Bioreduction of Hexavalent Chromium in Flow-Through Quartz Sand Columns

Hexavalent chromium (Cr(VI)) contamination of soil and groundwater is a major environmental concern for some industrial sites and most of the U.S. Department of Energy sites. Cr(VI) is toxic and fairly mobile in groundwater. Bioreduction of Cr(VI) to less toxic and less mobile Cr(III) is considered to be a feasible option. Among the Cr(VI) reducing bacteria, Shewanella oneidensis MR-1 (MR-1) has been shown to be effective in metal reduction under anaerobic conditions. Data on bioreduction of Cr(VI) by MR-1 in a flow-through soil column that better approximates the subsurface condition are not available. The objective of this research project was to study the bioreduction of Cr(VI) by MR-1 in a continuous-flow quartz sand column system. MR-1 was found to be very effective in reducing Cr(VI) to Cr(III) for concentrations ranging from 0.055 mM (2.85?mg/L) to 0.006 mM (0.31?mg/L). The amount of Cr(VI) reduced prior to its breakthrough was found to be inversely proportional to its concentration in the feed due to increased inhibition of microbial activity and a residual reduction of 20–45% of Cr(VI) was observed even after its breakthrough.     

Analysis of antiresonant reflecting optical waveguide gratings by use of the method of lines

The modal spectral response of an antiresonant reflecting optical waveguide (ARROW) with periodic corrugations or grating is calculated for both shallow and deep gratings with the Method of Lines. The effect of the ARROW layer thickness and the grating depth on the spectral response is studied. It is found that when the ARROW-layer thickness is close to resonance, the ripples in the reflection spectra become smooth and the peak reflectivity drops. This is attributed to the large increase in the leakage loss of the ARROW waveguide near resonance. The ARROW grating is characterized by modal reflectivity spectra, which exhibit a strong polarization discrimination property, in favor of the TE polarization.     

The Application of Critical Path Method (CPM) in Workflow Schema of Marble Processing Plants

The critical path method (CPM) is a widely applied technique in large-scale industrial project planning and control. Based on a detailed review of the current literature, no references have been found referring to the use of the CPM in marble processing plants and other industrial mineral plants. In this regard, this study proposes a new application area of CPM and suggests the implementation details of mineral processing workflows with particular emphasis on marble production facilities. In the study, the CPM is applied to marble processing plants for selecting an applicable production process and for determining the workflow schema in order to optimize the cost of operation and to effectively manage time. As a consequence of this analysis, a new production plan is proposed for medium-scale marble processing plants. A suitable marble processing plant has been built and taken into operation in accordance with the proposed plant plan. It has been observed that this plant has a higher production rate at a preferable capacity when compared to three other plants studied as a part of this research.     

Numerical Simulation of the FDTD Method in LabVIEW [Application Notes]

LabVIEW (Laboratory Virtual Instrument Engineering Workbench) is a National Instruments program development. In this article, we present an FDTD code developed in Lab VIEW for basic scattering modeling. 1-D formulation with simple radiating boundary condition followed by a 2-D formulation is presented. The implementation of the PML boundary condition has been used to truncate the 2-D model used for the simulation to avoid reflections from the edges of the modeling grid. This particular formulation allows one to terminate any given material directly in the PML layers without virtually any reflection between the region of interest and the PML absorbing boundaries. The formulation uses the electric field E, the magnetic field H, and the electric displacement D rather than only the electric and magnetic fields as in usual FDTD implementation. This formulation has the advantage of making the PML properties completely independent of the background medium.     

Addendum to ‘(Singular) state models and (singular) LTID systems’

In this note, a construction of state representations of singular linear time-invariant differential systems is described directly in terms of trajectories.     

Evaluation of throughwall crack pipes under displacement controlled loading

Tearing modulus solutions are developed for flawed throughwall pipes subjected to displacement controlled loading. Two cases of loading were considered: (1) a displacement controlled bending loading, and (2) a displacement controlled axial tension loading. A revised version of the EPRI J-integral estimation scheme is used in the development of the solutions. These solutions can be used for the entire range of elastic-plastic loading, from linear elastic, contained yielding, to large scale yielding of the crack section. Experimental data from pipes in bending were used to assess the accuracy of the compliant loading solutions. The evaluations were performed using elastic plastic J-integral (J) and tearing modulus (T) analysis methods. These solutions are shown to have good accuracy when used to predict the experimental results. The methodology and procedure can also be applied to part-throughwall cracks. These solutions have application to the leak before break fracture mechanics analyses.     

Effects of bovine serum albumin on the corrosion behaviour of AISI 316L, Co–28Cr–6Mo, and Ti–6Al–4V alloys in phosphate buffered saline solutions

The corrosion behaviour of AISI 316L, wrought Co–28Cr–6Mo and Ti–6Al–4V was studied in aerated solutions of phosphate buffered saline (PBS) at various concentrations of bovine serum albumin (BSA) at 37 °C. Open circuit potential, potentiodynamic polarization, linear polarization resistance (LPR) and electrochemical impedance spectroscopy (EIS) experiments along with X-ray photoelectron spectroscopy (XPS) on Co–28Cr–6Mo oxide layer were conducted to study the interaction of BSA and passive layers and to measure the corrosion rates. Ti–6Al–4V alloy had the lowest corrosion rate and the highest breakdown potential. It was shown that BSA has enhanced the alloy passive film stability at higher concentrations.     

Synthesis and characterization of two-armed poly(ɛ-caprolactone) polymers initiated by the Schiff's base complexes of copper(II) and nickel(II)

Two-armed poly(?-caprolactone) (TAPCL) polymers were successfully synthesized via the ring opening polymerization (ROP) of ?-caprolactone (?-CL) using the Schiff's base complexes [Cu(SAEE)₂] (1) and [Ni(SAEE)₂] (2), which have two hydroxyl functional groups, as the two-site initiators and tin(II) 2-ethylhexanoate (Sn(Oct)₂) as the catalyst in bulk at 115 °C. The Schiff's base complexes (1 and 2) were synthesized by utilizing the concentrated template synthesis method starting from salicyl aldehyde, 2-(2-aminoethoxy) ethanol and related metal acetate salts. The synthesized TAPCL polymers were characterized by GPC, FTIR, UV–vis, and electron paramagnetic resonance (EPR). The molecular weights of TAPCL polymers linearly increased with increasing molar ratio of the monomer to the initiator. The results obtained from FTIR, UV–vis, and EPR studies indicated that TAPCL polymers had the Schiff's base complexes at the junction point of PCL arms. The crystallization behavior of TAPCL was studied by using differential scanning calorimetry (DSC) and polarizing optical microscopy (POM). Thermal behavior of TAPCL was also investigated by thermogravimetrical analysis (TGA).     

Potentials and economic viability of small grain residue use as a source of energy in Serbia

One of the numerous challenges awaiting Serbia in the process of European integration is the increase in use of renewable sources of energy. The reason for such an increase is not merely a formal acceptance of European goals but the high energy import dependence, a relatively developed agricultural sector, with insufficiently exploited potentials of biomass, accompanied by an ever-growing awareness of the need for establishing long-lasting sustainable development. Serbia has a relatively undeveloped livestock sector which can absorb a limited portion of the biomass produced. Additionally, insufficient awareness on the part of farmers and the preconception of the low cost-effectiveness of biomass utilisation for the purpose of energy production are factors which, unsurprisingly, contribute to the current practice of burning the largest portion of the biomass produced on site, which is economically and ecologically unacceptable. This paper analyses the amounts of biomass available in Serbia and the prospects of its economically viable utilisation. The cost analysis conducted indicates that the energy obtained from small rectangular straw bales (the most widespread way of utilisation), is less costly by 28%, than the energy obtained from coal, whereas the energy obtained from round bales is cheaper by 34%. Sensitivity analysis has shown that the results obtained are relatively resistant to price changes in the most important inputs. The sensitivity is higher towards the efficiency of the machinery used; therefore, insistent efforts should be made for creating conditions where the introduction of more up-to-date technical solutions, already existing in developed countries, will become feasible.     

Interval-valued fuzzy graphs

We define the Cartesian product, composition, union and join on interval-valued fuzzy graphs and investigate some of their properties. We also introduce the notion of interval-valued fuzzy complete graphs and present some properties of self-complementary and self-weak complementary interval-valued fuzzy complete graphs.