CO2 absorption into a phase change absorbent: Water-lean potassium prolinate/ethanol solution

Phase change solvents are attractive energy-efficient absorbents for carbon dioxide (CO₂) capture due to CO₂-rich phase formation. Potassium prolinate + water + ethanol (ProK/W/Eth) solution has shown good capture characteristics as a promising one in our previous work. In this work, absorption rate of CO₂, solubility of N₂O, and heat of absorption for ProK/W/Eth solution were investigated using a stirred cell reactor and a CPA201 reaction calorimeter and these results were also compared with the aqueous ProK and 30 mass% MEA solutions. Using ethanol as a solvent can substantially increase the CO₂ physical solubility and the absorption rate of CO₂ in ProK/W/Eth solutions is far higher than that in aqueous 30 mass% MEA solutions especially at a low CO₂ loading range. Solid precipitation, obtained from the liquid-to-solid phase change absorption, was analyzed by ¹³C NMR and DSC-TGA. The enthalpy change for ProK/W/Eth solutions at various CO₂ loading was also discussed.     

An overview on the applications of the hesitant fuzzy sets in group decision-making: theory,support and methods

Due to the characteristics of hesitant fuzzy sets (HFSs), one hesitant fuzzy element (HFE), which is the basic component of HFSs, can express the evaluation values of multiple decision makers (DMs) on the same alternative under a certain attribute. Thus, the HFS has its unique advantages in group decision making (GDM). Based on which, many scholars have conducted in-depth research on the applications of HFSs in GDM. We have viewed lots of relevant literature and divided the existing studies into three categories: theory, support and methods. In this paper, we elaborate on hesitant fuzzy GDM from these three aspects. The first aspect is mainly about the introduction of HFSs, HFPRs and some hesitant fuzzy aggregation operators. The second aspect describes the consensus process under hesitant fuzzy environment, which is an important support for a complete decision-making process. In the third aspect, we introduce seven hesitant fuzzy GDM approaches, which can be applied in GDM under different decision-making conditions. Finally, we summarize the research status of hesitant fuzzy GDM and put forward some directions of future research.     

Electro-conductive Nanocrystalline Cellulose Film Filled with TiO2-Reduced-Graphene Oxide Nanocomposite

Imparting electro-conductive properties to nanocellulose-based products may render them suitable for applications in electronics, optoelectronics, and energy storage devices. In the present work, an electro-conductive nanocrystalline cellulose (NCC) film filled with TiO₂-reduced-graphene oxide (TiO₂-RGO) was developed. Initially, graphene oxide (GO) was prepared using the modified Hummers method and thereafter photocatalytically reduced using TiO₂ as a catalyst. Subsequently, an electro-conductive NCC film was prepared via vacuum filtration with the as-prepared TiO₂-RGO nanocomposite as a functional filler. The TiO₂-RGO nanocomposite and the NCC/TiO₂-RGO film were systematically characterized. The results showed that the obtained TiO₂-RGO nanocomposite exhibited reduced oxygen-containing group content and enhanced electro-conductivity as compared with those of GO. Moreover, the NCC film filled with TiO₂-RGO nanocomposite displayed an electro-conductivity of up to 9.3 S/m and improved mechanical properties compared with that of the control. This work could provide a route for producing electro-conductive NCC films, which may hold significant potential as transparent flexible substrates for future electronic device applications.     

Thermal optimization and experimental research of high-speed universal pulverizer

Because of high efficiency, energy conservation, simple operation, wide application range, and small size, the high-speed universal pulverizer has been well received by customers. However, its electrical motor can overheat when working, which hinders continuous operation of the pulverizer. In this study, a series of efforts were made to address this problem. Firstly, a detailed analysis of the working principle of the pulverizer was conducted and an optimization plan was proposed, consisting in punching ventilation holes on the surface of the original pulverizer. Simulations of the pulverizer flow field before and after optimization were performed. The hydrodynamic simulation results were used to conduct a steady state thermal analysis of the pulverizer, investigating the influence of the flow field on heat transfer. Additionally, experimental investigations were conducted on the pulverizer before and after optimization in order to measure and compare the parameters (motor working temperature, wind speed and temperature of the motor cooling system, vibration, noise, and pulverizing degree of the material) influencing the performance of the pulverizer. The numerical simulation results showed an increment in heat transfer caused by increment in air flow volume and velocity when air was injected into the pulverizer through bottom and side holes. Experimental results showed that the pulverizer with air injection through holes had the best performance when temperature, vibration, and refinement effect were considered as performance indicators. The full text can be downloaded at https://link.springer.com/article/10.1007/s40436-017-0208-3     

A 4-channel coil array interconnection by analog direct modulation optical link for 1.5-T MRI

Optical glass fiber shows great advantages over coaxial cables in terms of electromagnetic interference, thus, it should be considered a potential alternative for magnetic resonance imaging (MRI) receive coil interconnection, especially for a large number coil array at high field. In this paper, we propose a 4-channel analog direct modulation optical link for a 1.5-T MRI coil array interconnection. First, a general direct modulated optical link is compared to an external modulated optical link. And then the link performances of the proposed direct modulated optical link, including power gain, frequency response, and dynamic range, are analyzed and measured. Phantom and in vivo head images obtained using this optical link are demonstrated for comparison with those obtained by cable connections. The signal-to–noise (SNR) analysis shows that the optical link achieves 6%–8% SNR a improvement over coaxial cables by elimination of electrical interference between cables during MR signal transmission.      

Classification of fMRI time series in a low-dimensional subspace with a spatial prior

We propose a new method for detecting activation in functional magnetic resonance imaging (fMRI) data. We project the fMRI time series on a low-dimensional subspace spanned by wavelet packets in order to create projections that are as non-Gaussian as possible. Our approach achieves two goals: it reduces the dimensionality of the problem by explicitly constructing a sparse approximation to the dataset and it also creates meaningful clusters allowing the separation of the activated regions from the clutter formed by the background time series. We use a mixture of Gaussian densities to model the distribution of the wavelet packet coefficients. We expect activated areas that are connected, and impose a spatial prior in the form of a Markov random field. Our approach was validated with in vivo data and realistic synthetic data, where it outperformed a linear model equipped with the knowledge of the true hemodynamic response.     

Simultaneous determination of sulphamerazine, sulphamethazine and sulphadiazine in honey and chicken muscle by a new monoclonal antibody-based fluorescence polarisation immunoassay

A new monoclonal antibody (Mab) against sulphamerazine (SMR) was produced and a fluorescence polarisation immunoassay (FPIA) based on the Mab was developed and optimized for the simultaneous qualitative screening of SMR, sulphamethazine (SMZ) and sulphadiazine (SDZ). The Mab, raised from mice immunized with SMR, was bound to bovine serum albumin (BSA) using glutaraldehyde as the coupling reagent. Fluorescein-labelled SMR and SMZ (tracer) were synthesized and purified by thin layer chromatography (TLC). Cross-reactivities below 3.6% were displayed in the optimized FPIA for another 14 sulphonamides when both tracers were employed. The limits of detection (LOD) were 0.9 ng g(-1) for SMR, 2 ng g(-1) for SMZ and 3.1 ng g(-1) for SDZ. Analysis of SMR, SMZ and SDZ fortified chicken muscle and honey samples by the FPIA showed average recoveries of 86-131% with a standard deviation (SD) of 4.6-32. Comparative analyses of a SMZ-treated chicken muscle sample by both FPIA and high performance liquid chromatograph (HPLC) showed a good correlation (r = 0.9991). The study demonstrates the practical application of FPIA in screening chicken muscle and honey samples for sulphonamides residues.     

A digital microfluidic droplet generator produces self-assembled supramolecular nanoparticles for targeted cell imaging

Controlling the size distribution of polymer-based nanoparticles is a challenging task due to their flexible core and surface structures. To accomplish such as task requires very precise control at the molecular level. Here we demonstrate a new approach whereby uniform-sized supramolecular nanoparticles (SNPs) can be reliably generated using a digital microfluidic droplet generator (DMDG) chip. A microfluidic environment enabled precise control over the processing parameters, and therefore high batch-to-batch reproducibility and robust production of SNPs with a very narrow size distribution could be realized. Digitally adjustment of the mixing ratios of the building blocks on the DMDG chip allowed us to rapidly scan a variety of synthesis conditions without consuming significant amounts of reagents. Nearly uniform SNPs with sizes ranging from 35 to 350?nm were obtained and characterized by transmission electron microscopy and dynamic light scattering. In addition, we could fine-tune the surface chemistry of the SNPs by incorporating an additional building block functionalized with specific ligands for targeting cells. The sizes and surface properties of these SNPs correlated strongly with their cell uptake efficiencies. This study showed a feasible method for microfluidic-assisted SNP production and provided a great means for preparing size-controlled SNPs with desired surface ligand coverage.     

Fabrication of microneedles using two photon polymerization for transdermal delivery of nanomaterials

Microneedle devices for transdermal delivery of nanoscale pharmacologic agents were fabricated out of organically-modified ceramic (Ormocer) materials using two photon polymerization. Out-of-plane hollow microneedle arrays with various aspect ratios were fabricated using this rapid prototyping process. Human epidermal keratinocyte (HEK) viability on Ormocer surfaces fabricated using two photon polymerization was similar to that on control surfaces. Nanoindentation studies were performed to determine hardness and Young's modulus values for Ormocer materials. Microneedies were shown to enable more rapid distribution of the PEG-amine quantum dot solution to the deep epidermis and dermis layers of porcine skin than topical administration. Our results suggest that two photon polymerization may be used to create microneedle arrays for transdermal delivery of nanoscale pharmacologic agents.     

Effect of shell layers on luminescence of colloidal CdSe/Zn(0.5)Cd(0.5)Se/ZnSe/ZnS core/multishell quantum dots

Colloidal CdSe/Zn(0.5)Cd(0.5)Se/ZnSe/ZnS core/multishell quantum dots (QDs) were synthesized by using the well developed successive ion layer adsorption and reaction (SILAR) technique. The UV-vis and PL spectra, TEM, X-ray diffraction and Raman measurement were performed to investigate the structure and optical properties of prepared QDs during the growth of shell layers, which indicated that the stress in CdSe core became stronger with the increasing shell thickness. Due to the gradual adjustment of the lattice parameters in the radial direction and the radial increase of the respective valence- and conduction-band offsets, the optical measurements show a significant enhancement in the photoluminescence quantum yield (QY) and an expedited radiative decay in QDs overcoated with thicker shell. The temperature-dependent optical spectra were measured, and the relation between the microstructure and the optical properties of these core/multishell quantum dots was discussed.