Phosphorus fractionation in soil and sediments along a continuum from agricultural fields to nearshore lake sediments: Potential ecological impacts

The movement of phosphorus (P) from agricultural fields to streams and deposition in the nearshore of the lake presents a continuum of related physical and chemical properties that act to partition P into different physico-chemical fractions. We investigated changes in soil and sediment P fractionation as material was eroded from predominantly agricultural fields, transported via stream sediments, and deposited in a nearshore lake environment. Total phosphorus content of the soils and sediment decreased from field soils with an average concentration of 553.81 mg P kg^? 1 to 202.28 mg P kg^? 1 in stream sediments to 67.47 mg P kg^? 1 in lake sediments. Significant changes in P fractionation occurred during erosion, transport, and deposition of the particulate or sediment phase. The fractionation of P within the soils and sediments changed significantly from aluminum and organic matter associated P dominant in field soils to calcium associated P dominant in nearshore lake sediments. Various physical and chemical processes appear to be responsible for these transformations which impact the mobility and bioavailability of P. A significant amount of P was lost from field soils as they were transported and deposited. This P has either become available to biota or deposited in deeper portions of the lake system. Ultimately, the impact of P export on the nearshore lake environment may be influenced by the changes in P fractionation that occurred during transport and deposition and by the influence of macrophytes on the biogeochemical cycling of P in the sediment.     

Performance of four salmonids species in competition with Atlantic salmon

Economically and culturally important salmonid species often compete with Atlantic salmon (Salmo salar) released from stocking programs or that escaped during aquaculture production. Such competitive interactions may lower the individual fitness of these species by reducing survival and body growth. Here, we exposed juvenile brown trout (S. trutta), rainbow trout (Oncorhynchus mykiss), Chinook salmon (O. tshawytscha), and coho salmon (O. kisutch) to juvenile Atlantic salmon in artificial streams for 10 months. Survival and fitness-related traits of the four species were not negatively impacted by the presence of Atlantic salmon. The results suggest that brown trout and rainbow trout have better competitive abilities than Atlantic salmon, and that Chinook salmon and coho salmon have limited competitive interactions with Atlantic salmon. Although we discuss certain environmental conditions that can favor Atlantic salmon as a competitor at the juvenile life stage, Atlantic salmon may have little impact on the productivity of these four species.     

Use of Sb spray for improved performance of InAs/GaAs quantum dots for novel photovoltaic structures

Photoluminescence output from InAs/GaAs quantum dots has been improved by a Sb treatment immediately prior to capping with GaAs. Spectra taken at 300 and 80 K show a significant increase in output intensity when the quantum dots are exposed for 15 s under a Sb flux of approximately 0.1 monolayers per second, but this improvement is lost when the Sb exposure is extended to 30 s. There is no significant shift in the emission energies between samples indicating strain relief due to the cap layer is not responsible for the improvement. Analysis of temperature dependent photoluminescence taken between 80 and 300 K show increased activation energies at lower temperatures when an Sb spray is used, suggesting passivation of deep defect levels. For the higher temperature activation energy, corresponding to carrier escape from the QD to the barrier, whilst a 15 s Sb spray gives a substantial increase, the longer 30 s Sb spray sees the activation energy decrease, a result deduced to be due to Sb segregation providing shallow defect levels. A band structure including a very thin GaAsSb layer adjacent to the quantum dots is used to explain these results, with the 30 s Sb spray leading to shallow Sb segregation related defects and a lower activation energy. Depth dependent X-ray photoelectron spectroscopy data support the band structure proposed to explain the photoluminescence results and also reveals the highest concentration of Sb at the sample surface suggesting a ‘floating layer’ of Sb during growth of the GaAs cap. Some of the implications of these results, for growth of quantum dot samples and for two novel solar cell proposals, the intermediate band and hot carrier solar cells, are discussed.     

The feasibility of renewable energy sources for pumping clean water in sub-Saharan Africa: A case study for Central Nigeria

With less than 6 mm of rain from November through February every year, the central regions of Nigeria are in acute need of safe and consistent water supplies for drinking and other domestic or agricultural uses. Borehole supplies are capable of meeting a significant proportion of water needs, but ongoing fuel costs to power a generator and pump add a heavy burden to already disadvantaged communities. In this study, a techno-economic analysis is carried out in order to assess the feasibility of renewable energy sources and technologies to substitute for fossil-fuel powered pumping platforms. The results indicate that there is sufficient solar resource throughout these regions to facilitate relatively cost effective water pumping solutions, as well as a potentially effective wind resource depending on the exact location of the pumping station. Although systems based on these resources have high capital costs compared to petrol or diesel-based platforms, over a 20-year project life, the analysis indicates that ongoing fuel costs for a fossil-fuel-based system greatly outweigh the increased up-front costs of renewable alternatives. In conclusion, the results indicate that if the water demand at a particular site exceeds the capabilities of a hand pump, a renewable energy-powered pumping system is an attractive option, both economically and logistically in comparison to fossil-fuel-powered alternatives.     

Violence classifications and their impact on observed relationships with key factors in young offenders.

The understanding of violent criminal behavior is hindered by definitional problems in both the legal and research communities. Different definitions of violent criminal behavior and different classifications of the severity of violence are fundamental problems that need to be resolved in order to develop better conceptual models of the precursors to criminal violence that can inform management and treatment of violent young offenders. This study evaluated 6 classifications of violent juvenile offenses derived from the legal system and published research. The authors compare frequencies from different classifications and examine the influence of classifications on observed associations with expected predictor variables. Differences in frequencies and perceived associations between classifications highlight the need to adopt a consistent method of coding violent offenses for research purposes in order to obtain valid results that are capable of informing policy, the judiciary, and the development of effective interventions. The final classification system offers a method of systematic coding based on the type, frequency, and outcome of the violent behavior that distinguishes between levels of violence severity. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Topical Neck Cooling Prolongs Survival of Rats with Intra-Abdominal Feculent Sepsis by Activation of the Vagus Nerve

Global hypothermia prolongs survival in rats with intraabdominal feculent sepsis by inhibiting inflammatory responses. We hypothesized that topical neck cooling (TNC) has similar benefits. Septic shock was induced by cecal ligation and incision (CLI) in Sprague Dawley rats. Rats were randomized to sham laparotomy, control with CLI, CLI with TNC, or vagotomy at the gastroesophageal junction before CLI and TNC. Two more groups underwent peritoneal washout with and without TNC two hours after CLI. TNC significantly lowered neck skin temperature (16.7 ± 1.4 vs. 30.5 ± 0.6 °C, p < 0.05) while maintaining core body normothermia. TNC rats recovered from anesthesia 70 min earlier than the control (p < 0.05). Three hours following CLI, the control and vagotomy with TNC groups had significantly more splenic contraction, fewer circulating leukocytes and higher plasma IL-1β, IL-10 and TNF-α levels than TNC rats (p < 0.05). TNC prolonged survival duration after CLI by a median of four hours vs. control (p < 0.05), but no benefit was seen if vagotomy preceded TNC. Peritoneal washout alone increased survival by 3 h (9.2 (7.8–10.5) h). Survival duration increased dramatically with TNC preceding washout, to a 56% survival rate (>10 days). TNC significantly prolonged the survival of rats with severe intraabdominal sepsis by inhibiting systemic proinflammatory responses by activating vagal anti-inflammatory pathways.     

A Pyropheophorbide Analogue Containing a Fused Methoxy Cyclohexenone Ring System Shows Promising Cancer-Imaging Ability

Herein we report the synthesis, photophysical properties, positron emission tomography (PET) imaging and photodynamic therapy (PDT) efficacy of methyl 3-(1′-m-iodobenzyloxy)ethyl-3-devinyl-verdin 4 (with or without the ¹²⁴I isotope). The PET imaging ability and ex vivo biodistribution of [¹²⁴I] 4 were compared with the well-studied methyl [3-(¹²⁴1′-m-iodobenzyloxy)ethyl]-3-devinyl-pyropheophorbide-a methyl ester (PET-ONCO or [¹²⁴I] 2 ) and [¹⁸F]fluorodeoxyglucose ([¹⁸F]FDG) in BALB/c mice bearing colon-26 tumors. Whole-body PET images of [¹²⁴I] 4 containing a fused methoxy cyclohexenone ring system showed excellent tumor contrast with time (72>48>24 h post-injection). Ex vivo biodistribution results indicate that relative to the current clinical standard [¹⁸F]FDG and [¹²⁴I] 2 in 2 % ethanol formulation, [¹²⁴I] 4 , at the same radioactive dose (25 μCi per mouse), showed higher tumor uptake at 24 h post-injection and longer tumor retention. In biological environments, compound 4 showed lower fluorescence and lower singlet oxygen yield than 2 , which is possibly due to higher aggregation caused by the presence of a fused cyclohexenone ring system, resulting in limited in vitro/in vivo PDT efficacy. Therefore, the chlorophyll-a analogue [¹²⁴I] 4 provides easy access to a novel PET imaging agent (with no skin phototoxicity) to image cancer types—brain, renal carcinomas, pancreas—in which [¹⁸F]FDG shows limitations.     

Nonlinear inverse optimization approach for determining the weights of objective function in standing reach tasks

This paper presents a nonlinear inverse optimization approach to determine the weights for the joint displacement function in standing reach tasks. This inverse optimization problem can be formulated as a bi-level highly nonlinear optimization problem. The design variables are the weights of a cost function. The cost function is the weighted summation of the differences between two sets of joint angles (predicted posture and the actual standing reach posture). Constraints include the normalized weights within limits and an inner optimization problem to solve for joint angles (predicted standing reach posture). The weight linear equality constraints, obtained through observations, are also implemented in the formulation to test the method. A 52 degree-of-freedom (DOF) human whole body model is used to study the formulation and visualize the prediction. An in-house motion capture system is used to obtain the actual standing reach posture. A total of 12 subjects (three subjects for each percentile in stature of 5th percentile female, 50th percentile female, 50th percentile male and 95th percentile male) are selected to run the experiment for 30 tasks. Among these subjects one is Turkish, two are Chinese, and the rest subjects are Americans. Three sets of weights for the general standing reach tasks are obtained for the three zones by averaging all weights in each zone for all subjects and all tasks. Based on the obtained sets of weights, the predicted standing reach postures found using the direct optimization-based approach have good correlation with the experimental results. Sensitivity of the formulation has also been investigated in this study. The presented formulation can be used to determine the weights of cost function within any multi-objective optimization (MOO) problems such as any types of posture prediction and motion prediction.     

Pathway to health: Cluster-randomized trail to increase fruit and vegetable consumption among smokers in public housing.

Objectives: Examine the effectiveness of an intervention to increase fruits and vegetables (FV) consumption among smokers. Design: Cluster-randomized trial of 20 public housing developments; 10 randomly assigned to an FV intervention and 10 to a smoking cessation intervention. Main outcome measures: Usual (past 7 days) and past 30 days change in daily FV intake at 8 weeks and 6 months postbaseline. Results: Greater increases were seen in the FV group. At Week 8 and Month 6, the FV group had consumed 1.58 (p = .001) and 0.78 (p = .04), respectively, more daily FV servings in the past 7 days than the cessation group. At the same time points, the FV group had consumed 3.61 (p = .01) and 3.93 (p = .01), respectively, more FV servings in the past 30 days than the cessation group. Completing more motivational interviewing sessions (p = .02) and trying more recipes (p = .02) led to significantly greater increases at Month 6 among FV participants. Conclusions: Motivational interviewing counseling and lifestyle modification through trying out healthy recipes may be effective in helping a high-risk population increase their FV intake. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Contrǒle anticipé de la température au moyen d'une calculatrice analogique

An experimental set-up was used to study the anticipated control of temperature in a continuous flow tank. Temperature of the feed served to actuate the controller, Temperature at the outlet was used to bring corrections to unforeseen variations which might have happened after the point of measurement at the feed. Results have shown that anticipated control combined with feedback control is an improvement over feedback control alone. This improvement would be superior if the time constants of the process and the final control element were of the same order of magnitude.