Crack arrest and stress dependence of laser-induced surface damage in fused-silica and borosilicate glass

Results of experiments on stress-inhibited laser-driven crack growth and stress-delayed laser-damage initiation thresholds in fused silica, borosilicate glass (BK-7), and cleaved bulk silica are presented. A numerical model is developed to explain the crack arrest in fused silica. Good agreement is obtained between the model and a finite-element code. The crack arrest is demonstrated to be the result of the breaking of a hoop-stress symmetry that is responsible for crack propagation in fused silica.     

Effect of surface roughness and complex indices of refraction on polarized thermal emission

We present a series of measurements characterizing the dependence of polarized thermal emission on surface roughness. In particular, we measure the spectrally resolved degree of linear polarization (DOLP) for a series of roughened borosilicate (Pyrex) glass substrates as a function of the roughness parameter Ra, the root-mean-square slope distribution, and observation angle theta. Also measured are a series of smooth glass substrates coated with two particular polymers of interest, i.e., a common commercially available Krylon paint and a chemical-agent-resistant coating paint. The DOLP is measured over a 4-13 microm wave band by using a modified Fourier transform IR spectrometer in which a wire-grid polarizer and a quarter-wave Fresnel rhomb are used in conjunction to measure all four Stokes parameters. In addition, we show an enhanced DOLP due to anomalous dispersion exhibited by the surface material.     

In situ infrared aerosol spectroscopy for a variety of nerve agent simulants using flow-through photoacoustics

We present newly measured results of an ongoing experimental program established to measure optical cross sections in the mid- and long-wave infrared for a variety of chemically and biologically based aerosols. For this study we consider only chemically derived aerosols, and in particular, a group of chemical compounds often used as simulants for the detection of extremely toxic organophosphorus nerve agents. These materials include: diethyl methylphosphonate (DEMP), dimethyl methylphosphonate (DMMP), diisopropyl methylphosphonate (DIMP), and diethyl phthalate (DEP). As reported in a prior study [Appl. Opt. 44, 4001 (2005)], we combine two optical techniques well suited for aerosol spectroscopy [i.e., flow-through photoacoustics and Fourier transform infrared (FTIR) emission spectroscopy], to measure in situ the absolute extinction and absorption cross sections over a variety of wavelengths spanning the IR spectral region from 3 to 13 mum. Aerosol size distribution(s), particle number density, and dosimetric measurements are recorded simultaneously in order to present optical cross sections that are aerosol mass normalized, i.e., m(2)/gram. Photoacoustic results, conducted at a series of CO(2) laser lines, compare well with measured broadband FTIR spectral extinction. Both FTIR and photoacoustic data also compare well with Mie theory calculations based on measured size distributions and previously published complex indices of refraction.     

MEMS multi-vibrating ring gyroscope for space applications

Microsystem Technologies - This paper presents the design of a novel multi-ring vibratory gyroscope. The design incorporates two sets of rings, inner and outer, separated by a set of perforated...     

Improvements of the reactivity devices modeling for the advanced CANDU reactor

In the context of the ACR™ (Advanced CANDU Reactor), 3D transport calculations are required in order to simulate the reactivity devices located perpendicularly to the fuel channels. The computational scheme that is usually used for CANDU-6 and ACR reactors is based on a simplified supercell geometry in which the fuel clusters and devices are replaced by annuli. Recently, an exact modeling of 3D supercell configurations was introduced within the framework of the ACR calculations. However, with such a model, fine meshing requirements lead to problems that are very demanding in terms of computational resources.

In this paper, we present improvements introduced in the ACR context to reduce the cost of the 3D supercell calculations. Two avenues of investigations are reported. First, the introduction of an accelerated characteristics method permits to reduce the computational burden of such calculations involving a large number of regions. In addition, contrarily to CANDU-6 supercell configurations, the ACR 3D geometry is prismatic and consequently a special tracking procedure can be used. This approach introduces no approximation and is significantly faster than the general 3D tracking technique. Thanks to these modifications in the computational procedure, 3D supercell calculations with a level of mesh discretization comparable to 2D cell configurations become affordable for industrial applications.     

A simplified αβ based Gaussian sum filter

State estimation is a major problem in many fields, such as target tracking. For a linear Gaussian dynamic system, the KF provides the optimal state estimate, in the minimum mean square error sense. In general, however, real-world systems are governed by the presence of non-Gaussian noise and/or nonlinear systems. In this paper, the problem of state estimation in the case of a linear system affected by a non-Gaussian measurement noise is addressed. Based on the theoretical framework of the Gaussian sum filters (GSF), we propose a novel static version of this filter that uses the well known αβ filter. The simulation results show that the proposed filter has acceptable performances in terms of RMSE and a reduced computational load, compared to the classical GSF.     

Modeling reactivity devices for advanced CANDU reactors using the code DRAGON

Full core analysis of typical power reactors generally performed uses few group diffusion theory, it is necessary to generate beforehand, using a lattice code, the required few group cross-sections and diffusion coefficients associated with each region in the core.

For the ACR™ (Advanced CANDU Reactor), the problem is more complex because these reactors contain vertical reactivity devices that are located between two horizontal fuel bundles. The usual calculation scheme relies in this case on a 2D fuel cell calculation to generate the few group fuel properties and on a 3D supercell calculation for the analysis of the reactivity devices present in the core. Because of its complexity, the supercell calculations have usually been performed using simplified fuel geometries. The development of new geometry features in DRAGON and the availability of faster computers have made it possible to improve the 2D cell and 3D supercell models by using explicitly 3D assemblies of clusters to simulate the reactivity devices in CANDU reactors, including the ACR. These studies will thus improve the fine reactor core results by generating more accurate and appropriate reactor databases.

In this paper, we will review the lattice-cell/supercell calculation procedure using the code DRAGON by introducing a new supercell model. The use of such an explicit 3D geometry implies a very fine spatial mesh discretization that can generate a large number of regions leading to problems that cannot be solved by the collision probability (CP) method. The method of characteristics (MoC) is then the only alternative for such cases. A comparison of results using these two methods will also be presented for 3D models with a coarse mesh discretization.     

Antioxidant Activity of the Essential Oil and Oleoresin of Zingiber Officinale Roscoe as Affected by Chemical Environment

Three different biochemical test systems were chosen based on their solubility to study the antioxidant activity of ginger extracts. Reducing power and DPPH^. scavenging activity tests were considered to produce hydrophilic environments and the H₂O₂ test was considered as creating a lipophilic environment. The average yields were 10.23 ± 1.02% and 0.48 ± 0.19% for oleoresin and essential oil, respectively. The content of total phenols was 67.6 ± 1.08 mg GAE/g of dry extract. In terms of EC₅₀, in hydrophilic environment standards, it showed the highest effects compared to ginger extracts, with oleoresin presenting more activity than essential oil. In contrast, except for quercetin, essential oil showed the best scavenging activity in inhibiting H₂O₂ compared to all other antioxidants. The present work demonstrated that, when using reducing power, DPPH· free radical scavenging and H₂O₂ scavenging assays, the same ginger extracts exhibit different antioxidant activities, which were affected not only by the extract itself but also by the chemical environment (hydrophilic/lipophilic).     

Biosorption of mercury from aqueous solutions by powdered leaves of castor tree (Ricinus communis L.)

A new biosorbent produced from castor leaves powder [Ricinus communis L.] was used to remove mercury(II) from aqueous solutions. The initial mercury concentrations, contact time and initial pH were evaluated. The ability of castor leaves to remove mercury at various pH (2-8) was studied. The maximum capacity (Qmax) of biomass was found to be 37.2mg Hg(II)/g at pH 5.5. Biosorption equilibrium was established in approximately 1h. The equilibrium data were described well by Langmuir and Freundlich models. The adsorbed mercury on biomass was desorbed using 10 ml of 4M HCl solution. The biomass could be reused for other biosorption assays. The ability of biomass to adsorb mercury(II) in a column was investigated. These studies consider the possibility of using leaves of castor tree as an inexpensive adsorbent for the removal of Hg(II) from contaminated chemical and mining industry wastewaters. It is also suggested that the dried biomass might be simply kept and used in a very low cost metal ion removal system.     

Modeling and influence of shear retention parameter on the response of reinforced concrete structural elements

To obtain the complete solutions describing the balance of a reinforced concrete structure, it is necessary to introduce a behavioral law characterizing the physical properties of material. The goal of this work is to study the response of reinforced concrete elements by taking into account the variation of the shear retention parameter (aggregate interlock) and the mesh density. The concrete was assumed as elastic-plastic material and follow the Drucker–Prager failure criterion with associated flow rule, the steel reinforcements were assumed to be elastic-perfectly plastic. The numerical results obtained are compared with other results available in the literature. Translated from Problemy Prochnosti, No. 4, pp. 108–116, July–August, 2009.