容量法测定硝盐中硫酸根含量

本文介绍了采用容量法测定硝盐中硫酸根含量的方法及原理。进行了盐酸、铬酸钡等各种试剂用量的选择试验和样品回收率、实验方法精密度和准确度等方面的实验,结果表明,该方法稳定性和重复性好,测试结果准确可靠。这是一种操作简便快速准确的分析方法。     

絮凝剂对钢板酸洗废液除硅的影响

采用阳离子聚丙烯酰胺絮凝剂进行除硅，取得了很好的效果。采用正交实验法研究了絮凝剂的用量、反应温度、搅拌速度、搅拌时间对除硅率的影响。     

替莫唑胺联合利妥昔单抗对复发的老年原发中枢神经淋巴瘤的应用

Objective: The aim of our study was to analyze the long-term results of rituximab combined with temozolomide in treatment of elderly patients (> 60 years) with relapsed primary central nervous system lymphoma (PCNSL). Methods:Twelve postoperative elderly patients (> 60 years) were treated between August 2004 and October 2009. Temozolomide 100 mg/m2 to 200 mg/m2 days 1 to 7 and 15 to 21 and rituximab 375 mg/m2 days 1, 5, 8, 22. The maximum number of rituximab cycles was two. After one or two cycles of this combination, patients with an objective response and an acceptable level of toxicity continued treatment with single agent temozolomide (days 1 to 5, every 28 days). The overall survival was analyzed by using Kaplan-Meier. Results: The overall survival was 9 months. Toxicity was very mild with no grade 3-4 neurotoxicity toxic events. Conclusion: Rituximab combined with temozolomide seems to yields substantial long-term survival with moderate toxicity for the treatment of elderly relapsed PCNSL.     

辊底式加热炉下降烟道耐火材料改造实践

通化钢铁股份有限公司的连铸连轧生产线采用了先进的辊底式加热炉技术,其烟道工作衬设计采用1260℃绝热涂抹浇注料,耐火材料在使用六七个月后出现较严重的剥落现象。经过试验和生产使用证明,把浇注料改造成纤维模块应用于烟道工作层,在满足了生产工艺要求的前提下,使用寿命可达到18个月以上。     

The influence of temperature, pressure, salinity and capillary force on the formation of methane hydrate

We present here a thermodynamic model for predicting multi-phase equilibrium of methane hydrate liquid and vapor phases under conditions of different temperature, pressure, salinity and pore sizes. The model is based on the 1959 van der Waals-Platteeuw model, angle-dependent ab initio inter- molecular potentials, the DMW-92 equation of state and Pitzer theory. Comparison with all available experimental data shows that this model can accurately predict the effects of temperature, pressure, salinity and capillary radius on the formation and dissociation of methane hydrate. Online calculations of the p-T conditions for the formation of methane hydrate at given salinities and pore sizes of sediments are available on: www.geochem-model.org/models.htm.     

SO2-3、NH3?H2O、Cu2＋对高硫金精矿石硫合剂浸出的影响

采用石硫合剂提金法对高硫金精矿进行浸出试验,考察了SO 2-3、NH3? H2 O、Cu 2＋浓度对浸出过程的影响。其结果表明：在磨矿细度-400目80％,液固比6∶1,SO 2-3浓度0．1 mol/L, NH3? H2 O浓度1．6 mol/L,Cu 2＋浓度0．04 mol/L,Na2 CO3浓度0．1 mol/L,搅拌速度500 r/min,浸出温度40℃,浸出时间8 h的条件下,金的浸出率达到88％左右;浸出过程中加入SO 2-3,保证S 2-x和S2 O 2-3的稳定性,并减少因S单质、CuS和Cu2 S的沉积而阻碍浸金传质过程的影响;NH3? H2 O不仅调节浸出pH值,而且与Cu 2＋形成[Cu（NH3）4]2＋,促进金的浸出。     

延性相增韧的陶瓷材料中相界面对韧性的作用

论述了相界面结合与延性相的几何形态之间的匹配关系对延性相增韧的陶瓷基复合材料韧性的影响。对于连续延性相,例如网状、纤维或片状的延性相,界面结合较弱对增韧非常有益,因为裂纹扩展过程中相界面可发生部分分离,使桥接裂纹的延性相发生很大的塑性变形,消耗大量能量。而对于颗粒状的延性相,由于其球形形状及小的连续程度,经常导致断裂时断口上的延性相被完全拔出,几乎没有发生塑性变形,增韧效果较差,因此强的相界面结合强度是非常重要的。     

高炉炉喉钢砖的铸造技术和质量控制

炉喉钢砖是安装在高炉炉喉部位的重要零部件,不但要承受400℃～500℃的高温,而且还要承受炼铁原料的冲击磨损,根据高炉的特点,确定较适宜铸造工艺方案,保证钢砖的尺寸精度和材质性能,实现其寿命与高炉寿命同步,在生产过程中,针对薄壁复杂结构的铸件特点,采用合理的浇冒口系统,实现同时凝固原则,解决铸件的变形、裂纹问题,铸件的工艺出品率提高了20%,满足了高炉使用性能要求。     

Mechanism of Thermal Decomposition of Rare Earth Acetate Hydrates

The mechanism of thermal decomposition of rare earth acetate hydrates(Ln(Ac)_3·nH_2O,n=5,forLn=La;n=4,for Ln=Pr→Lu,Y,except Pm)has been studied by TG-DTG,DSC,infrared spectra,X-raydiffraction and chemical analysis.The thermal decomposition reaction consists of two stages,one is dehydrationand the other one is decompostion.The final product is oxide.It has been found that the temperature of pro-ducing anhydrous acetates decreases with increasing atomic number of rare earth elements.The activation ener-gies for dehydration and decomposition reaction of rare earth acetate hydrates have been calculated byFreeman-Carroll and Kissinger method.The dependence of activation energy Jor dehydration reaction on theatomic number of rare earth elements shows“inclined‘W’effect”.The enthalpy changes for dehydration anddecomposition reaction have been determined.     

炼焦煤成焦过程中显微结构形成行经的探讨

选取了三种不同变质程度的炼焦煤进行炼焦试验,控制炼焦终温在400～1100℃范围内,相隔一定温度进行一次试验,测定炼制的焦炭的显微组分,观察显微结构的变化。结果表明：随着炼焦终温的逐渐升高,焦炭光学组织指数OTI有所增加,增加的幅度逐渐变缓。说明在煤软化熔融形成小球体的阶段,对焦炭的显微结构的形成有着重要的影响,从而影响焦炭的质量。