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51.
52.
Fiona M. Blighe Karen Young Juan J. Vilatela Alan H. Windle Ian A. Kinloch Libo Deng Robert J. Young Jonathan N. Coleman 《Advanced functional materials》2011,21(2):364-371
We have measured the mechanical properties of coagulation‐spun polymer–nanotube composite fibers. Both the fiber modulus, Y, and strength, σB, scale linearly with volume fraction, Vf, up to Vf ~10%, after which these properties remain constant. We measured dY/dVf = 254 GPa and dσB/dVf = 2.8 GPa in the linear region. By drawing fibers with Vf < 10% to a draw ratio of ~60%, we can increase these values to dY/dVf = 600 GPa and dσB/dVf = 7 GPa. Raman measurements show the Herman's orientation parameter, S, to increase with drawing, indicating that significant nanotube alignment occurs. Raman spectroscopy also shows that the nanotube effective modulus, YEff, also increases with drawing. We have calculated an empirical relationship between the nanotube orientation efficiency factor, ηo, and S. This allows us to fit the data for YEff versus ηo, showing that the fiber modulus scales linearly with ηo, as predicted theoretically by Krenchel. From the fit, we estimate the nanotube modulus to be; YNT = 480 GPa. Finally, we show that the fiber strength also scales linearly with ηo, giving an effective interfacial stress transfer of τ = 40 MPa and a nanotube critical length of lc=1250 nm. This work demonstrates the validity of the Cox‐Krenchel rule of mixtures and shows that continuum theory still applies at the near‐molecular level. 相似文献
53.
Layer 2 and 3 virtual private networks: taxonomy, technology, and standardization efforts 总被引:6,自引:0,他引:6
Virtual private network services are often classified by the OSI layer at which the VPN service provider's systems interchange VPN reachability information with customer sites. Layer 2 and 3 VPN services are currently being designed and deployed, even as the related standards are being developed. This article describes the wide range of emerging L2 and L3 VPN architectures and technical solutions or approaches, and discusses the status of standards work. Some specific L2VPN and L3VPN technologies described here include virtual private LAN service, transparent LAN service, BGP/MPLS-based VPNs (RFC 2547bis), virtual router, and IPSec VPN approaches. We discuss recent and continuing standards efforts in the IETF 12vpn and 13vpn working groups, and related work in the pseudo-wire emulation edge-to-edge working group, as well as in some other standards fora, and describe some mechanisms that provide membership, reachability, topology, security, and management functions. 相似文献
54.
Scott N. Schiffres Kyu Hun Kim Lin Hu Alan J. H. McGaughey Mohammad F. Islam Jonathan A. Malen 《Advanced functional materials》2012,22(24):5251-5258
The thermal conductivity of gas‐permeated single‐walled carbon nanotube (SWCNT) aerogel (8 kg m?3 density, 0.0061 volume fraction) is measured experimentally and modeled using mesoscale and atomistic simulations. Despite the high thermal conductivity of isolated SWCNTs, the thermal conductivity of the evacuated aerogel is 0.025 ± 0.010 W m?1 K?1 at a temperature of 300 K. This very low value is a result of the high porosity and the low interface thermal conductance at the tube–tube junctions (estimated as 12 pW K?1). Thermal conductivity measurements and analysis of the gas‐permeated aerogel (H2, He, Ne, N2, and Ar) show that gas molecules transport energy over length scales hundreds of times larger than the diameters of the pores in the aerogel. It is hypothesized that inefficient energy exchange between gas molecules and SWCNTs gives the permeating molecules a memory of their prior collisions. Low gas‐SWCNT accommodation coefficients predicted by molecular dynamics simulations support this hypothesis. Amplified energy transport length scales resulting from low gas accommodation are a general feature of CNT‐based nanoporous materials. 相似文献
55.
GABA(A) receptors composed of alpha1beta3 gamma2 and alpha1beta3 subunits were expressed in insect Sf9 cells and solubilized in 1% Triton X100. In sucrose density gradients, [3H]-Ro15-1788 binding activity, in the case of alpha1beta3 gamma2, and [3H]-muscimol binding activity, in the case of alpha1beta3 containing receptors sedimented as a single sharp peak suggesting the formation of receptors containing a defined number of subunits. When alpha1beta3gamma2 -containing receptors were incubated with an alpha-subunit specific antibody (bd24), a single class of antibody receptor complex was formed irrespective of the receptor-antibody ratio. This is consistent with two alpha subunits cross-linked within the receptor by the antibody. Similar results were obtained using a beta-subunit specific antibody (bd17). Several classes of antibody-receptor complex were formed when receptors were pre-incubated with a gamma specific antibody (anti gamma(2) 1-15 Cys). This profile is consistent with the presence of a single gamma subunit in each complex. Experiments with alpha1beta3 subunit containing receptors and antibody bd24 produced a profile similar to that seen with alpha1beta3 gamma2 receptors, consistent with two alpha subunits per receptor complex. In this case, the anti-beta subunit antibody, bd17, produced a unique and complex profile consistent with three beta subunits per receptor. This method permits the rapid determination of subunit stoichiometries of homogeneous receptor populations 相似文献
56.
Optical tweezers are an important tool for studying cellular and molecular biomechanics. We present a robust optical tweezers device with advanced features including: multiple optical traps, acousto-optic trap steering, and back focal plane interferometry position detection. We integrate these features into an upright microscope, with no compromise to its capabilities (differential interference contrast microscopy, fluorescence microscopy, etc.). Acousto-optic deflectors (AODs) steer each beam and can create multiple time-shared traps. Position detection, force calibrations and AOD performance are presented. The system can detect subnanometer displacements and forces below 0.1 pN. 相似文献
57.
朗讯科技(中国)公司借上海“2005年中国国际信息通信展览会”之机,于2005年6月21日在沪举办了“2005通信服务高层论坛-朗讯服务解决方案研讨会”,邀请国内政府机构、运营商以及企业代表与来自国际知名运营商和朗讯全球服务部(IWS)的专家们一道,共同探讨通信业务和通信服务面临的挑战、未来发展方向以及相关的服务解决方案。 相似文献
58.
The majority of off-road vehicles employed in agriculture are equipped with a hydraulic steering. An efficient way of automating the steering mechanism of these vehicles is by controlling the electrohydraulic valve that operates the steering cylinder. Electronically-controlled hydraulic valves often behave nonlinearly and, consequently, they introduce certain complexities in the analysis of the hydraulic system. Therefore, it is necessary to understand their behavior before designing a control system that is able to auto-steer an agricultural machine safely and efficiently. The objective of this work was to characterize the performance of an electrohydraulic valve with the aid of a set of experiments conducted on a hardware-in-the-loop electrohydraulic simulator. The operation of the valve was classified in four types (I, II, III, and IV) according to the valve characteristic curves and the properties of the input signal. The phenomena of deadband, hysteresis, and saturation helped to discriminate between types. The input signal, especially its frequency, was crucial in studying the functioning of the valve. The hardware-in-the-loop simulator was fed with signals that imitated the auto-steering action. The outcomes obtained from this research provide some critically supporting information for designing high performance steering controllers for agricultural vehicles. 相似文献
59.
Alan Pasha Tabatabai Daniel S. Seara Joseph Tibbs Vikrant Yadav Ian Linsmeier Michael P. Murrell 《Advanced functional materials》2021,31(10):2006745
Unlike nearly all engineered materials which contain bonds that weaken under load, biological materials contain “catch” bonds which are reinforced under load. Consequently, materials, such as the cell cytoskeleton, can adapt their mechanical properties in response to their state of internal, non-equilibrium (active) stress. However, how large-scale material properties vary with the distance from equilibrium is unknown, as are the relative roles of active stress and binding kinetics in establishing this distance. Through course-grained molecular dynamics simulations, the effect of breaking of detailed balance by catch bonds on the accumulation and dissipation of energy within a model of the actomyosin cytoskeleton is explored. It is found that the extent to which detailed balance is broken uniquely determines a large-scale fluid-solid transition with characteristic time-reversal symmetries. The transition depends critically on the strength of the catch bond, suggesting that active stress is necessary but insufficient to mount an adaptive mechanical response. 相似文献
60.
Marcus A. OMara Sean P. Ogilvie Matthew J. Large Aline Amorim Graf Anne C. Sehnal Peter J. Lynch Jonathan P. Salvage Izabela Jurewicz Alice A. K. King Alan B. Dalton 《Advanced functional materials》2020,30(32)
Here, an approach is presented to incorporate graphene nanosheets into a silicone rubber matrix via solid stabilization of oil‐in‐water emulsions. These emulsions can be cured into discrete, graphene‐coated silicone balls or continuous, elastomeric films by controlling the degree of coalescence. The electromechanical properties of the resulting composites as a function of interdiffusion time and graphene loading level are characterized. With conductivities approaching 1 S m?1, elongation to break up to 160%, and a gauge factor of ≈20 in the low‐strain linear regime, small strains such as pulse can be accurately measured. At higher strains, the electromechanical response exhibits a robust exponential dependence, allowing accurate readout for higher strain movements such as chest motion and joint bending. The exponential gauge factor is found to be ≈20, independent of loading level and valid up to 80% strain; this consistent performance is due to the emulsion‐templated microstructure of the composites. The robust behavior may facilitate high‐strain sensing in the nonlinear regime using nanocomposites, where relative resistance change values in excess of 107 enable highly accurate bodily motion monitoring. 相似文献