Analysis of Particle and Crystallite Size in Tungsten Nanopowder Synthesis

Tungsten nanopowders were synthesized by a low-temperature technique and then heat treated in a gaseous reductive atmosphere in order to study the phase evolution, crystallite size, and particle size of the powders as the heat treatment temperature was modified. Synthesis of the powders was carried out in aqueous media using NaBH₄ as a reducing agent using careful control of the pH of the solutions. The XRD patterns of the as-synthesized powders showed an amorphous phase. After washing, energy dispersive spectroscopy showed that the powders had peaks for oxygen and tungsten. In order to promote crystallization and eliminate the oxygen, the powders were heat treated at 773 K, 923 K, and 1073 K (500 °C, 650 °C, and 800 °C) in a H₂/CH₄ reducing atmosphere for 2 hours. XRD after heat treatment showed α-W peaks for the powders treated at 1073 K and 923 K (800 °C and 650 °C) and a mixture of β-W and α-W for the powders treated at 773 K (500 °C). The crystallite sizes determined from X-ray peak broadening were 12, 16, and 20 nm, whereas the average particle sizes from dynamic light scattering were 260, 450, and 750 nm, for heat treatment temperatures of 773 K, 923 K, and 1073 K (500 °C, 650 °C, and 800 °C), respectively. The average crystallite size and particle sizes increased proportionally with the treatment temperature, in contrast to what has been found for some ceramics, in which as the heat treatment temperature is increased, the crystallite size increases, but the particle size stays constant.     

The variable property grain model applied to the zinc oxide-hydrogen sulfide reaction

The variable property grain model, including the effect of grain diffusion resistance, has been applied to experimental results from the reaction of hydrogen sulfide with zinc oxide. Grain radius is assumed to vary under the combined effects of sintering and extent of reaction. Property variations are correlated by the specific surface area, an easily measured quantity. All model parameters with the exception of the grain diffusion coefficient have been evaluated by literature correlations or independent experimental measurements. Significant improvement in the match with experimental data, as compared to the constant property grain model, has been achieved.     

Numerical simulation of dispersed gas-liquid flows

This paper reviews the available information on numerical simulation of dispersed gas-liquid flows. Emphasis is on informing the reader about various aspects of constructing simulation models rather than giving an exhaustive literature review. The information is organised in a way so as to provide answers to the following questions: how to formulate model equations? how to select suitable algorithms and numerical techniques to solve these model equations? how to translate these into workable computer codes? how to use such codes for simulating flows in industrial equipment? Though greater emphasis is given to dispersed gas-liquid flows, the methodology can be applied to any multi-phase problem. Special features of multi-phase flow simulation over single-phase simulation are highlighted. A case of gas-liquid flow in a bubble column is presented as an illustration for the general methodology. The simulated mean flow field agrees reasonably with the experimental data. Properly validatedcfd codes thus can serve as a useful tool for design engineers of multi-phase systems. Some of the common pitfalls in using simulation codes for design are also discussed. This review is expected to give an overall idea about the present state-of-art of two-phase simulation in industrial equipment.     

Scheduling light-trails on WDM rings

We consider the problem of scheduling communication on optical WDM (wavelength division multiplexing) networks using the light-trails technology. We seek to design scheduling algorithms such that the given transmission requests can be scheduled using a minimum number of wavelengths (optical channels). We provide algorithms and close lower bounds for two versions of the problem on an n$n$ processor linear array/ring network. In the stationary   version, the pattern of transmissions (given) is assumed to not change over time. For this, a simple lower bound is c$c$, the congestion or the maximum total traffic required to pass through any link. We give an algorithm that schedules the transmissions using O(c+logn)$O(c+logn)$ wavelengths. We also show a pattern for which Ω(c+logn/loglogn)$\Omega (c+logn/loglogn)$ wavelengths are needed. In the on-line   version, the transmissions arrive and depart dynamically, and must be scheduled without upsetting the previously scheduled transmissions. For this case we give an on-line algorithm which has competitive ratio Θ(logn)$\Theta (logn)$. We show that this is optimal in the sense that every on-line algorithm must have competitive ratio Ω(logn)$\Omega (logn)$. We also give an algorithm that appears to do well in simulations (for the classes of traffic we consider), but which has competitive ratio between Ω(log²n/loglogn)$\Omega ({log}^{2}n/loglogn)$ and O(log²n)$O\left({log}^{2}n\right)$. We present detailed simulations of both our algorithms.     

Performance of personal access communications system-unlicensed B

The FCC has allocated the band between 1920 MHz and 1930 MHz for unlicensed personal communications services (UPCS) using isochronous or circuit operation. The UPCS spectrum is between the licensed PCS spectrum bands of 1850-1910 MHz and 1930-1990 MHz. Terminal interoperability in both the UPCS spectrum on private indoor wireless systems and the licensed spectrum on public PCS systems is desirable and encouraged by the FCC. This paper presents a port channel assignment process for the personal access communications system-unlicensed B (PACS-UB) which abides by the FCC etiquette for UPCS and discusses the corresponding uplink and downlink performance. Uplink power control is employed to improve the uplink performance. PACS-UB has a high degree of commonality with licensed PACS to permit economical licensed/unlicensed terminals and common network services. The results of our simulation show that, at 1% to 2% blocking probability, 99% of downlink local-mean signal-to-noise plus interference ratio (SINR) values are above 17 dB for a 10 to 20 m port separation. For a three-dimensional office environment, the uplink limits the SINR performance, however, with uplink power control, a 5.5 to 7 dB improvement in the uplink SINR can be achieved even for high traffic load     

Experimental Investigation on the Performance of a Solar Still Using SiO2 Nanoparticles /Jatropha curcas L

Silicon - Now, enticing systematic civic since everywhere the world is used in green synthesis and benefit of the simple is eco-friendly with an emergent method of producing nanoparticles (NPs)....