A parametric study of burning of multicomponent droplets in a dilute spray

The model for sphericosymmetric thin‐flame combustion of a multicomponent fuel droplet in a dilute spray using a unit cell approach, developed in the companion paper, has been used for studying the interaction effect between droplets. The effects of droplet spacing, ambient oxidizer concentration, ambient temperature and pressure have been considered. Droplet life increases with decrease in droplet spacing, ambient temperature and ambient oxidizer concentration. However, droplet life has a weak dependence on ambient pressure. Copyright © 2001 John Wiley & Sons, Ltd.     

Ferromagnetism in lead graphite-pencils and magnetic composite with CoFe2O4 particles

This work has been initiated with a curiosity to investigate the elemental composition and magnetic response of different grades of lead pencils (6B, 2B, HB, 2H, 5H) that people use in daily life. Interestingly, experimental results landed with a great achievement of observing soft magnetism in lead pencils, indicating a wide scope of magnetic tuning for room temperature applications. A novel magnetic composite has been synthesized by mixing different concentration of CoFe₂O₄ (CF) nanoparticles in 5H and 6B pencils for studying the magnetic tailoring aspects using pencils. Our results showed different possibilities of controlling disorder induced ferromagnetic parameters and a simple approach of producing sufficiently high coercive magnetic composite using pencils.     

Synthesis and characterization of poly(pyridinium salt)s derived from various aromatic diamines

Several poly(pyridinium salt)s containing various aromatic diamine moieties and tosylate counterions were prepared by the ring-transmutation polymerization reaction of bis(pyrylium tosylate) with aromatic diamines in dimethyl sulfoxide at 130?135 °C for 48 h and their tosylate counterions were exchanged to triflimide polymers by a metatheses reaction in an organic solvent. Their chemical structures were established by using various spectroscopic techniques. Their number-average molecular weights (M_n) were in the range of 38–46 kg/mol and polydispersities in the range of 1.13–1.43 as determined by gel permeation chromatography. They showed excellent thermal stabilities in nitrogen in the range of 326–477 °C. They exhibited lyotropic liquid-crystalline phase in polar aprotic and protic organic solvents above their critical concentrations depending on their microstructures and counterions. Their optical properties were examined by using UV–Vis and photoluminescent spectroscopy, which revealed that some polymers emitted UV light, some emitted blue light, and some emitted green light (both in solutions and solid states) depending on their microstructures, counterions, and on solvent polarity of organic solvents.     

Performance prediction of 60 kWp PV power plant in an educational institute

Due to government initiatives, many solar photovoltaic (PV) power plants of different sizes will be set up in India in the near future. In this context, the performance of a 60?kW_p PV power plant is discussed in this paper which is installed at National Institute of Technology (a centrally funded institute of Government of India), Agartala, located in a small state (Tripura) of North East India where supply of grid electricity is a critical issue. This article examines the various parameters for performance prediction of this solar power plant.     

Structural and Optical Characterizations of Electrochemically Grown Connected and Free-Standing TiO2 Nanotube Array

A TiO₂ nanotube array was grown electrochemically by using single and mixed electrolyte/s with 20 V constant potential at room temperature. Anodization was carried out for 120 min using five different electrolytes, e.g., H₃PO₄, NH₄F, HF, NH₄F with H₃PO₄ and HF with H₃PO₄. Structural characterizations of the grown titania nanotubes were conducted by using x-ray diffraction and field emission scanning electron microscopy. Optical properties of the grown nanotubes were investigated through photoluminescence (PL) spectroscopy. In the case of the 4 M H₃PO₄ electrolyte, no perceptible growth of nanotubes was observed. The individual electrolytes of 0.3 M NH₄F and 1 M HF resulted into the formation of the wall-connected nanotubes. In contrast, the mixed electrolytes comprising the strong (NH₄F, HF) and weak (H₃PO₄) electrolytes have been found to be efficient for the growth of wall-separated titania nanotubes. The results of the PL spectroscopy have demonstrated that the free-standing nanotubes offer low PL intensity compared to its connected counterpart owing to the lower carrier recombination rate of free-standing nanotubes.     

Heat loss factor of evacuated tubular receivers

Tubular receivers with an evacuated space between the absorber and concentric glass cover to suppress convection heat loss are employed as absorbers of linear concentrators in the intermediate temperature range. A knowledge of their heat loss factor is important for a study of the thermal performance of such solar concentrating systems. The heat loss factor of a collector can be calculated by solving the governing heat transfer equations or estimated from an empirical equation, if available. The governing equations must be solved simultaneously by iterations, but this is tedious and cumbersome. Although several correlations exist for determining the heat loss factor for flat-plate collectors and non-evacuated tubular absorbers of linear solar collectors, there is no available correlation for predicting the heat loss factor of evacuated receivers.

A correlation to calculate the heat loss factor (U_L) of evacuated tubular receivers as a function of variables involved (absorber temperature, emittance, diameter and wind loss coefficient) has been obtained. The correlation developed by a least square regression analysis predicts the heat loss factor to within ±1.5% of the value obtained by exact solution of the simultaneous equations in the following range of variables: wind loss coefficient, 10–60 W/m²°C; emittance, 0.1–0.95; and absorber temperature, 50–200°C.     

Photoelectrochemical cells consisting of phenosafranin-EDTA and different redox couples with illuminated semiconductor electrode

A photoelectrochemical cell, semiconductor (In₂O₃)/dye-EDTA//redox couple/Pt, has been developed using phenosafranin dye and EDTA aqueous solution in one compartment and Cu⁺/Cu²⁺, Fe(CN)₆⁴⁻/Fe(CN)₆³⁻, I⁻/I₂, and Fe²⁺/Fe³⁺ in the other compartment of an H-shaped cell separated by a glass membrane. All the cell characteristics such as open-circuit voltage, short-circuit current, fill factor, power efficiency, and solar energy efficiency have been determined. There is 2-3-fold increase of efficiency of the cell compared to the same cell with illuminated Pt electrode.     

Quasi‐static and dynamic nanoindentation and scratch behavior of multifunctional titania/poly(methyl methacrylate) composite

Nanoindentation (NI) and nanoscratch testing was used to determine the dynamic viscoelastic properties of titania reinforced poly(methyl methacrylate) nanocomposites. It was observed that the dynamic NI have a significant effect on the measured indentation modulus and nano‐hardness of the polymer‐based composite. Agreement was found between quasi‐static and dynamic NI result of the nanocomposites. The sinus‐nanoindentation had a limited effect on the measured viscoelastic properties of the composite. However, tribological properties and scratch hardness confirmed that the titania nanofillers act as the friction coefficient modifier in polymer matrix. POLYM. COMPOS., 35:1372–1376, 2014. © 2013 Society of Plastics Engineers