The effect of gamma and electron beam irradiation on the thermal and mechanical properties of injection‐moulded high crystallinity poly(propylene)

In the present study, the effect of gamma and electron beam (EB) irradiation on the thermal and mechanical properties of high crystalline polypropylene (HPP) was studied. To study the structural modifications of HPP polymer which could occur following these treatments at different doses (20, 40, 60, 80, 100, and 120 kGy) were applied to all samples. Nonirradiated HPP were used as control samples, differential scanning calorimetry analysis, thermogravimetric analysis, and Mechanical tests were carried out to evaluate the effect of both irradiation treatments (EB and gamma irradiation) on HPP samples. Irradiated samples of HPP decreases melting temperature (T_m) of matrix in EB more than in gamma rays up to 5°C. The changes of mechanical properties exhibit different radiation stability towards ⁶⁰Co‐gamma radiation and EB radiation. This difference reflects much higher penetration of the gamma radiation through the polymeric material as a function of sample thickness. The degradation on polymer properties caused by gamma irradiation was more than that caused by EB irradiation. Next, we compared the effects of gamma and EB irradiation to determine which of these two processes better maintained the integrity of the irradiated product. POLYM. COMPOS., 2008. © 2008 Society of Plastics Engineers.     

Effect of the type of superplasticizer on the properties of cementitious systems incorporating slag

Superplasticizers have become an integral ingredient in the formulation of concretes. After 40?years, their use and dosage remain uncertain due to variations in their compositions and those of cement. In addition, the substitution of cement by supplementary cementitious materials having different chemical compositions exacerbates the problem without counting the multiplicity of superplasticizers to choose from. The present work consists of a study of the rheological and mechanical properties of cementitious systems containing slag and various types of superplasticizers. The tests were carried out on pastes, mortars and concretes incorporating slag in partial cement replacement and four superplasticizers types, polynaphthalene sulphonate (PNS) and three polycarboxylates (PC). The results of this study demonstrate that the viscosity and the yield stress increase with the rate of incorporation of the slag. The air increases with the polycarboxylates but this effect is less perceptible in the presence of the slag. Polycarboxylates improve workability more than PNS. The use of polycarboxylates reduces the viscosity and the yield stress. The compressive strength of concretes containing slag is low at early age but high at long run. They exhibit good resistances to scaling. The permeability to chloride ions is considerably reduced in the presence of the slag independently of the type of superplasticizer, suggesting good durability of these concretes in potentially aggressive external environments.     

Radiation synthesis of hydrogels based on carboxymethyl cellulose and its application in removal of pollutants from wastewater

Synthesis of carboxymethyl cellulose‐g‐methacrylic acid/acrylamide Poly(CMC/MAAc:AAm) hydrogel was carried out using direct radiation copolymerization technique at ambient temperature. The gel (%) increased with increasing the content of AAm till level off at Poly(CMC/MAAc:AAm) (1/50:50 wt%) hydrogel and the swelling behavior found to be increased with increasing MAAc content in the hydrogel composition up to Poly(CMC/MAAc:AAm) (1/60:40 wt%). The grafting yield, grafting ratio, swelling behavior, and the thermal stability of Poly(CMC/MAAc:AAm) binary system are higher than those reported in our previous study by the same author which described the individual grafting of acrylamide (AAm) and methacrylic acid (MAAc) with different concentration onto carboxymethyl cellulose (CMC) using direct radiation grafting technique. The swelling kinetics and diffusion mechanism indicate that the water penetration obey non‐Fickian transport mechanism. The characterization of the prepared hydrogel was evaluated using Fourier transform infrared, X‐ray diffraction, thermogravimetric analysis, and scanning electron microscopy. The analyses by different analytical tools confirmed the successful grafting of both MAAc and AAm onto CMC. The adsorption capacity of Poly(CMC/MAAc:AAm) (1/60:40 wt%) hydrogel toward metal ions such as Cu⁺² and Co⁺², dyes such as acid blue dye and methyl green have been investigated. J. VINYL ADDIT. TECHNOL., 25:E35–E43, 2019. © 2017 Society of Plastics Engineers     

Mechanical,morphological, and thermal properties of poly(vinyl chloride)/low‐density polyethylene composites filled with date palm leaf fiber

This article investigates the mechanical, morphological, and thermal properties of poly(vinyl chloride) (PVC) and low‐density polyethylene (LDPE) blends, at three different concentrations: 20, 50, and 80 wt% of LDPE. Besides, composite samples that were prepared from PVC/LDPE blend reinforced with different date palm leaf fiber (DPLF) content, 10, 20, and 30 wt%, were also studied. The sample in which PVC/LDPE (20 wt%/80 wt%) had the greatest tensile strength, elongation at break, and modulus. The good thermal stability of this sample can be seen that T_10% and T_20% occurred at higher temperatures compared to others blends. DPLF slightly improved the tensile strength of the polymer blend matrix at 10 wt% (C10). The modulus of the composites increased significantly with increasing filler content. Ageing conditions at 80°C for 168 h slightly improved the mechanical properties of composites. Scanning electron microscopic micrographs showed that morphological properties of tensile fracture surface are in accordance with the tensile properties of these blends and composites. Thermogravimetric analysis and derivative thermogravimetry show that the thermal degradation of PVC/LDPE (20 wt%/80 wt%) blend and PVC/LDPE/DPLF (10 and 30 wt%) composites took place in two steps: in the first step, the blend was more stable than the composites. In the second step, the composites showed a slightly better stability than the PVC/LDPE (20 wt%/80 wt%) blend. Based on the above investigation, these new green composites (PVC/LDPE/DPLF) can be used in several applications. J. VINYL ADDIT. TECHNOL., 25:E88–E93, 2019. © 2018 Society of Plastics Engineers     

Thiazole derivatives‐functionalized polyvinyl chloride nanocomposites with photostability and antimicrobial properties

Polyvinyl chloride (PVC) was modified via substitution reaction with 2‐aminothiazole and ethyl 2‐aminothiazole‐4‐carboxylate separately in the absence and in presence of silver (AgNPs) or copper (CuNPs) nanoparticles, using metal salts as precursors, in 3% (w/w) with respect to PVC. The functionalized PVC‐nanocomposites have been characterized via FTIR, ¹HNMR spectroscopic analyses, in addition to the morphological investigation such as scanning (SEM) and transmission electron microscopy (TEM). Spectral data confirmed the introduction of the thiazole (ester) to the PVC backbone. TEM analysis showed that the sizes of the AgNPs and CuNPs have fallen in the range of 10–30 nm and 30–50 nm for the prepared nanocomposites, respectively. Evaluating the photostability of modified nanocomposites was estimated by following the extent of discoloration for UV‐irradiated samples colorimetrically in accordance with the irradiation time. The antimicrobial activity of the modified nanocomposites was explored against three Gram+ve bacteria (Bacillus subtilis, Staphylococcus aureus, and Streptococcus faecalis), three Gram‐ve bacteria (Escherichia coli, Neisseria gonorrhoeae, and Pseudomonas aeruginosa), and two fungi (Candida albicans and Aspergillus flavus). Aminothiazole (ester)‐functionalized PVC exhibited significant antimicrobial efficiencies against the investigated pathogens. However, incorporation of AgNPs or CuNPs to the modified PVC enhanced their inhibitory effect against the microorganisms under investigation. J. VINYL ADDIT. TECHNOL., 25:E137–E146, 2019. © 2018 Society of Plastics Engineers     

Laser beam machining of zirconia ceramic: An investigation of micro-machining geometry and surface roughness

Journal of Mechanical Science and Technology - Micro-machining of dental ceramics namely as zirconium oxide is carried out through laser beam machining. Micro-channels of different sizes are...     

From appropriation to formal intervention: An analytical framework for understanding the appropriation process in residual spaces of Cairo

The paper addresses the issue of how residual spaces are intervened upon through formal and informal processes. It argues that a profound understanding for the dynamics of informal interventions, denoted by appropriation, could enhance the performance of their formal peers.Adopting a qualitative approach, the paper departs from Lefebvre’s unitary theory of space and arrives at an analytical framework that helps to understand the appropriation processes in residual spaces. It, then, attempts to empirically challenge the applicability of this framework through analyzing a Cairene residual space that has undergone two cycles of intervention: a formal and informal one.     

An onsite demonstration and validation of LiDAR technology for wind energy resource assessment

The investigation of wind resource at higher heights is very crucial in planning wind power project. Normally, this involves the installation of a high and costly meteorological mast with a cup anemometer and wind vanes. This investigation uses the new ground-based remote-sensing technique Light Detection and Ranging (LiDAR) to investigate the wind resource at higher heights. This paper describes the LiDAR technology principle and examines the potential of LiDAR measurement to estimate the wind resource at higher heights by conducting a measurement campaign at Tamil Nadu, India. The wind statistics were determined using the 10?min average time-series wind data monitored by ZephIR LiDAR. These include the Weibull parameters, daily mean wind speed, wind power density, wind energy density, vertical wind speed profile and capacity factor. The investigation reveals that the vertical wind speed profile measured from the LiDAR system has approximate closer values to the standard meteorological measurement.     

Fuzzy-modeling with Particle Swarm Optimization for enhancing the production of biodiesel from Microalga

Biodiesel is one of the promising energy sources that could replace petroleum oil in the near future. Microalgae is occupying a distinguished position among the promising sources for biodiesel production. Enhancement of the lipids production during the pretreatment is a key factor for the biodiesel production. High-pressure homogenizer is a better pretreatment procedure to enhance the lipid extraction from microalgae. In this research, a robust model of biodiesel system using fuzzy logic is built based on the experimental data for biodiesel system. Then, Particle Swarm Optimization (PSO) optimizer is applied for determining the best operating parameters of biodiesel system. The decision variables used in the optimization process are; pressure, number of passes, and reaction time that maximizes the percentage of recovery lipids of biodiesel. A comparison study was carried out between the optimized results thought PSO algorithm and those obtained by the experimental results and the optimized results through the Response Surface Methodology (RMS). Results demonstrated that using the proposed optimization methodology is significantly better than RSM, a nearly 78.7% increase in lipids extraction could be achieved according to the current model.     

Saliency-based framework for facial expression recognition

This article proposes a novel framework for the recognition of six universal facial expressions. The framework is based on three sets of features extracted from a face image: entropy, brightness, and local binary pattern. First, saliency maps are obtained using the state-of-the-art saliency detection algorithm “frequency-tuned salient region detection”. The idea is to use saliency maps to determine appropriate weights or values for the extracted features (i.e., brightness and entropy).We have performed a visual experiment to validate the performance of the saliency detection algorithm against the human visual system. Eye movements of 15 subjects were recorded using an eye-tracker in free-viewing conditions while they watched a collection of 54 videos selected from the Cohn-Kanade facial expression database. The results of the visual experiment demonstrated that the obtained saliency maps are consistent with the data on human fixations. Finally, the performance of the proposed framework is demonstrated via satisfactory classification results achieved with the Cohn-Kanade database, FG-NET FEED database, and Dartmouth database of children’s faces.