全文获取类型
收费全文 | 84557篇 |
免费 | 1007篇 |
国内免费 | 412篇 |
专业分类
电工技术 | 842篇 |
综合类 | 2317篇 |
化学工业 | 11687篇 |
金属工艺 | 4817篇 |
机械仪表 | 3042篇 |
建筑科学 | 2175篇 |
矿业工程 | 562篇 |
能源动力 | 1152篇 |
轻工业 | 3696篇 |
水利工程 | 1268篇 |
石油天然气 | 343篇 |
无线电 | 9278篇 |
一般工业技术 | 16421篇 |
冶金工业 | 2682篇 |
原子能技术 | 341篇 |
自动化技术 | 25353篇 |
出版年
2019年 | 14篇 |
2018年 | 14457篇 |
2017年 | 13386篇 |
2016年 | 9973篇 |
2015年 | 612篇 |
2014年 | 239篇 |
2013年 | 238篇 |
2012年 | 3166篇 |
2011年 | 9456篇 |
2010年 | 8313篇 |
2009年 | 5565篇 |
2008年 | 6806篇 |
2007年 | 7804篇 |
2006年 | 148篇 |
2005年 | 1250篇 |
2004年 | 1165篇 |
2003年 | 1208篇 |
2002年 | 576篇 |
2001年 | 115篇 |
2000年 | 200篇 |
1999年 | 83篇 |
1998年 | 99篇 |
1997年 | 60篇 |
1996年 | 67篇 |
1995年 | 31篇 |
1994年 | 40篇 |
1993年 | 29篇 |
1992年 | 28篇 |
1991年 | 38篇 |
1990年 | 13篇 |
1988年 | 26篇 |
1987年 | 14篇 |
1985年 | 13篇 |
1982年 | 13篇 |
1980年 | 12篇 |
1969年 | 24篇 |
1968年 | 44篇 |
1967年 | 33篇 |
1966年 | 42篇 |
1965年 | 44篇 |
1963年 | 28篇 |
1962年 | 22篇 |
1961年 | 18篇 |
1960年 | 30篇 |
1959年 | 35篇 |
1958年 | 37篇 |
1957年 | 36篇 |
1956年 | 34篇 |
1955年 | 63篇 |
1954年 | 68篇 |
排序方式: 共有10000条查询结果,搜索用时 203 毫秒
21.
Ferrite particles coated with biocompatible phases can be used for hyperthermia treatment of cancer. We have synthesized substituted
calcium hexaferrite, which is not stable on its own but is stabilized with small substitution of La. Hexaferrite of chemical
composition (CaO)0.75(La203)0.20(Fe2O3)6 was prepared using citrate gel method. Hydroxyapatite was prepared by precipitating it from aqueous solution of Ca(NO3)2 and (NH4)2HPO4 maintaining pH above 11. Four different methods were used for coating of hydroxyapatite on ferrite particles. SEM with EDX
and X-ray diffraction analysis shows clear evidence of coating of hydroxyapatite on ferrite particles. These coated ferrite
particles exhibited coercive field up to 2 kOe, which could be made useful for hysteresis heating in hyperthermia. Studies
by culturing BHK-21 cells and WBC over the samples show evidence of biocompatibility. SEM micrographs and cell counts give
clear indication of cell growth on the surface of the sample. Finally coated ferrite particle was implanted in Kasaulli mouse
to test its biocompatibility. The magnetic properties and biocompatibility studies show that these hydroxyapatite coated ferrites
could be useful for hyperthermia. 相似文献
22.
Chloride doped polyaniline conducting polymer films have been prepared in a protic acid medium (HCl) by potentiodynamic method
in an electrochemical cell and studied by cyclic voltammetry and FTIR techniques. The FTIR spectra confirmed Cl- ion doping in the polymers. The polymerization rate was found to increase with increasing concentration of aniline monomer.
But the films obtained at high monomer concentration were rough having a nonuniform flaky polyaniline distribution. Results
showed that the polymerization rate did not increase beyond a critical HCl concentration. Cyclic voltammetry suggested that,
the oxidation-reduction current increased with an increase in scan rate and that the undoped polyaniline films were not hygroscopic
whereas chloride doped polyaniline films were found to be highly hygroscopic. 相似文献
23.
24.
A coupled finite-element model, CON2D, has been developed to simulate temperature, stress, and shape development during the
continuous casting of steel, both in and below the mold. The model simulates a transverse section of the strand in generalized
plane strain as it moves down at the casting speed. It includes the effects of heat conduction, solidification, nonuniform
superheat dissipation due to turbulent fluid flow, mutual dependence of the heat transfer and shrinkage on the size of the
interfacial gap, the taper of the mold wall, and the thermal distortion of the mold. The stress model features an elastic-viscoplastic
creep constitutive equation that accounts for the different responses of the liquid, semisolid, delta-ferrite, and austenite
phases. Functions depending on temperature and composition are employed for properties such as thermal linear expansion. A
contact algorithm is used to prevent penetration of the shell into the mold wall due to the internal liquid pressure. An efficient
two-step algorithm is used to integrate these highly nonlinear equations. The model is validated with an analytical solution
for both temperature and stress in a solidifying slab. It is applied to simulate continuous casting of a 120 mm billet and
compares favorably with plant measurements of mold wall temperature, total heat removal, and shell thickness, including thinning
of the corner. The model is ready to investigate issues in continuous casting such as mold taper optimization, minimum shell
thickness to avoid breakouts, and maximum casting speed to avoid hot-tear crack formation due to submold bulging. 相似文献
25.
Atsushi Narumi Kosei Kawasaki Harumi Kaga Toshifumi Satoh Naoya Sugimoto Toyoji Kakuchi 《Polymer Bulletin》2003,49(6):405-410
Summary
The potato phosphorylase-catalyzed polymerization of α-D-glucose-1-phosphate (G-1-P) onto poly[styrene-block-(4-vinylbenzyl maltohexaoside)] (1) was performed at the molar ratios of [G-l-P]0 and [maltohexaose]0 of 35, 80, and 250. The product was found to be soluble in dimethyl sulfoxide, which was a good solvent for amylose, and
showed the complex-formation with iodine, indicating that the product was assignable to poly[styrene-block-(styrene-graft-amylose)] (2). The quantitative analysis of the liberated phosphoric acid gave the average degree of polymerization o f the glucose unit
(n) as 27, 5 1, and 180 for 2-I, 2-II, and 2-III, respectively.
Received: 29 November 2002/Accepted: 22 December 2002
Correspondence to Toyoji Kakuchi 相似文献
26.
ZhaoYahong ZhangZhongpei WuWeiling 《电子科学学刊(英文版)》2003,20(3):177-182
Adaptive modulation and power allocation is introduced into the multicarrier DSCDMA system to improve the system performance and bandwidth efficiency.First,the system design appropriate for adaptive modulation and power allocation is given,then the algorithm of adaptive modulation and power allocation is applied.Simulation results demonstrate great performance improvement compared with the fixed modulated one. 相似文献
27.
As an aid towards improving the treatment of exchange and correlation effects in electronic structure calculations, it is
desirable to have a clear picture of the errors introduced by currently popular approximate exchange-correlation functionals.
We have performed ab initio density functional theory and density functional perturbation theory calculations to investigate
the thermal properties of bulk Cu, using both the local density approximation (LDA) and the generalized gradient approximation
(GGA). Thermal effects are treated within the quasiharmonic approximation. We find that the LDA and GGA errors for anharmonic
quantities are an order of magnitude smaller than for harmonic quantities; we argue that this might be a general feature.
We also obtain much closer agreement with experiment than earlier, more approximate calculations. 相似文献
28.
Effect of doping of carbon nanotubes by magnetic transition metal atoms has been considered in this paper. In the case of
semiconducting tubes, it was found that the system has zero magnetization, whereas in metallic tubes the valence electrons
of the tube screen the magnetization of the dopants: the coupling to the tube is usually antiferromagnetic (except for Cr). 相似文献
29.
The effect of humidity during storage on the crosslinking reactions of isocyanate groups was investigated with attenuated total reflectance Fourier transform infrared spectroscopy with pressure‐sensitive adhesives composed of poly[ethyl acrylate‐co‐(2‐ethylhexyl acrylate)‐co‐(2‐hydroxyethyl methacrylate)] as a base resin and polyisocyanate as a crosslinker. A peak‐resolving analysis of the amide II region revealed four bands. According to an analysis of the Fourier transform infrared spectra of the model compounds, these four bands were assigned to free urethane linkages, hydrogen‐bonded urethane linkages, free urea linkages, and hydrogen‐bonded urea linkages. As expected, storage under humid conditions led to the formation of free and hydrogen‐bonded urea linkages corresponding to the promotion of isocyanate consumption. Peak resolution of the amide II region was found to be a reasonable way of monitoring urethane and urea linkages during crosslinking reactions. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 3039–3045, 2003 相似文献
30.
In order to investigate the reduction mechanism of thioglycolic acid (TG) on the keratin fibers, cross-sectional samples of white human hair treated with TG were prepared. The heterogeneous reaction between TG and keratin fibers involving the diffusion of TG into human hair was analyzed at the molecular level using microspectrophotometry and FT-Raman spectroscopy. The diffusion of TG into human hair clearly increased by increasing the treatment time and by raising pH. The TG relative concentration and the disconnected relative concentration of disulfide (–SS–) groups at various depths of the hair samples with pH 9.0 were in good agreement, indicating that the reaction rate (the disconnection of –SS– groups) was faster than the diffusion rate of TG into human hair. From these experiments, we demonstrated that TG diffuses gradually beyond the cuticle region, and toward the inside of the cortex region along with the disconnection of –SS– groups. 相似文献