用离子束混合及快速热处理方法形成钽的硅化物

本文描述用离子束透过钽金属膜进行混合和快速热处理方法来形成钽的硅化物.用溅射方法在P型硅衬底上淀积一层金属钽,然后用砷离子束透过钽金属模进行混合,采用快速热处理后形成了平整的硅化钽薄层.使用厚度为500埃的钽金属膜,得到钽的硅化物薄层电阻为5.5Ω/□.研究了砷离子能量、剂量及钽膜厚度对钽的硅化物薄层电阻的影响.用透射电镜和台阶仪对所形成的硅化钽进行了分析和厚度测量.     

Bridging process and structure through criteria

Scholars in design face two central challenges in design methods inquiry: firstly, to integrate process and solution, and secondly, to examine developmental junctures leading to innovation. With these goals in mind, we maintain that design criteria deserve greater attention and illustrate this position with a study of noted designers' use of criteria. The primary finding was that five criteria functions were considered during the design process. The study also explored potential relationships between designer variables (i.e., professional expertise and personality type) and criteria use.     

微光CCD摄像器件综合特性的分析与比较

ＣＣＤ的优良特性使其在微光电视技术领域得到了广泛运用。本文对各种微光ＣＣＤ摄像器件的综合特性例如信噪比、探测率、动态范围与计数模式等进行了详细的研究与对比，并得出基本结论。     

氨基磺酸系高性能减水剂的研制开发

本文主要讨论了氨基磺酸系高性能减水剂的合成过程及后期混凝土试验情况。通过对反应温度、反应时间、溶液浓度和酸碱度、投料顺序及速度、第四单体的选择等反应条件的控制,合成具有最佳分子结构的最终产物,并通过红外光谱图和核磁共振谱图对合成主产物的分子结构进行了验证。同时,大量的混凝土试验说明氨基磺酸高性能减水剂具有优良的保坍性能。     

Scharnhauser公园学校和体育馆,奥斯特菲尔登

这个综合学校包括一个主建筑,一个体育馆和各种户外设施,朝向一片处在前军事基地上的住宅开发区。整个主建筑沿纵向被一个由顶部采光的回廊从中间分开,由此可以进入两侧的教室,回廊局部变宽的部分构成一个公共空间。这个构想与将城市设计理论运用于建筑内部设计的概念相符合:街道、广场和建筑被看成了建筑内部空间部分。虽然这个建筑从外部看来是个大体块,但内部空间却设计流畅,通道有的通向楼层的各个角落,也有的依着倾斜的地势因势而建。由墙面反射的散射光线加强了内部空间的肃穆和厚重感。在具有宗教感的整体风格下,整个学校的设计和装饰也显得古香古色,如一部宽阔的观光楼梯、两个塔形和壁炉形的建筑构成元素等。不同历史风格建筑的叠加给这个校区带来一种复杂的味道,堪比阿尔多·罗西(Aldo Rossi)的设计或泰辛(Tessin)新理性主义的代表作。     

The effect of pack-aluminisation on the microstructure of MCrAlY and the performance of thermal barrier coatings

Plasma spraying and pack-aluminising processes were combined and applied to the nickel-base superalloy Mar-M247 to improve its cyclic oxidation resistance. The performance tests of duplex ZrO₂-8 wt.%Y₂O₃/MCrAlY thermal barrier coatings (TBCs) were conducted at 1050 °C, 1075 °C, 1100 °C, 1150 °C and 1200 °C. The results of the experiments in this study showed that TBC specimens with the aluminised MCrAlY bond coat exhibited higher cyclic lives (except for the Ni-22Cr-10Al-1Y bond coat), at all the temperatures tested, than specimens on which the bond coat was not aluminised. The microstructures of the Co-29Cr-6Al-1Y, Co-32Ni-21Cr-8Al-0.5Y and Ni-22Cr-10Al-1Y bond coats with or without aluminising treatment were examined in detail using a scanning electron microscope equipped with an electron probe microanalyzer.     

Photoinduced bidirectional phase transitions in single crystals of polydiacetylenes

Photoinduced phase transitions have been observed between the two phases in single crystals of polydiacetylenes with side-groups of alkylurethanes. The threshold of the excitation intensity for the photochromism is extremely low, one absorbed photon per 140 repeated backbone units, indicating a collective nature of the photoconversion. The excitation spectra for the converted fraction clearly show that the photoinduced phase transition is mediated by photogeneration of polaronic species and not of singlet excitons.     

Chiroptical activity of holmium pyrogermanate: tetragonal Ho2Ge2O7

Chiroptical luminescence and circular dichroism measurements are reported for single crystals of Ho₂Ge₂O₇. These crystals belong to the tetragonal space group P4,2,2 (or P4₃2₁2) with Z=4. Each Ho³⁺ ion in the crystal structure is coordinated to seven oxygens to form a distorted pentagonal bipyramid. The Ho³⁺ ions exhibit luminescence from several excited multiplet levels; chiroptical luminescence spectra are reported for ⁶I₈ → ⁶F₆, ⁶S₂, and ⁶F₃ at a sample temperature of 10 K. Room-temperature absorption and circular dichroism measurements are reported for the ⁶I₈ → ⁶F₆, ⁵S₂, ⁶F₄, and ⁶F₃ transition regions.