汽车B柱内饰板热流道大型精密注塑模设计

汽车B柱内饰板产品分为左右各一件,大小和形状不完全相同,其体积大、结构复杂,内部有斜螺丝柱和较多的斜异形内孔,侧面卡扣位多,其外形为3D弧形曲面、表面质量要求高,注塑时容易出现填充困难及缩痕、翘曲变形等缺陷。针对以上特点,设计了一套一模两腔、热流道成型、多种复杂抽芯机构联合脱模的精密注塑模具。为保证两件产品同时填充且具有相同的成型质量,采用三板模结构以及两个顺序阀热喷嘴进胶转冷流道在产品侧面进胶的方式。详述了整体式模芯结构、热流道浇注系统、冷却系统、排气系统、导向定位系统及弹镶针机构、T槽直接和间接抽斜滑块机构、斜抽芯机构和斜顶机构等多种联合脱模机构的设计要点,解决了B柱左右内饰板注塑过程中的脱模困难及熔体填充和生产周期长等问题,通过优化组合设计,从整体上简化和优化了模具结构,降低了模具制造成本。     

Fabrication and characterization of hierarchical porous Ni2+ doped hydroxyapatite microspheres and their enhanced protein adsorption capacity

Hydroxyapatite (HAP) is a common bio-adsorbent, which performance depends heavily upon its morphology and microporous structure. In this study, a novel synthesis strategy was proposed for hierarchical porous HAP microspheres by a simple “one-pot” hydrothermal reaction. In the strategy, L-glutamic acid serves as soft template to modulate the morphology and inner crystalline of HAP. To evaluate the application potential, doping Ni²⁺ on hierarchical porous HAP microspheres gives metal chelated affinity adsorbents. The prepared adsorbents show a perfect spherical shape, particles size of 96.6 μm, relatively specific surface area of 48.5 m²·g^-1 and hierarchical pores (mesopores: 4 nm and macropores: 53 nm). By the adsorption evaluation, it reveals that the Ni²⁺-HAP adsorbents have high adsorption capacities of 275.11 and 97.55 m²·g^-1 for hemoglobin and bovine serum albumin, respectively, which is comparable to other similar adsorbent. Therefore, this work provides a promising method for high-efficiency hydroxyapatite microspheres for proteins purification.     

骨料线机制砂库装车系统干法除尘设计

本文通过对现有骨料线机制砂库装车除尘系统的介绍,探讨了干法除尘设计的基本思路和具体的工艺过程。结果表明,通过设计带气力输送系统的除尘工艺。能够很好的解决现有工艺的不足,能够提高骨料企业的环境治理水平、具有很好的参考价值。     

Stimuli-Responsive Natural Proteins and Their Applications

Natural proteins are essential biomacromolecules that fulfill versatile functions in the living organism, such as their usage as cytoskeleton, nutriment transporter, homeostasis controller, catalyzer, or immune guarder. Due to the excellent mechanical properties and good biocompatibility/biodegradability, natural protein-based biomaterials are well equipped for prospective applications in various fields. Among these natural proteins, stimuli-responsive proteins can be reversibly and precisely manipulated on demand, rendering the protein-based biomaterials promising candidates for numerous applications, including disease detection, drug delivery, bio-sensing, and regenerative medicine. Therefore, we present some typical natural proteins with diverse physical stimuli-responsive properties, including temperature, light, force, electrical, and magnetic sensing in this review. The structure-function mechanism of these proteins is discussed in detail. Finally, we give a summary and perspective for the development of stimuli-responsive proteins.     

Preparation and toughening mechanism of Mo2NiB2-based cermets with SiC whiskers

Mo₂NiB₂ is a kind of cermet with excellent mechanical properties, stable chemical properties, and excellent corrosion resistance and is often used in wear-resistant application fields, such as injection molding machine parts, can making tools and hot copper extruding dies. The brittleness of Mo₂NiB₂-based cermets limits their wide application. Mo₂NiB₂-based cermets were prepared by the vacuum sintering method, the effect of SiC whiskers (SiCw) on the microstructure and mechanical properties of cermets was investigated, and the toughening mechanism of SiCw on cermets was further discussed. The results indicate that with increasing SiCw content, the indentation fracture toughness (K_IC), transverse fracture strength (TRS), and Vickers hardness (HV) of the cermets first increase and then decrease. The HV, TRS, and indentation fracture toughness of Mo₂NiB₂-based cermets with 0.5 wt% SiCw are 1 113 HV, 1 620 MPa, and 27.97 MPa·m^1/2, respectively, which are 16.8%, 22.7%, and 25% higher than those without SiCw. In the sliding friction tests, Mo₂NiB₂-based cermets with 0.5 wt% SiCw have the smallest friction coefficient, low wear rate, and high wear resistance. SEM observation and analysis of the crack path and fracture surface showed that the toughening mechanism is whisker bridging, crack deflection, microcrack toughening, and whisker pull-out. The results indicate that the addition of 0.5 wt% SiCw can effectively improve the mechanical properties of Mo₂NiB₂-based cermets and further expand the application space of Mo₂NiB₂-based cermets.     

Design of a europium-activated lithium-silicate cyan phosphor via cation substitution

Lithium-containing silicates have been considered as a considerable alternative for luminescent materials. In this study, a novel cyan-emitting phosphor, Na₃LiHf₂Si₃O₁₂: Eu²⁺, was successfully synthesized via cationic substitution with Na₄Hf₂Si₃O₁₂: Eu²⁺ as the initial model. The crystal structure, morphology, and luminescence performance of Na_4-xLi_xHf₂Si₃O₁₂: Eu²⁺ were investigated in detail. The substitution of Li⁺ for Na⁺ site causes a significant blue-shift of the emission band in the range of 550–500 nm and a smaller full width at half maximum. As a result, a cyan phosphor Na₃LiHf₂Si₃O₁₂: Eu²⁺ that can be effectively excited by near-ultraviolet and high-energy beams is obtained. The mechanism of emission regulation was proposed based on the transformation of crystal structure and luminescence performance. In addition, the thermal quenching and cathodoluminescence behaviors were also studied. The results show that cation substitution is an effective method to design new lithium-containing silicate phosphors.     

铜冶炼含砷固体废物的处置现状与展望

随着国内经济的高速发展,从采矿、选矿、冶炼过程中富集到环境中的砷量急剧增加,高砷固废的处置总的原则是"资源化、无害化、减量化",最佳方向是转变成产品,新型药品、有机化,环保建材、高纯砷金属、高端电导体材料等是发展的新方向。     

Interpretation of Dynamic Strain Aging in an Intercritical Annealed Steel by Dislocation Multiplication Induced by Martensitic Transformation

Metallurgical and Materials Transactions A - To elucidate the dynamic strain aging (DSA) mechanism that causes serrated flow in the tensile curves of an intercritical annealed steel with retained...     

Accurate measurement of residual stresses of 2219-T87 aluminum alloy friction stir welding joints based on properties of joints

In order to avoid the deviation caused by calculating the residual stresses of welding joints with the release coefficients of the same parent metal, a new method has been proposed based on the properties of weld joints. Since the mechanical property of 2195-F Al alloy is close to that of 2219-T87 Al alloy Friction stir welding (FSW) joint, 2195-F Al alloy is selected as the substitute material of 2219-T87 Al alloy FSW joint in the calibration test. Release coefficients of 2195-F Al alloy and proper correction coefficient are used to calculate the residual stresses of 2219-T87 Al alloy FSW joints. Compared to the results calculated with release coefficients of its parent metal, it has been proved that the proposed correction method is more precise in residual stresses measurement of weld joints. The mathematical analysis and the results of verification tests have shown that this new method is reliable, and it will provide guidance in academic research and engineering application of the spherical indentation strain-gauge method.     

钛铁矿机械活化-稀酸酸解反应耦合

采用稀酸酸解反应工艺,利用机械活化-稀酸酸解反应耦合技术,在磁驱转动的球磨反应装置上进行了钛铁矿的酸解反应。考察了反应器旋转速率、酸矿比、球料比及硫酸浓度等对酸解反应的影响。结果表明,在硫酸质量分数为60%、酸矿比1.6:1、球料比10:1及反应温度90℃条件下,与原矿浸出反应空白实验相比,采用活化-浸出耦合反应的浸出速率明显提高,浸出2 h酸解率从32%提高到49%,所得钛液的稳定性大于450 mL。扫描电镜(SEM)及X射线衍射(XRD)表征结果表明,耦合反应使得矿物颗粒不断破碎、细化和脱落,使剩余未活化芯继续活化并不断反应浸出。