. NRP-2 also regulates the expression of E6/E7 and keratinocyte differentiation markers. Our findings suggest that miR-331-3p has an important role in regulating cervical cancer cell proliferation, and that miR-331-3p may contribute to keratinocyte differentiation through NRP2 suppression. miR-331-3p and NRP2 may contribute to anti-cancer effects. 相似文献
86.
Aritomo Yamaguchi Takafumi Shido Yasuhiro Inada Toshihiro Kogure Kiyotaka Asakura Masaharu Nomura Yasuhiro Iwasawa 《Catalysis Letters》2000,68(3-4):139-145
The time-resolved reduction process of copper cations in/on ZSM-5 during temperature-programmed reduction (300–700 K) was studied by energy-dispersive X-ray absorption fine structure (DXAFS) as well as transmission electron microscopy (TEM). Two Cu-ZSM-5 samples with different Cu loadings were prepared by an ion-exchange method. The Cu K-edge DXAFS spectra for isolated Cu2+ species in the channels of ZSM-5 and CuO particles on the outer surfaces of ZSM-5 were recorded at an interval of 1 s during the reduction. The curve fitting analysis of the EXAFS data and the XANES analysis revealed that the isolated Cu2+ species in the channels were reduced stepwise. They were reduced to isolated Cu+ species at 400–450 K and the Cu+ species to Cu0 metallic clusters at 550–650 K. Small clusters like Cu4 were initially formed, followed by particle growth. A small part of them went out to the outer surfaces of ZSM-5 during the reduction. In contrast, CuO particles on the outer surfaces were reduced directly to Cu0 metallic particles around 450 K. 相似文献
87.
Toshiaki Yamaguchi Sota Shimizu Toshio Suzuki Yoshinobu Fujishiro Masanobu Awano 《Journal of the American Ceramic Society》2009,92(S1):S107-S111
We report the design and fabrication of a novel electrode-supported honeycomb solid oxide fuel cell (SOFC), that can generate high volumetric power density. Among various cell designs, honeycomb SOFCs are suitable for compact SOFC modules because they have a large surface electrode area per unit volume. We have succeeded in fabricating a cathode-supported honeycomb SOFC via extrusion of a LaSrMnO3 honeycomb monolith and through the use of a new slurry injection method for the channel surface coating using electrolyte/anode bi-layers. The fabricated honeycomb SOFCs exhibited high volumetric power densities of approximately 1.2 W/cm3 at 600°C under a wet H2 fuel flow. 相似文献
88.
Kazutaka Fujiwara Soonil Lee Niall Donnelly Takashi Yamaguchi Clive A. Randall 《Journal of the American Ceramic Society》2009,92(11):2634-2641
A series of composite, negative temperature coefficient (NTC) ceramics were carefully processed with compositions based on the Y(Cr,Mn)O3 +Y2 O3 system and these were investigated for resistance stability in hostile environments. This specific system is of interest for high-temperature automobile thermistors, however either through the processing or in use of these, materials can be exposed to reducing atmospheres at temperatures around 900°–1000°C. The thermochemical processes at intermediate temperatures and low <10−10 atm can influence the resistance of the given ceramics. Through an impedance analysis it is determined that the resistance increase is associated primarily with a grain boundary resistance increase. The grain and grain boundary elements are modeled through parallel constant phase element and resistance equivalent circuits connected in series. Possible origins of the defect chemistry being controlled through high-temperature processes at the sintering are partial Schottky reactions that are compensated through a superoxidation reaction on cooling and aging. The reduction process reversed the superoxidation reaction and transited the grain boundary surfaces to ionically compensated B-site vacancies with oxygen vacancies. 相似文献
89.
Kosuke Yamaguchi Kei Inumaru Yasunori Oumi Tsuneji Sano Shoji Yamanaka 《Microporous and mesoporous materials》2009,117(1-2):350-355
Fundamental photocatalytic behaviors were investigated for mechanical mixtures of TiO2 crystalline particles (P25) and MFI type zeolite (silicalite) in the decomposition reaction of 2-propanol vapor in air for the first time. Mechanical mixing enables reliable comparisons to be made between photocatalysts because the contents of TiO2 and the adsorbent can be widely varied (51 times in this study) while keeping the particle size and crystallinity of TiO2 unchanged. That is, the use of mechanical mixture highlights the behavior of molecules adsorbed in the microporous crystals, keeping the TiO2 unchanged. In the case of the mixed photocatalysts, the initial 2-propanol concentration in the gas phase was significantly reduced because of adsorption into the zeolite. After photo-irradiation started, 2-propanol was decomposed to CO2 with no (or trace amount of) acetone detected in the gas phase. The analysis of final amount of CO2 formed by the decomposition demonstrated that just by the mechanical mixing of TiO2 and zeolite, the TiO2 photocatalyst decomposed completely the reactant and intermediate molecules strongly adsorbed into the zeolite. On the other hand, in reference experiments in which TiO2 and zeolite were not mixed and were separately placed in a photoreactor, the organic compounds strongly adsorbed in the zeolite could not be decomposed to CO2 by the photocatalyst. It is notable that the CO2 formation rates for the mixed photocatalysts were mostly constant for those comprising 40 wt% or larger amounts of zeolite, while being slower than for pure TiO2. The rate-determining step was discussed based on these data. The present study showed that the mixed photocatalyst could remove organic vapors by adsorption in the dark and decompose completely to CO2 at moderate reaction rates under photo-irradiation with minimized evolution of intermediate molecules into the gas phase. 相似文献
90.
Tetsuji Yamaguchi Kumi Negishi Seiichi Hoshino Tadao Tanaka 《Cement and Concrete Research》2009,39(12):1149-1155
In order to predict long-term leaching behavior of cement constituents for safety assessments of radioactive waste disposal, we modeled diffusive mass transport in micropores in cement based materials. Based on available knowledge on the pore structure, we developed a transport porosity model that enables us to estimate effective porosity available for diffusion (transport porosity) in cement based materials. We microscopically examined the pore structure of hardened cement pastes to partially verify the model. Effective diffusivities of tritiated water in hardened cement pastes were also obtained experimentally, and were shown to be proportional to the estimated transport porosity. 相似文献