Synthesis,characterization, and supercapacitor studies of manganese (IV) oxide nanowires

One-dimensional manganese (IV) oxide (MnO₂) (～20 nm in average diameter) were synthesized by cathodic electrodeposition and heat treatment. The mechanism of electrodeposition and nanowire formation were discussed. The product was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Fourier transform infrared (FT-IR). Nanowires with varying lengths and diameters were found in TEM and SEM images of the sample. The results of N₂ adsorption–desorption analysis indicated that the BET surface area of the MnO₂ nanowires was 157 m² g^?1 and the pore size distributions were 2.5 and 4.5 nm. The electrochemical performances of the prepared MnO₂ as an electrode material for supercapacitors were evaluated by cyclic voltammetry and galvanostatic charge/discharge measurements in a solution of 0.5 M Na₂SO₄. The higher specific capacitance of 318 F g^?1 and good capacity retention of 86% were achieved after 1000 charge–discharge cycles had been observed for the MnO₂ nanowires electrode.     

A Modified Method Based on the Discrete Sliding Norm Transform to Reduce the PAPR in OFDM Systems

Orthogonal frequency division multiplexing (OFDM) is a modulation technique that allows the transmission of high data rates over wideband radio channels subject to frequency selective fading by dividing the data into several narrowband and flat fading channels. OFDM has high spectral efficiency and channel robustness. However, a major drawback of OFDM is that the peak‐to‐average power ratio (PAPR) of the transmitted signals is high, which causes nonlinear distortion in the received data and reduces the efficiency of the high power amplifier in the transmitter. The most straightforward method to solve this problem is to use a nonlinear mapping algorithm to transform the signal into a new signal that has a smaller PAPR. One of the latest nonlinear methods proposed to reduce the PAPR is the L₂‐by‐3 algorithm, which is based on the discrete sliding norm transform. In this paper, a new algorithm based on the L₂‐by‐3 method is proposed. The proposed method is very simple and has a low complexity analysis. Simulation results show that the proposed method performs better, has better power spectral density, and is less sensitive to the modulation type and number of subcarriers than L₂‐by‐3.     

A secure search protocol for lightweight and low-cost RFID systems

In radio frequency identification (RFID) systems, search protocols are used to find a specific item in a large number of tagged products. These protocols should be secure against RFID attacks such as traceability, impersonation, DoS and eavesdropping. Sundaresan et al. (IEEE Trans Dependable Secure Comput, 2015) presented a server-less search protocol based on 128-bits PRNG function and claimed that their method can address all vulnerabilities of previous protocols. In this paper, we prove that Sundaresan et al.’s protocol is vulnerable to traceability attack with the high probability. In addition, we present an improved protocol to solve the proposed problem and analyze its security level informally and formally based on AVISPA tool and BAN logic.     

A Zero-Pole Reposition Based, 0.95-mW, 68-dB,Linear-in-dB,Constant-Bandwidth Variable Gain Amplifier

A variable-gain amplifier with very low power consumption and wide tuning range is presented. The operational principle of this unique structure is discussed, its most important formulas are derived and its outstanding performance is verified by simulation in TSMC 0.18-μm N-well CMOS fabrication process. Owing to the novel zero-pole repositioning technique, the proposed circuit demonstrates very high frequency bandwidth of 79 MHz while drawing only 0.52 mA from 1.8 V power supply. The interesting results such as a very small core area of about 0.0025 mm² as well as a wide linear-in-dB and constant-bandwidth tuning range of 68.2 dB along with a very low power consumption of 0.95 mW are achieved utilizing standard CMOS technology. The stability of the proposed VGA is verified through transient sinusoidal response analysis. Full process, voltage and temperature (PVT) variation analysis of the circuit is also investigated through Monte Carlo and corner case analysis in order to approve the robustness of the structure. Monte Carlo simulations show standard deviation values of 4.6 dB and 78.3 MHz in gain and gain-bandwidth product, respectively. These results show that our zero-pole repositioning method would lend itself well for use in low-power and high-frequency applications, especially in high-speed automatic gain control amplifiers.     

Best Minimum Summation Scheduler for Long Term Evolution

Resource scheduling in Long Term Evolution (LTE) is an open and rising issue. It has an enormous impact on the entire system performance. Due to the nature of LTE system, the scheduler has to be designed carefully. It has to overcome many challenges such as limited processing time and the high dynamic behavior. This paper proposes a novel scheduling policy for the MAC layer in LTE called the Best Minimum Summation (BMS). The main aim of this scheduling policy is to achieve high performance with low complexity. Three sub-schedulers have been developed. Each one of these schedulers deals with scheduling table in different dimension. The first one operates on the scheduling table through the user dimension (BMS.UE); while the second one operates on the scheduling table through the resource block dimension (BMS.RB). The third scheduler operates on the scheduling table correlating both of these dimensions (BMS.2D). All of the proposed solutions were intensively evaluated in a system level simulator. Three performance metrics were used which are throughput, error rate and fairness. The results have shown that the ability of the BMS.UE scheduler to outperform other existing schedulers of LTE.     

Magnesium Ion Doping and Micro-Structural Engineering Assist NH4V4O10 as a High-Performance Aqueous Zinc Ion Battery Cathode

Layered ammonium vanadate materials exhibit significant mass-specific capacity and ion transport rate due to their small molecular weight and large ionic radius. However, the strong electrostatic interactions of Zn²⁺ and V–O bonds and the fragile ionic bonding of N-H^…O bonds hinder their development. Therefore, this work reports Mg²⁺ doping NH₄V₄O₁₀ materials accompanied by flower-like morphology to lower the migration energy barrier and inhibit amine dissolution. Owing to the 3D-flower-like morphology and the combined impact of Mg²⁺ and structural water, the binding of Zn^2+…V-O is significantly enhanced and additional ion channels were constructed. Pre-intercalated Mg²⁺ enhances the structural integrity and prevents irreversible deammoniation from obtaining excellent cyclic stability. Density functional theory (DFT) calculations show that MNVO provides a smoother Zn²⁺ diffusion path with a lower migration barrier. Benefited from these advantages, the MNVO cathode exhibits a high specific capacity of 410 mAh g⁻¹ at 0.1 A g⁻¹, satisfactory cyclic stability (90.2 % capacity retention at 10 A g⁻¹ after 5000 cycles), and capable rate ability (118 mAh g⁻¹ at 25 A g⁻¹) within 0.4-1.5 V. Furthermore, the zinc ion storage mechanism in the MNVO cathode is investigated through multiple analyses.     

Fabrication of porous ZnO via electrochemical etching using 10 wt% potassium hydroxide solution

We described the fabrication of porous ZnO using the electrochemical etching method. ZnO thin films deposited by radiofrequency sputtering were etched electrochemically using 10 wt% KOH solution as an etching medium to obtain porous ZnO surface structure. A constant voltage of 15 V was applied to enhance the etching process. The etched samples were then characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and photoluminescence (PL) spectroscopy to examine their structural and optical properties. XRD spectra showed that by performing the electrochemical etching process, porous ZnO could be obtained without severely deteriorating the crystallinity of the samples. Moreover, SEM characterization revealed that hillock-type porous ZnO was fabricated successfully. In addition, the cross-sectional SEM images revealed that there were only minimal changes in the layer thickness after the ZnO had been etched for various lengths of time. This finding shows the dominance of the vertical etching process. Notably, the intensity of PL spectra increased and the PL excitation peak exhibited a red shift trend as the etching time increased. These observations are due to the increase of the surface to volume ratio of the ZnO surface and the strain relaxation along the dislocation and grain boundary.     

Joint reference frame inter-mode selection for fast H.264 video coding

The H.264/AVC video coding standard uses multiple reference frames and variable-size macroblock partitions in inter-prediction. This flexibility allows the standard to achieve excellent rate-distortion performance at the cost of high encoding complexity. We present an algorithm for fast joint selection of the reference frames and macroblock partitions in rate-distortion-based coding. Experimental results for eight standard test video sequences show that, compared with exhaustive search, our algorithm can save up to 74.9 % of the encoding time with negligible loss in rate-distortion performance. The presented algorithm is also evaluated using a subjective assessment metric; quality evaluation measures based on user satisfaction. Diverse types of video sequences were used with different frame rates, quantization parameters, and resolutions. The effects of changing bit rate and resolution on compression efficiency and viewers’ satisfaction are also presented. Results show that our algorithm provides high scores of perceptual satisfaction that are significantly affected by the compression technique. As a result, we claim that our algorithm presents original and significant enhancement compared with exhaustive search. In addition, overall test results showed that our technique outperformed three of the best previously proposed methods and gave higher viewer satisfaction.