Cellulose nanocrystal-mediated assembly of graphene oxide in natural rubber nanocomposites with high electrical conductivity

This study reports a green and powerful strategy for preparing cellulose nanocrystal (CNC)/graphene oxide (GO)/natural rubber (NR) nanocomposites hosting a 3D hierarchical conductive network. Due to good dispersibility and amphiphilic nature of CNC, well dispersed CNC/GO nanohybrids were prepared. Hydrogen bonding interactions between CNC and GO greatly enhanced the stability of the CNC/GO nanohybrids. CNC/GO nanohybrids were introduced into NR latex under sonication and the mixture was cast. Self-assembled CNC/GO nanohybrids preferentially dispersed in the interstice between latex microspheres allowing the construction of a 3D hierarchical conductive network. By combining strong hydrogen bonds and 3D conductive network, both electrical conductivity and mechanical properties (tensile strength and modulus) have been significantly improved. The electrical conductivity of the nanocomposite with 4 wt% GO and 5 wt% CNC exhibited an increase of nine orders of magnitude compared to the nanocomposite with only 4 wt% GO; meanwhile, the electrical percolation threshold was 3-fold lower than for NR/GO composites.     

Understanding student participation in undergraduate course communities: A case study

Participation is the cornerstone of any community. Promoting, understanding and properly managing it allows not only keeping the community sustainable, but also providing personalized services to its members and managers. This article presents a case study in which student participation in a course community was motivated using two different extrinsic mechanisms, and mediated by a software platform. The results were compared with a baseline community of the same course, in which participation was not motivated by external means. The analysis of these results indicates that managing a partially virtual course community requires the introduction of monitoring services, community managers and extrinsic mechanisms to motivate participation. These findings allow community managers to improve their capability for promoting participation and keeping the community sustainable. The findings also raise several implications that should be considered in the design of software supporting this kind of community, when managing the participation of its members.     

Mathematical morphology on hypergraphs,application to similarity and positive kernel

The focus of this article is to develop mathematical morphology on hypergraphs. To this aim, we define lattice structures on hypergraphs on which we build mathematical morphology operators. We show some relations between these operators and the hypergraph structure, considering in particular transversals and duality notions. Then, as another contribution, we show how mathematical morphology can be used for classification or matching problems on data represented by hypergraphs: thanks to dilation operators, we define a similarity measure between hypergraphs, and we show that it is a kernel. A distance is finally introduced using this similarity notion.     

A laboratory assessment of the impact of brewery wastewater discharge on sulfide and methane production in a sewer

The impact of brewery wastewater discharge on sulfide and methane production in a sewer was assessed. Experiments were carried out on laboratory scale sewer reactors consisting of both an experimental and a control reactor. The control reactor was intermittently fed with real fresh sewage while the experimental reactor was fed with a mixture of brewery and domestic wastewater at two different proportions (10 and 25% v/v). 10% v/v discharge of brewery wastewater increased the H2S and CH4 production rates in the sewer reactor by 40% and 30%, respectively. When the brewery wastewater fraction was increased to 25% v/v, the H2S production rate of the experimental reactor decreased to the level of the control reactor. In contrast, the CH4 production rate maintained at a level that was 30% higher than that in the control reactor. These results indicate that the discharge of brewery wastewater into sewers can give negative impacts in relation to odour and corrosion management of the systems and will increase the greenhouse gas emissions from sewers. The study also reveals that the impact of trade waste on the biological reactions in sewers is complex, and requires careful experimental assessment in each case.     

Licence de brevet et partage du risque: Résultats de simulation

Annals of Telecommunications - Le partage du risque est une des raisons les plus souvent avancées pour expliquer les clauses financières des contrats de licence. Pour autant, aucune...     

PI k mass production and an optimal circuit for the Nečiporuk slice

Letf: {0,1} ⁿ {0,1} ^m be anm-output Boolean function inn variables.f is called ak-slice iff(x) equals the all-zero vector for allx with Hamming weight less thank andf(x) equals the all-one vector for allx with Hamming weight more thank. Wegener showed that PI _k -set circuits (set circuits over prime implicants of lengthk) are at the heart of any optimum Boolean circuit for ak-slicef. We prove that, in PI _k -set circuits, savings are possible for the mass production of anyFX, i.e., any collectionF ofm output-sets given any collectionX ofn input-sets, if their PI _k -set complexity satisfiesSC _m (FX)3n+2m. This PI _k mass production, which can be used in monotone circuits for slice functions, is then exploited in different ways to obtain a monotone circuit of complexity 3n+o(n) for the Neiporuk slice, thus disproving a conjecture by Wegener that this slice has monotone complexity (n ^3/2). Finally, the new circuit for the Neiporuk slice is proven to be asymptotically optimal, not only with respect to monotone complexity, but also with respect to combinational complexity.     

Hysteresis‐Free 1D Network Mixed Halide‐Perovskite Semitransparent Solar Cells

The morphology of hybrid organic–inorganic perovskite films is known to strongly affect the performance of perovskite‐based solar cells. CH₃NH₃PbI_3‐xCl_x (MAPbI_3‐xCl_x) films have been previously fabricated with 100% surface coverage in glove boxes. In ambient air, fabrication generally relies on solvent engineering to obtain compact films. In contrast, this work explores the potential of altering the perovskites microstructure for solar cell engineering. This work starts with CH₃NH₃PbI_3‐xCl_x, films with grain morphology carefully controlled by varying the deposition speed during the spin‐coating process to fabricate efficient and partially transparent solar cells. Devices produced with a CH₃NH₃PbI_3‐xCl_x film and a compact thick top gold electrode reach a maximum efficiency of 10.2% but display a large photocurrent hysteresis. As it is demonstrated, the introduction of different concentrations of bromide in the precursor solution addresses the hysteresis issues and turns the film morphology into a partially transparent interconnected network of 1D microstructures. This approach leads to semitransparent solar cells with negligible hysteresis and efficiencies up to 7.2%, while allowing average transmission of 17% across the visible spectrum. This work demonstrates that the optimization of the perovskites composition can mitigate the hysteresis effects commonly attributed to the charge trapping within the perovskite film.     

Classical and variational multiscale LES of the flow around a circular cylinder on unstructured grids

The effects of numerical viscosity, subgrid scale (SGS) viscosity and grid resolution are investigated in LES and VMS-LES simulations of the flow around a circular cylinder at Re=3900 on unstructured grids. The separation between the largest and the smallest resolved scales in the VMS formulation is obtained through a variational projection operator and finite-volume cell agglomeration. Three different non-dynamic eddy-viscosity SGS models are used both in classical and in VMS-LES. The so-called small-small formulation is used in VMS-LES, i.e. the SGS viscosity is computed as a function of the smallest resolved scales. Two different grid resolutions are considered. It is found that, for each considered SGS model, the amount of SGS viscosity introduced in the VMS-LES formulation is significantly lower than in classical LES. This, together with the fact that in the VMS formulation the SGS viscosity only acts on the smallest resolved scales, has a strong impact on the results. However, a significant sensitivity of the results to the considered SGS model remains also in the VMS-LES formulation. Moreover, passing from classical LES to VMS-LES does not systematically lead to an improvement of the quality of the numerical predictions.     

Measurement of enterprise knowledge by state characterization

Abstract: Enterprise production is becoming more and more knowledge oriented nowadays and knowledge management is playing a key role in making commercial profit and maintaining enterprise competence. Knowledge characterization and measurement are the bases of knowledge management, and this paper aims to develop a method for characterizing and measuring knowledge in a comprehensive and practical way. Knowledge in its static state is modelled as a vector, whose values vary with the situation, and changes in state are modelled as a finite state machine.