Electronic,Magnetic, Electric and Magnetocaloric Properties of the Multiferroic Orthorhombic YMnO3

Journal of Superconductivity and Novel Magnetism - Multiferroic oxide materials have attracted much intention in recent years due to their application in different fields such as magnetic...     

Molecular weight influence on shape memory effect of shape memory polymer blend (poly(caprolactone)/styrene-butadiene-styrene)

The shape memory effect (SME) does not only concern the macroscopic structure. It concerns also the polymer structure at morphological, macromolecular, and molecular scales. This effect may depend on different physicochemical properties like morphology heterogeneity, chain rigidity, steric hindrance, chain polarity, free volume, cross-linking or entanglement density, molecular shape and weight, and so on. Hence, finding the relationship between the SME and these properties is very important. This can help to obtain the knowledge about the phenomenon origin and mechanism. One of the basic polymer properties, which can have direct SME, may be the molecular weight (M_w ). The question here is: If the M_w of a shape memory polymer (SMP) changes, for different reasons like degradation, what will be the effect of this change on its SME. In order to answer to this question, the investigation is focused on an SMP blend of 40% poly(ɛ-caprolactone) (PCL) and 60% styrene-butadiene-styrene (SBS). Then, enzymatic hydrolysis is performed on this blend to change its M_w . It is shown that this change is only related to the variation in the M_w of PCL. After that, different samples with a distinct average M_w are prepared and characterized by various experimental methods. Shape memory tests are performed on these blends, and the recovery rate (R_r ) for each of them is determined. It is found that when M_w of PCL decreases, its degree of crystallinity, its glass transition, and its melting temperatures, corresponding to the PCL phase, increase. However, the elongation at break of the blend declines with the reduction in M_w . The tests show that the alteration in the blend's M_w influences its SME. Indeed, R_r of the (PCL/SBS) mixture drops with the decrease in M_w of PCL.     

Solid-Phase Synthesis of Substrate-Based Dipeptides and Heterocyclic Pseudo-dipeptides as Potential NO Synthase Inhibitors

More than 160 arginine analogues modified on the C-terminus via either an amide bond or a heterocyclic moiety (1,2,4-oxadiazole, 1,3,4-oxadiazole and 1,2,4-triazole) were prepared as potential inhibitors of NO synthases (NOS). A methodology involving formation of a thiocitrulline intermediate linked through its side-chain on a solid support followed by modification of its carboxylate group was developed. Finally, the side-chain thiourea group was either let unchanged, S-alkylated (Me, Et) or guanidinylated (Me, Et) to yield respectively after TFA treatment the corresponding thiocitrulline, S-Me/Et-isothiocitrulline and N-Me/Et-arginine substrate analogues. They all were tested against three recombinant NOS isoforms. Several compounds containing a S-Et- or a S-Me-Itc moiety and mainly belonging to both the dipeptide-like and 1,2,4-oxadiazole series were shown to inhibit nNOS and iNOS with IC₅₀ in the 1–50 μM range. Spectral studies confirmed that these new compounds interacted at the heme active site. The more active compounds were found to inhibit intra-cellular iNOS expressed in RAW264.7 and INS-1 cells with similar efficiency than the reference compounds L-NIL and SEIT.     

Ultraviolet radiation aging impact on physicochemical properties of crosslinked polyethylene cable insulation

This article deals within the study of the effect of artificial radiations on physical and chemical properties of the crosslinked polyethylene (XLPE) material, widely used for manufacturing high-voltage cables. Within this framework, several experimental tests, using essential characterization techniques, were performed to study XLPE behavior under ultraviolet (UV) aging. Attenuated total reflection Fourier transform infrared spectroscopy, differential scanning calorimetry, thermogravimetric analysis, X-ray diffraction, and scanning electron microscopy were thus carried out to identify the main structure changes of the material before and after exposure to UV. In addition, appearance changes and DC (Direct Current) volume resistivity were evaluated. The obtained results showed that UV radiation has a great effect on the physicochemical properties of XLPE cable insulation. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48575.     

Geothermal and solar energy–based multigeneration system for a district

In this study, parabolic trough collector with an integrated source of geothermal water is used with regenerative Rankine cycle with an open feedwater heater, an electrolyzer, and an absorption cooling system. The absorption fluids used in the solar collectors were Al₂O₃‐ and Fe₂O₃‐based nanofluids. Detailed energetic and exergetic analyses are done for the whole system including all the components. A comparative analysis of both the used working fluids is done and plotted against their different results. The parameters that are varied to change the output of the system are ambient temperature, solar irradiance, the percentage of nanofluids, the mass flow rate of the geothermal well, the temperature gradient of the geothermal well that had an effect on the net power produced, and the outlet temperature of the solar collector overall energetic and exergetic efficiencies. Other useful outputs by this domestic integrated multigeneration system are the heating of domestic water, space heating (maintaining the temperature at 40°C‐50°C), and desalination of seawater (flash distillation). The hydrogen production rate for both the fluids diverges with each other, both producing average from 0.00490 to 0.0567 g/s.     

Unconstrained Hand Dorsal Veins Image Database and Recognition System

Hand veins can be used effectively in biometric recognition since they are internal organs that, in contrast to fingerprints, are robust under external environment effects such as dirt and paper cuts. Moreover, they form a complex rich shape that is unique, even in identical twins, and allows a high degree of freedom. However, most currently employed hand-based biometric systems rely on hand-touch devices to capture images with the desired quality. Since the start of the COVID-19 pandemic, most hand-based biometric systems have become undesirable due to their possible impact on the spread of the pandemic. Consequently, new contactless hand-based biometric recognition systems and databases are desired to keep up with the rising hygiene awareness. One contribution of this research is the creation of a database for hand dorsal veins images obtained contact-free with a variation in capturing distance and rotation angle. This database consists of 1548 images collected from 86 participants whose ages ranged from 19 to 84 years. For the other research contribution, a novel geometrical feature extraction method has been developed based on the Curvelet Transform. This method is useful for extracting robust rotation invariance features from vein images. The database attributes and the veins recognition results are analyzed to demonstrate their efficacy.     

Similarity based image selection with frame rate adaptation and local event detection in wireless video sensor networks

Wireless Video Sensor Networks (WVSNs7unding environmental information. Those sensor nodes can locally process the information and then wirelessly transmit it to the coordinator and to the sink to be further processed. As a consequence, more abundant video and image data are collected. In such densely deployed networks, the problem of data redundancy arises when information are gathered from neighboring nodes. To overcome this problem, one important enabling technology for WVSN is data aggregation, which is essential to be cost-efficient. In this paper, we propose a new approach for data aggregation in WVSN based on images and shot similarity functions. It is deployed on two levels: the video-sensor node level and the coordinator level. At the sensor node level the proposed algorithms aim at reducing the number of frames sensed by the sensor nodes and sent to the coordinator. At the coordinator level, after receiving shots from different neighbouring sensor nodes, the similarity between these shots is computed to eliminate redundancies and to only send the frames which meet a certain condition to the sink. The similarity between shots is evaluated based on their color, edge and motion information. We evaluate our approach on a live scenario and compare the results with another approach from the literature in terms of data reduction and energy consumption. The results show that the two approaches have a significant data reduction to reduce the energy consumption, thus our approach tends to overcome the other one in terms of reducing the energy consumption related to the sensing process, and to the transmitting process while guaranteeing the detection of all the critical events at the node and the coordinator levels.

     

Characterization and sustainable management strategies of municipal solid waste in Egypt

Clean Technologies and Environmental Policy - The aim of the present study was to establish a national database of waste characteristics for Egypt to support the assessment of various waste...     

How Can Lean Manufacturing Lead the Manufacturing Sector during Health Pandemics Such as COVID 19: A Multi Response Optimization Framework

Lean manufacturing has been used for the last few decades as a process and performance improvement tool. Initially known as Toyota production system (TPS), lean is now used in almost all service and manufacturing sectors to deliver favorable results such as decreased operational cost, increased customer satisfaction, decreased cycle time, and enhanced profits. During the coronavirus disease (COVID 19) pandemic, the manufacturing sector struggled immensely and could not function well even after lockdown was eased in many countries. Many companies found out there are not ready to conform with new regulations made by authorities in many countries. This paper proposes the use of simulation and multi response optimization in addition to other typical lean tools in order to arrive at optimum performance at the end of each project through an established optimization framework. The framework is used in a real case study performed at an aluminum extrusion factory. Lean manufacturing helps organizations to operate with smaller number of resources. It standardizes all processes so that most of the jobs can be done by most of the workers, but this is not enough to create a healthy, sanitized work place. Our framework utilizes the strengths of lean tools and adds pandemic readiness factor to them to ensure improvement in performance and health pandemic readiness. Implementation of the framework in the case company resulted in 50% reduction in labor, $730000 in expected annual cost savings, reduction in inventory levels, improved employee morale and the achievement of pandemic ready status.