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21.
The reaction between Pb and HNO3 has been investigated using the thermometric technique. Weight-loss measurements on the reaction were also obtained. As the HNO3 concentration is increased from 5×10–2 to 4mol l–1, the corrosion rate increases. This is shown thermometrically by a substantial increase in the maximum temperature attained, T
m, as well as a decrease in the time, t, required for reaching T
m. Dissolution of Pb in HNO3 is proposed to take place according to an autocatalytic mechanism. Passivation sets were detected in solutions 11 mol l–1 HNO3. A parallel indication between the thermometric technique and weight-loss measurements was obtained. The rate-determining step of the autocatalytic process involves HNO2 in dissolution of Pb in HNO3. This is supported by the results of addition of hydrazine to the solution. This additive raises the maximum measured temperature, without affecting the corresponding time necessary to reach it. The effect of addition of NaNO2, NaNO3, NaCl, Na2SO4, NaH2PO4 and NaClO4 on the reaction number, RN, of Pb in 4 mol l–1 HNO3 was examined. Only NaNO2 accelerates the dissolution reaction while the other salts show as inhibition effect. It was found that these additives inhibit dissolution due to the displacement of some cathodic depolarizing components, as NO2, from the active sites on the metal surface. The effect of addition of HCl, H2SO4, HClO4 and H3PO4 on the reaction number, RN, of Pb in 4 mol l–1 HNO3 was also investigated. The observed acceleration and retardation of the dissolution of Pb was found to be dependent on both the concentration and nature of anions of the extra acids added. 相似文献
22.
Farouk M. Slibi Dhia-Aldin Abd El-Fattah Z. M. Atallah M. El-Sherbiny M. A. Hassan Moukhtar A. 《SILICON》2021,13(9):3003-3010
Silicon - Melt-quenching technique was used to prepare borosilicate glasses of composition xSiO2- (75-x) B2O3–24.7Li2O-0.3Cr2O3 (x = 0, 10, 20, 30, 40 and 50 mol%). With... 相似文献
23.
Abd El-Aziz S. Fouda Mohamed A. Ismail Abdulraqeb A. Al-Khamri Ashraf S. Abousalem 《中国化学工程学报》2021,40(12):197-217
This study describes the adsorption behavior of three arylthiophene derivatives namely: 2-(4-amidino-3-fluorophenyl)-5-[4-methoxy phenyl] thiophene dihydrochloride salt (MA-1217), 2-(4-amidinophenyl)-5-[4-chlorophenyl] thiophene dihydrochloride salt (MA-1316) and 2-(4-amidino-3-fluorophenyl)-5-[4-chlorophenyl]thiophene dihydrochloride salt (MA-1312) at C-steel in 1.0 mol·L-1 HCl interface using experimental and theoretical studies. Electrochemical and mass loss measurements showed that the inhibition efficiency (IE) of the arylthiophene derivatives increases with increasing concentrations and exhibited maximum efficiency 89% at 21×10-6 mol·L-1 (MA-1217) by mass loss method. The investigated arylthiophene derivatives obey the Langmuir adsorption isotherm. From polarization studies the arylthiophene derivatives act as mixed-type inhibitors. Surface analysis were carried out and discussed. The mode of orientation and adsorption of inhibitor molecules on C-steel surface was studied using molecular dynamics (MD) simulations. Quantum chemical parameters as well as the radial distribution function indices and binding energies confirm the experimental results. 相似文献
24.
25.
Nor Aziah Buang Zaiton Abd. Majid Yusran Sulaiman Suhaila M. Sanip Ahmad Fauzi Ismail 《Journal of Porous Materials》2006,13(3-4):331-334
Production of novel porous material is a major target in current material science research due to its wide applications. As carbon nanotube (CNTs) is a one dimensional hollow structure it is also one of the promising materials in applications ranging from electronics to hydrogen storage medium. Catalytic chemical vapor deposition (CCVD) is a method whereby CNTs can be produced in large amount. Thus, in this work, we have synthesized CNTs via pyrolysis of acetylene using various supported transition-metal catalysts in a fixed-bed reactor. Scanning electron microscope (SEM) and transmission electron microscope (TEM) were used to investigate the CNTs structure. The structures of nanotubes formed by acetylene pyrolysis were dependent on the catalysts used. It was found that alumina supported Ni/Fe catalyst inhibited the formation of CNTs growth while alumina supported Ni/Co catalyst gave high density of CNTs. However, nanotubes grown over alumina supported Ni/Fe catalyst were less dense due to the deactivation of the catalyst at the early stage of the pyrolysis process. 相似文献
26.
Electrocopolymerization of a binary mixture of 3‐chloroaniline and 2‐amino‐4‐phenylthiazole on platinum electrode in acid medium was carried out under different reaction conditions such as temperature, current density, hydrochloric acid, and monomer concentrations with duration time. The initial rate of the electrocopolymerization reaction on platinum electrode is small and the rate law is Rp = K2 [D]1.29[HCl]0.97[M]1.94. The apparent activation energy is found to be 38.87 kJ/mol. The obtained copolymer film is characterized by 1H‐NMR, elemental analysis, GPC IR, UV‐visible, and cyclic voltammetry and compared with those of the two homopolymers. The mechanism of the electrocopolymerization reaction is also discussed and the monomer reactivity ratio (r1and r2) is calculated. The thermogravimetric analysis (TGA) is used to confirm the proposed structure and determination of the number of water molecules in the polymeric chain unit. X‐ray and scanning electron microscopic analysis are used to investigate the surface morphology. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 2076–2087, 2005 相似文献
27.
In this paper, a novel watermarking scheme for quantum images based on Hadamard transform is proposed. In the new scheme, a unitary transform controlled by a classical binary key is implemented on quantum image. Then, we utilize a dynamic vector, instead of a fixed parameter as in other previous schemes, to control the embedding process. The dynamic embedding vector is decided by both the carrier quantum image and the watermark image, which is only known by the authorized owner. The proposed scheme is analyzed from visual quality, computational complexity, and payload capacity. Analysis and results show that the proposed scheme has better visual quality under a higher embedding capacity and lower complexity compared with other schemes proposed recently. 相似文献
28.
Although leather has a number of desirable properties such as thermal stability and fire retardancey, in addition to high toughness, it has a few drawbacks such as weight, high water absorption, poor soil and rot resistance, and nonuniformity. If these defects are overcome, leather's usefulness would be further enhanced and its competitive position with respect to synthetics would increase. This study reports the physical and mechanical properties of buffalo leather after chemical graft copolymerization with ethyl acrylate, butyl acrylate, and 2‐ethyl hexyl acrylate using benzoyl peroxide as an initiator. The optimum conditions for grafting (e.g., monomer and initiator concentrations, temperature and time of grafting, and solvent leather ratio) were extensively investigated. The study achieved outstanding properties for buffalo leather in reduction of water uptake after grafting, especially on using 2‐ethyl hexyl acrylate and butyl acrylate monomers. FT‐IR and solid 13C‐NMR for leather before and after grafting confirmed the grafting process.© 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1478–1483, 2003 相似文献
29.
M. Amine Abou-State Fouad F. Abd El-Megeid 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1972,22(9):993-999
Egyptian cotton linters were pulped by the nitric acid process. In order to reduce the high ash and silica contents of the resulting pulps it was found necessary to apply hot refining with sodium hydroxide solution. Different conditions of concentration, temperature, and pressure in the refining step were investigated. Refining before and during bleaching were compared. 相似文献
30.
S.A.Abd El-Maksoud 《Electrochimica acta》2004,49(24):4205-4212
Phthalazin derivatives were tested as corrosion inhibitors of copper in 1 M H2SO4 using electrochemical polarization and weight loss techniques. This study monitored the evolution of the inhibitory effect of the phthalazin derivatives, according to their substituents. A significant decrease in the corrosion rate of copper was observed in the presence of the investigated inhibitors. The inhibition efficiency (%I) increases with increasing inhibitor concentration. The potentiodynamic polarization data indicated that, the inhibitors were of mixed type, but the cathodic effect is more pronounced. The slopes of the cathodic and anodic Tafel lines are approximately constant and independent on the inhibitor concentration. The mechanism of inhibition was discussed in the light of the chemical structure of the undertaken inhibitors. The adsorption on the copper surface follows the Langmuir isotherm model. 相似文献