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81.
In the electrochemical system with liquid-liquid interface, intense local convections by the resonance with potential pulses take place. Therefore, with laser beam scattering, temporal movement of the water-mercury interface was observed. As a result, the scattering efficiency showed non-linear oscillation.
Such non-linear response could be controlled by potential pulse height. As the potential height was increased, new scattering peaks in the oscillation emerged, which was expected of a kind of bifurcation phenomenon. From these results, phase portrait, Poincarè section, correlation dimension of the strange attractor and the largest Lyapunov exponent of the trajectories were obtained. Consequently, it was concluded that all the parameters indicate chaotic behavior of the resonance flow. 相似文献
82.
A. Satsuma K. Yamada K. Sato K. Shimizu T. Hattori Y. Murakami 《Catalysis Letters》1997,45(3-4):267-269
Partially protonated alkaline mordenites showed higher activity per acid amount below 573 K than acidic zeolites for the selective
reduction of NO with C3H6 in the presence of O2, which can be related to a high concentration of NO3
- species in the zeolite channels.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
83.
Taichi Sato 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1976,26(4):207-213
The thermal decomposition of uranium peroxide hydrates, UO4·4H2O and UO4·2H2O, has been investigated by thermal analyses, X-ray diffraction study and infrared spectroscopy. As a result, it is concluded that the thermal decomposition of uranium peroxide hydrates proceeds in the following sequence: where 3 ≤ x ≤ 3.5. 相似文献
84.
Taicho Sato Shuji Ikoma Fusaji Ozawa 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1980,30(1):225-232
The preparation of gelatinous aluminium hydroxide from aqueous solutions containing a mixture of the chloride, nitrate or sulphate of aluminium and urea by heating at 95°C has been investigated under different conditions. The pH value of aqueous solutions, on heating for a given period of time, gradually increases, rises steeply at pH 4.0–7.5 and finally approaches a constant value. The precipitate appears at about pH 7 in the presence of chloride or nitrate ions and about pH 4 in the presence of sulphate ions. Although the gelatinous precipitates in the chloride and nitrate systems are apparently different from the granular, filterable one in the sulphate system, their compositions are not influenced by the species of aluminium salt. The fresh precipitates exist in an amorphous state, and go to pseudoboehmite by ageing. It seems that the amount of pseudoboehmite increases as the concentration of aluminium salt in aqueous solution decreases. However, the transformation from amorphous aluminium hydroxide to pseudoboehmite is reduced in the presence of sulphate ions. Furthermore, it is found that the X-ray diffraction peak for the (200) plane, as an orthorhombic structure, in the pseudoboehmite precipitated from chloride or nitrate solution is more intense than that from sulphate solution. 相似文献
85.
Glyoxal, which was the strong mutagen formed by ozonation of humic substances, was treated with granular activated carbon (GAC) and the behavior of glyoxal was investigated. Glyoxal itself was adsorbed well on GAC at pH 5–7. But, glyoxal increased by GAC treatment of ozonated humic substances when the ozone dose was insufficient to decolorize the humic substances. The precursors of glyoxal may be among other ozonated products which may be changed to glyoxal on GAC. 相似文献
86.
1 INTRODUCTION Since Cu-ZSM-5 was reported as an effective catalyst for the selective catalytic reduction (SCR) of NO by hydrocarbons in the presence of excess oxygen, the SCR of NOx has received much attention as a kind of potential technology for cleaning NOx in various oxygen-rich exhausts of diesel engine, lean burning gasoline engine and gas engine. Although a number of catalysts have been tested, to date, it still seems to be difficult to find a catalyst that is completely suit… 相似文献
87.
A gel polymer electrolyte based on poly(acrylonitrile-co-styrene) as polymer matrix and N-methyl pyridine iodide salt as I− source was prepared. Controlling the concentration of polymer matrix of poly(acrylonitrile-co-styrene) at 17.5 wt.%, mixing the binary organic solvents mixture ethylene carbonate and propylene carbonate with 6:4 (w/w), and the concentration of N-methyl pyridine iodide and iodine with 0.5 and 0.05 M, respectively, the gel polymer electrolyte attains the maximum ionic conductivity (at 30 °C) of 4.63 mS cm−1. Based on the gel polymer electrolyte, a quasi-solid state dye-sensitized solar cell was fabricated and its overall energy conversion efficiency of light-to-electricity of 3.10% was achieved under irradiation of 100 mW cm−2. 相似文献
88.
T. Sato T. Murakami T. Endo M. Shimada K. Komeya T. Kameda M. Komatsu 《Journal of Materials Science》1991,26(7):1749-1754
Corrosion behaviour of Si3N4 ceramics containing Y2O3, Al2O3 and AIN as sintering aids was investigated under hydrothermal conditions at 200–300 C and saturated vapour pressures of water for 1–10 days. Hydrothermal corrosion resulted in the dissolution of the Si3N4 matrix and the formation of a product layer consisting of the original grain-boundary phases and hydrated silica. The dissolution rate of Si3N4 ceramics decreased with decreasing crystallinity of the grain-boundary phase. The dissolution rate could be adequately described by a parabolic plot in the initial stage of the reaction. The apparent activation energies were 83.5–108 kJ mol–1, and the bending strength of the corroded samples decreased from 600 to 400 MPa in the initial stage of the reaction upto a weight loss of 0.004 g cm–2, and then was almost constant up to a weight loss of 0.012 g cm–2. 相似文献
89.
Sohei Sato Hironori Hondoh Satoru Ueno 《Journal of the American Oil Chemists' Society》2021,98(3):269-280
Fat bloom in chocolate is a substantial problem that affects its sensory properties, such as texture and appearance. This phenomenon is because of diffuse light reflection on a roughened surface of chocolate, caused by structural changes of fat crystals subjected to various temperature conditions. The purpose of this study is to characterize the fat bloom formed through gradual two-step cooling after exposure to temperatures (35–37 °C) slightly above the cocoa butter Form βV melting point (33.8 °C). To clarify the fat bloom formation process, the structural changes in cocoa butter and on the chocolate surface, at the dynamic thermal condition for bloom formation, was investigated using X-ray diffraction (XRD), fluorescence light microscopy, and scanning electron microscopy (SEM). The results revealed that an entirely light brown fat bloom occurred, even in the absence of the Form βVI or other polymorphic transformation. Microscopic observation showed that the light brown appearance was because of the porous structure on the chocolate surface. This porous structure was formed by liquid oil moving inside of chocolate from the surface. The formation of a coarse network and the subsequent de-oiling, because of movement of unsolidified liquid fat into the chocolate, appeared to be the main causes of bloom formation. Therefore, a coarsened fat network and oil movement besides the conventional principles of polymorphic transformation of cocoa butter should be considered. 相似文献
90.
Alloy 903 and Alloy 909 are well-known Fe-Co-Ni-Al-Ti-Nb alloys with controlled low thermal expan-sion, but they have some
properties that can be improved. To improve stress-accelerated grain boundary oxidation embrittlement of Alloy 903 and instability
of theγ phase of alloy 909, two new alloys with good stress-rupture ductility, high creep-rupture strength, high tensile strength
at high temperature, and good controlled thermal expansion were developed. These property improvements were accomplished by
the combination of optimizing the Fe-Co-Ni ratio of the matrix and stabilizing theγ phase with the addition of aluminum. 相似文献