Optimized structure and electrochemical properties of sulfonated carbon nanotubes/Co–Ni bimetallic layered hydroxide composites for high-performance supercapacitors

Technical development in electronic devices is frequently stifled by their insufficient capacity and cyclic stability of energy-storage devices. The nano-structured materials have sensational importance for providing novel and optimized combination to overcome exiting boundaries and provide efficient energy storage systems. Metal hydroxide materials with high capacity for pseudo-capacitance properties have grabbed special attention. Lately, the blend of nickel and cobalt hydroxides has been considered as a favorable class of metallic hydroxide materials owing to their comparatively high capacitance and exceptional redox reversibility. The sulfonated carbon nanotube fluid (SCNTF) was prepared by the ion exchange method to be utilized as the exceptional templates due to astonishing specific surface area, ensuring the maximum utilization of the active material. The CoNi-layered double hydroxides (LDHs)/SCNTF core-shell nanocomposite was prepared by the simple solvothermal method. Structural analysis showed that the composite material had the high conductance of carbon materials, the pseudo-capacitance characteristics of metal hydroxides, and porous structure, which facilitates the ion shuttle when the electrolyte reacts with the active material. Electrochemical analysis results showed that CoNi-LDHs/SCNTF had excellent rate performance, reversible charge-discharge properties and cycle stability. It exhibited an extreme specific capacity of 1190.5 F g^?1 at a current density of 1 A g^?1; whereas specific capacity remained 953.7 F g^?1 at the current density was 10 A g^?1. In addition, the capacity retention rate after 5000 charge-discharge cycles at a current density of 20 A g^?1 was 81.0%. The results indicated that the CoNi-LDHs/SCNTF core-shell nanocomposite material is cost efficient and an effective substitute in energy storage applications.     

Mechanism of gas absorption enhancement in a slurry droplet containing reactive, sparingly soluble microparticles

The absorption of a gaseous species by a slurry droplet containing reactive and sparingly soluble microparticles is numerically simulated. The problem studied is relevant to spray flue gas desulfurization systems and the objective of this study was to elucidate the effect of the reactive solid particles on the parameters that determine the mass transfer processes. Spherical droplets with internal circulation similar to Hill’s vortex flow were considered. Quasi-steady conservation equations representing the absorbed and dissolved reactant species and equations representing the dissolution of particles were numerically solved using the droplet internal circulation streamline as a coordinate. Second-order and instantaneous chemical reactions were both addressed. The results show that the reactant microparticles enhance the absorption rate by increasing the gradient of the absorbed species beneath the droplet surface. The relative effect of solid particles depends strongly on the droplet internal circulation and diminishes as stronger recirculation occurs.     

A comprehensive experimental evaluation of asphaltene dispersants for injection under reservoir conditions

As the efficiency of dispersants with different origins is questionable for each typical oil sample, the present study provides a reproducible and reliable method for screening asphaltene dispersants for a typical asphaltenic crude oil. Four different asphaltene dispersants (polyisobutylene succinimide, polyisobutylene succinic ester, nonylphenol-formaldehyde resin modified by polyamines, and rapeseed oil amide) were prepared and their performance on two oils from an Iranian field under laboratory and reservoir conditions was studied. A thorough analysis including ash content and SARA tests was performed on the solid asphaltene particles to characterize the nature of deposits. Then a highly efficient carrier fluid, which is crucial when injecting dispersant into the wells, was selected from a variety of chemicals by comparing their solubility. In the next step, using an optical microscope, a viscometer, and a Turbiscan, the screening of dispersants under laboratory conditions was done on a mixture of dead oil and dispersant to evaluate the onset of asphaltene precipitation and its stability when titrating by a precipitant. Finally, two different mixtures of the efficient dispersants, live oil, and carrier fluid were used with the solid detection system (SDS) and the filtration method to examine their effects on the onset pressure of asphaltene precipitation and the asphaltene content of the crude oil under reservoir conditions. The results show that the combination of experimental methods used in this work could be consistently applied to screening asphaltene dispersants. Among the four different dispersants applied here, the dispersant based on nonylphenol-formaldehyde resin modified by polyamines showed the best performance on the available live oils. This chemical modified the onset pressure of asphaltene precipitation of light oil from 4300 psi to about 3600 psi and decreased the precipitated asphaltene of heavy oil by about 30 %.     

Effects of slip and heat transfer on the peristaltic flow of a third order fluid in an inclined asymmetric channel

The present investigation is concerned with the peristaltic flow of an incompressible and magnetohydrodynamic MHD third order fluid in an inclined asymmetric channel. Both thermal and velocity slip conditions have been taken into account. The channel walls are maintained at different temperatures. The governing differential systems subjected to their boundary conditions have been solved for small Deborah number. In the derived solution expressions, the long wavelength and low Reynolds number assumptions are utilized. Graphical results are presented for the pressure rise, longitudinal velocity and temperature. Comparison with the previous published work regarding viscous fluid and no-slip case is performed. Pumping and trapping phenomena are displayed graphically just to examine the various interesting aspects of the present work.     

TOC determination of Gadvan Formation in South Pars Gas field, using artificial intelligent systems and geochemical data

Potentially, TOC content is affected by logging data in a source rock (density, sonic, neutron and resistivity logs). Hence, to analyze these logs, which we make a quick and reliable assessment of a source rock. So, it is a quick and economically cheaper method rather than direct geochemical analysis. A source rock interval poses to less density, lower velocity, higher sonic porosity, higher gamma ray values and increase in resistivity. In this research, Gadvan Formation was studied in two boreholes as potential of source rock. The log data of two wells were used to construct of intelligent models in a source rock of the South Pars Gas field in southwest of Iran. A suite of geophysical logs (neutron, density, sonic and resistivity logs) and cutting chip data samples data were applied for determining TOC content of this formation. Rock-Eval pyrolysis data reveal that Gadvan Formation is poor source rock (less than 0.5%). Hence we attempted a correlation between geophysical data and direct TOC content measurements of using ? Log R, Rock-Eval, neural network and fuzzy logic techniques.The results showed that intelligent models were successful for prediction of TOC content from conventional well logs data. Meanwhile, similar responses from other different intelligent methods indicated that their validity for solving complex problems.     

Stability Analysis of Stakeholders’ Cooperation in Inter-Basin Water Transfer Projects: a Case Study

Water Resources Management - This study investigates the conflict resolution among different stakeholders in a water transfer project. The portion of the Beheshtabad Water Transfer Project in Iran...     

Schauder fixed point theorem based existence of periodic solution for the response of Duffing’s oscillator

An initial-boundary value problem that is Duffing’s oscillator with time varying coefficients will be studied. Using Banach’s fixed-point theorem, the existence of periodic solution of the equation will be predicted. The method applied in this paper is the Schauder second fixed point theorem, which includes the response of structures under vibratory force systems. As an example, the dynamics of nonlinear simply supported rectangular thin plate under influence of a relatively moving mass is studied. By expansion of the solution as a series of mode functions, the governing equations of motion are reduced to an ordinary differential equation for time development vibration amplitude, which is Duffing’s oscillator. Finally, a parametric study is developed, after that some numerical examples are solved, and the validity of the present analysis is clearly shown. This paper was recommended for publication in revised form by Associate Editor Maenghyo Cho Hossein Ali Sepiani received his B.S. degree in Mechanical Engineering from University of Kashan, Iran, in 2003. He then received his M.S. degree from University of Tehran, in 2006. Currently, Hossein is continuing his research at University of Tehran. His research interests include new materials (FGMs, Nano-materials, SMAs, SMPs, etc), Composites (Woven Fabrics and Fiber Metal Laminates), Smart Materials (Shape Memory Alloy, Magnet/Electro-rheological and Piezoelectric Sensors and Actuators), Intelligent structures (Structures integrated with smart materials), Vibration and control of Intelligent Structures and their application. Ahmad Feyz Dizaji got his B.S. degree from University of Tehran, Iran, in 1970. Then he continued his study in U.S. and received his PhD. degree from Michigan State University in 1983, in Applied Mathematics under the supervision of Professor Shui-ni Chow and Professor J. Mallet-Paret. Since then he has been a member of the Faculty of Engineering in University of Tehran, teaching mathematics in both undergraduate and graduate levels.     

Nano-second UV laser processed micro-grooves on Ti6Al4V for biomedical applications

Laser surface texturing can be used to produce well defined micro-grooves on biomedical materials such as Ti-6Al-4V. Such micro-grooves can be optimized to improve the integration with surrounding tissue. This paper examines the effects of Gaussian shaped beam profiles for nano-second laser processing on the laser micro-groove geometry, topography, and micro-structure of Ti-6Al-4V under atmospheric conditions. Laser and machining parameters such as pulse rate, scan speed, wavelength, groove width and pitch are shown to affect the resulting micro-groove geometries. In contrast to prior micro-groove studies using top-hat beam profiles with ultra-violet (UV) Excimer lasers or large area masking techniques, grooves produced with Nd:YVO₄ exhibit improved roughness parameters and reduced heat-affected zones. Initial processing parameters are established for the fabrication of micro-groove geometries on flat geometries that are relevant to biomedical implants and devices.     

Prediction of the plastic viscosity of self-compacting steel fibre reinforced concrete

Micromechanical constitutive models are used to predict the plastic viscosity of self-compacting steel fibre reinforced concrete (SCFRC) from the measured plastic viscosity of the paste. The concrete is regarded as a two-phase composite in which the solid phase is suspended in a viscous liquid phase. The liquid matrix phase consists of cement, water and any viscosity modifying agent (VMA) to which the solids (fine and coarse aggregates and fibres) are added in succession. The predictions are shown to correlate very well with available experimental data. Comments are made on the practical usefulness of the predicted plastic viscosity in simulating the flow of SCFRC.     

Particle transport in a small square enclosure in laminar natural convection

The transport of particles with diameters in the range of 50 nm to 1 μm in laminar free convection of air in square enclosures was numerically investigated by an Eulerian–Lagrangian method. Two-dimensional square enclosures with widths from 2.5 mm to 5 cm, with two adiabatic surfaces and 100 and 200 °C temperature difference between the other two surfaces, were considered. The Rayleigh numbers varied from 100 to 8×10⁵. The air flow was simulated in Eulerian frame using a commercial CFD software, whose predictions were compared with published benchmark results. Lagrangian particle transport calculations were carried out by tracking 1000 particles that were initially randomly distributed in the flow field, and assuming one-way coupling between the particles and the carrier gas. Particle motion mechanisms considered included gravity, drag, lift force, thermophoresis and Brownian dispersion.The results showed that at Rayleigh numbers lower than about 10 000 the entire flow field was dominated by a single recirculation pattern. For these low Rayleigh number cases most of the particles disperse towards the walls, while a fraction of particles were trapped in a quasi-steady recirculation zone. Inside this recirculation zone the particles were at quasi-equilibrium with respect to the hydrodynamic and dispersive forces that acted on them, and left the zone due to Brownian dispersion only at a very low rate. This quasi-equilibrium zone was not observed at the higher Rayleigh numbers where a single recirculation pattern no longer governed the entire flow field. The results also confirmed the important role of thermophoresis and Brownian dispersion, in particular for submicron size particles.