电子束辐照对医用一次性防护服材料断裂强力的影响

消毒灭菌是医用一次性防护服（简称医用防护服）生产过程中的重要环节,相比传统环氧乙烷灭菌,辐照灭菌更快速高效。由于医用防护服的防护性能有严格的标准要求,其材料的辐照效应具有重要研究意义。采用电子束加速器分别对聚丙烯（PP）、聚酯纤维（PET）、特卫强（Tyvek）3种材料的医用防护服样品进行不同吸收剂量的辐照处理,并进行不同时间的老化试验。针对GB 19082-2009中与辐照效应相关的主要性能指标进行测试。结果表明,50 kGy以下吸收剂量的电子束辐照对上述3种材料医用防护服的抗渗水性、抗合成血液穿透性、过滤效率等性能影响较小,但对PP和Tyvek材料的医用防护服断裂强力影响较大。通过双因素方差分析研究辐照和老化两种因素对上述3种材料医用防护服断裂强力影响的显著性。结果表明,吸收剂量和老化时间分别有不同的影响,其中吸收剂量对PP材料医用防护服样品断裂强力影响最显著。经验证,提升PP材料医用防护服的初始断裂强力,可使其辐照后性能满足标准。     

Synthesis,characterization, conductivity,band gap,and kinetic of thermal degradation of poly‐4‐[(2‐mercaptophenyl) imino methyl] phenol

The oxidative polycondensation reaction conditions of 4‐[(2‐mercaptophenyl) imino methyl] phenol (2‐MPIMP) were studied in an aqueous acidic medium between 40 and 90°C by using oxidants such as air, H₂O₂, and NaOCl. The structures of the synthesized monomer and polymer were confirmed by FTIR, ¹H NMR, ¹³C NMR, and elemental analysis. The characterization was made by TGA‐DTA, size exclusion chromatography (SEC) and solubility tests. At the optimum reaction conditions, the yield of poly‐4‐[(2‐mercaptophenyl) imino methyl]phenol (P‐2‐MPIMP) was found to be 92% for NaOCl oxidant, 84% for H₂O₂ oxidant 54% for air oxidant. According to the SEC analysis, the number‐average molecular weight (M_n), weight‐average molecular weight (M_w), and polydispersity index values of P‐2‐MPIMP were found to be 1700 g mol^?1, 1900 g mol^?1, and 1.118, using H₂O₂; 3100 g mol^?1, 3400 g mol^?1, and 1.097, using air; and 6750 g mol^?1, 6900 g mol^?1, and 1.022, using NaOCl, respectively. According to TG analysis, the weight losses of 2‐MPIMP and P‐2‐MPIMP were found to be 95.93% and 76.41% at 1000°C, respectively. P‐2‐MPIMP showed higher stability against thermal decomposition. Also, electrical conductivity of the P‐2‐MPIMP was measured, showing that the polymer is a typical semiconductor. The highest occupied molecular orbital, the lowest unoccupied molecular orbital, and the electrochemical energy gaps (E′_g) of 2‐MPIMP and P‐2‐MPIMP were found to be ?6.13, ?6.09; ?2.65, ?2.67; and 3.48, 3.42 eV, respectively. Kinetic and thermodynamic parameters of these compounds investigated by MacCallum‐Tanner and van Krevelen methods. The values of the apparent activation energies of thermal decomposition (E_a), the reaction order (n), pre‐exponential factor (A), the entropy change (ΔS*), enthalpy change (ΔH*), and free energy change (ΔG*) were calculated from the TGA curves of compounds. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Effect of polymer additives and process temperature on the physical properties of bitumen‐based composites

Polymer modified bitumen (PMB) is a binder obtained by the incorporation of polymer into the bitumen by mechanical mixing or chemical reaction. This study deals with the modification of bitumen with three types of polymers (LDPE, EVA, and SBS) in the presence of filler (CaCO₃). The morphological, mechanical, rheological properties, and thermal conductivity of the PMBs have been analyzed by scanning electron microscopy, tensile testing, melt flow index (MFI) measurements and hot wire method, respectively. The results indicate that the above‐mentioned properties of PMBs are influenced by polymer and bitumen nature and its composition. The mechanical properties of composites prepared at different temperatures exhibit small differences. In general, the inclusion of polymer increases tensile strength and Young's modulus and reduces percentage strain and MFI values, also, polymer inclusion reduces the thermal conductivity values of the composites. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

“人间佛教”理念下凝固的佛音——福建厦门莲花山佛心寺扩建规划设计

本文以厦门莲花山佛心寺扩建规划为例,对如何通过保护与建设、自然与人文、传统与现代、宗教与旅游、出世与入世等二元矛盾问题的综合思考,营造出具有闽南风格的现代佛寺进行的探讨。     

城市经营理念下对公共休憩空间的思考——以厦门为例

从城市经营理念出发,重审当前公共休憩空间的状况,并指出规划存在的误区并分析其根源,最后结合案例说明城市经营理念在公共休憩空间的意义和具体应用。     

水利专业毕业设计质量控制的研究与实践

在分析水利专业毕业设计质量存在的主要问题和原因的基础上,提出了毕业设计质量控制的原则和措施。扬州大学水利专业毕业设计质量控制实践表明,通过完善毕业设计质量控制体系,开展研究性教学和研究性学习,引导学生树立严谨、求实的设计思想,学生的创新思维和创新能力得到了培养,毕业设计质量有了显著提高。     

土体对悬臂挡墙模态的影响与应用

模态参数是损伤诊断和状态评估的关键性指标,但对悬臂挡墙,由于墙体结构与墙后半无限土体相互作用机理的复杂性,目前尚无有效的方法模拟出其模态参数。文章首先通过现场脉冲锤击模态试验得出墙土系统实际模态参数,并与忽略墙后土体作用下挡墙结构模态参数对比,表明墙后土体影响效应不可忽略的基础上,对墙后土体给予墙体附加刚度、质量计算方法进行了研究,并进而进行了考虑土体影响效应时挡墙的有限元模态分析,其结果与现场测试相吻合,从而证明了土体影响效应计算方法的合理性与脉冲锤击模态测试方法的可行性。最后,在此基础上对挡墙主要损伤及破坏状态下模态参数特征及诊断方法进行了研究;为悬臂挡墙健康诊断提供了一种快速、简便、无损、有效的模态分析检测法。     

Analysis of nitride storage non-volatile memories with HfSiOx blocking dielectric and TiN metal gate for low power embedded applications

Nitride storage non-volatile memories with hafnium silicate (HfSiO_x) blocking dielectric and titanium nitride (TiN) metal gate aimed at low power embedded applications beyond the 45 nm node, have been fabricated and investigated. In addition to presenting the typical figures of merit of flash memories, the scalability of the devices has been assessed. We have also investigated the physical origin of the observed memory features.     

一种陶瓷分散剂的合成工艺及应用性能

利用碱木质素代替部分苯酚合成了改性氨基磺酸系分散剂LMA,并考察了不同工艺条件下LMA对墙地砖陶瓷浆料应用性能的影响。结果表明,LMA的最优化反应条件为m(A):m(P):m(L):m(F)=1.00:0.29:0.68:0.84,其中碱木质素代替苯酚的替代率为70%,反应体系pH值10.5,缩合温度95℃,缩合时间3.0 h。对最优条件下合成的改性氨基磺酸系分散剂LMAY进行红外分析,证实碱木质素已成功引入。当陶瓷浆料固含量为68%时,LMAY最佳掺量为0.4%,此掺量下陶瓷浆料的流出时间为37.13 s,厚化度为1.25,优于无机盐分散剂。     

有机改性高岭土/聚氨酯纳米复合材料的制备与表征

用原位插层复合法制备了有机改性纳米高岭土/聚氨酯复合材料。研究了纳米复合材料的力学性能、耐热性能及纳米填料在复合材料中的形态。结果表明,当改性纳米高岭土质量分数为3%时,复合材料的拉伸强度为29.3 MPa、弹性模量达6.23 MPa、断裂伸长率达492%,均比纯聚氨酯弹性体增加10%以上,同时其热稳定性也有所提高;改性纳米高岭土加入量低于3%时,以剥离形态存在于聚氨酯基体中,而高于3%时,则开始出现片层形态且有团聚现象。