几种重要DCPD共聚树脂的开发和利用

本文对DCPD／C9、DCPD／笨本分、DCPD／丙烯醇等几种重要共聚树脂的合成及应用，作了较为详细的论述，并对双环戊二烯共聚树脂产业发展提出了建议。     

单高压法硝酸尾气超标原因及改进措施

针对单高压硝酸装置生产中出现的尾气超标问题进行理论分析和模拟实验验证，最后认定造成问题的原因是由于空气提升器周围配管不当，影响了空气提升器效果。通过采取相应的措施，保证了尾气迭标排放。     

钢筋混凝土牛腿结构拉压杆模型及配筋设计

美国混凝土结构规范(ACI 318-08)将拉压杆模型设计方法作为规范性附录,用于指导混凝土结构D区的设计。首先介绍拉压杆模型构成,分析按中国规范(GB 50010-2010)的设计参数(荷载、混凝土强度、钢筋强度)设计时,压杆、拉杆及节点区内力的计算,提供了设计步骤。按照中国规范参数,对牛腿结构进行拉压杆模型设计,对比分析了按建议方法进行设计时与按ACI 318-08规范设计时安全度的差别。算例分析表明,按建议的拉压杆方法进行牛腿结构设计,力学概念清晰,计算简便,与中国规范规定设计方法的安全度水平相当,可用于钢筋混凝土牛腿结构的设计。     

Simplified Monthly Hydrology and Irrigation Water Use Model to Explore Sustainable Water Management Options in the Murray-Darling Basin

We aimed to provide whole-of-basin simulations of flows and diversions in the Murray-Darling Basin for economic and policy analysis. We describe a model based on a subdivision of the basin into 58 catchments. In each catchment, the monthly runoff, river flow and irrigation demand are modelled as lumped processes. This is the first single model of the whole of the Murray-Darling Basin. The model was calibrated using monthly flow and annual diversion records, both by trial and error and using an automated method. We use the model to examine the impact on the flow and diversions in the Murray-Darling Basin of proposed diversion reductions and climate change. The diversion reductions return water to the environment, increasing river flows below the main irrigation areas. However, a middle-of-the-range climate change projection may result in a 13 % decrease in total flows in 2030, which offsets the enhancement to flows gained by diversion reductions.     

Synthesis and magnetic properties of CuFe2O4 nanotube arrays

CuFe2O4 nanotube arrays with different outer diameters were synthesized in anodic aluminum oxide templates through sol-gel techniques followed by heating treatment processes. The morphology of the nanotube arrays was investigated by field emission scanning electron microscope and transmission electron microscopy, suggesting that the nanotube arrays are ordered and uniform. The X-ray diffraction results indicate that the crystal structure of the nanotube arrays is polycrystalline with a spinel-type structure. The measurements of magnetic properties indicate that CuFe2O4 nanotube arrays with outer diameter of 200 nm exhibit magnetic anisotropy with easy magnetization direction along the axis of nanotubes.     

Preliminary study on some properties of Co-Cr dental alloy formed by selective laser melting technique

The surface condition, some properties and ion releasing behavior of cobalt-chromium (Co-Cr) dental alloy formed by selective laser melting (SLM) technique were investigated. Before porcelain fused firing, the surface condition of the Co-Cr alloy was observed using a scanning electron microscope (SEM), and then the density and hardness were examined. After porcelain fused firing, the interface of porcelain and alloy was observed, and then the metal-ion release of the samples was tested. SLM technique provides Co-Cr alloy higher hardness than casting method. After degassing-oxidation procedure and porcelain fused firing, the interface of the alloy and porcelain showed excellent combination. Co ion was more than Cr ion released from SLM Co-Cr alloy, the amounts of Co and Cr ions were safe according to ISO security criterion. Considering the properties before and after porcelain fused sintering process, SLM technique is suitable for dental Co-Cr alloy restoration.     

Treatment of textile dye effluent using a self-made positively charged nanofiltration membrane

A self-made positively charged nanofi ltration(NF)membrane was used to treat textile dye effluent to generate water for reuse,and the factors affecting nanofi ltration process such as operating pressure,feed flow and membrane cleaning were investigated.With an applied pressure of 1.0 MPa and a feed flow of 40 L/h,this NF membrane has a removal of 93.3% for CODcr and a reduction of approximately 51.0% in TDS,salinity and conductivity achieving the chroma removal of 100%.The permeate obtained through this membrane is suitable for recycling.Moreover,the membrane could be reused after being cleaned with 1% NaOH solution.     

Influences of reinforcement on differential drying shrinkage of concrete

Shrinkage strain of concrete specimen with different reinforcement configuration was measured at various depths from the exposed surface by using several pairs of displacement sensors. Only one surface of the concrete specimen was exposed to dry condition during the experiment. The results show that differential shrinkage strain occurs in both plain and steel reinforced concrete specimens according to depths from the exposed surface. A higher reinforcement ratio results in a greater restraint against shrinkage of concrete nearby reinforcement rebar and a worse differential shrinkage strain distribution in the concrete specimen. The restraint against shrinkage of concrete becomes lower with the increasing distance from reinforcement rebar. Under the same reinforcement arrangement, a higher free shrinkage of concrete leads to a stronger restraint against shrinkage and a higher shrinkage stress formation in local concrete. The relationship between shrinkage strain and reduction of relative humidity in reinforced concrete structure is far different from that in plain concrete.     

LaNi4.1-xCo0.6Mn0.3Alx储氢合金结构及电化学储氢性能研究

为改善LaNi4.1 Co0.6 Mn0.3储氢合金的性能,研究了系列LaNi4.1-xCo0.6Mn0.3Alx(x=0,0.15,0.3,0.45)合金的结构和电化学储氢性能.结果表明:制备的合金为典型CaCu5型AB5储氢合金,随着A1替代量增加,LaNi5相的晶胞参数a、c、c/a值和晶胞体积逐渐增大,相应合金的放电容量有所降低,但合金电极的循环稳定性和不可逆自放电和高温容量得到明显改善.60个循环后的容量保持率(S60)分别为58.79％ (x=0)、79.72％(x=0.3)、79.35％(x=0.45);合金电极不可逆容量损失率(贮存96 h)由14.41％(x=0)降到2.38％ (x=0.45).在323 K的放电容量由266.04mA·h/g(x=0)增加到302.4mA·h/g(x=0.15)、302.12mA·h/g(x=0.3)和299.88 mA·h/g(x=0.45).但Al替代Ni后,合金电极的交换电流密度I0和氢原子在合金内部的氢扩散系数DH降低,导致其高倍率放电性能变差.     

A numerical study of rock burst development and strain energy release

We consider rock burst to be a dynamic disaster similar to earthquakes, rapid land sliding, or coal mine gas dynamic disasters. Multi-scale mechanical principles imply the same mechanism of damage evolution proceeds the catastrophe. Damage may occur at various scales from a meso-scopic scale to a macroscopic, or engineering scale. Rock burst is a catastrophe at the scale of the engineering structure, such as a tunnel cross section or the work face of a long wall mine. It results from dynamic fracture of the structure where microscopic damage nucleates, expands, and finally propagates into a macroscopic sized fracture band. Rock burst must, therefore, undergo a relatively long development, or gestation, time before its final appearance. In this paper, a study of rock burst within a deeply buried tunnel by numerical methods is described. The results show that during rock burst gestation the distributed microscopic damage in the rock surrounding the tunnel localizes, intersects, and then evolves into a set of concentrated “V” shaped damage bands. These concentrated damage bands propagate in the direction of maximum shear as shearing slide bands take shape. Rock burst happens within the wedge separated by the shear bands from the native tunnel rock. An analysis of the wedge fracture shows that the unloading effects result in rock burst and rapid release of the strain energy. The implications for rock burst prediction in tunnels are that: (1) rock burst develops in the upper arch corners of in the tunnel cross section prior to developing in other zones, so good attention must be paid there; (2) all monitoring, prevention, and treatment of rock burst should be done during the gestation phase; (3) the shear bands contain abundant information concerning the physics and mechanics of the process and they are the foundation of physical and mechanical monitoring of acoustic emission, micro seismic events, stress, and the like. Thus a special study of the shearing mechanism is required.