Hybrid Organic/Inorganic Nanostructures for Highly Sensitive Photoelectrochemical Detection of Dissolved Oxygen in Aqueous Media

Precise, reliable, and remote measurement of dissolved oxygen in aqueous media is of great importance for many industrial, environmental, and biological applications. In particular, photoelectrochemical sensors working in differential mode have recently demonstrated promising properties, in terms of stability, sensitivity, and application potential. Here, a new approach is presented, combining visible light sensitivity, efficient photocurrent generation, and solution‐processed fabrication methods of conjugated polymers, with charge carriers selectivity, energetic alignment favorable to efficient interfacial charge transfer and high surface area achievable by using metal oxide nanostructures. Extensive characterization and optimization of the hybrid organic/inorganic system are carried out, leading to the realization of an oxygen sensor device, based on nanostructured palladium oxide/poly[(9,9‐dioctylfluorenyl‐2,7‐diyl)‐alt‐5,5‐(4′,7′‐di‐2‐thienyl‐2′,1′,3′‐benzothiadiazole]/[6,6]phenyl‐C61‐butyric acid methyl ester (PdO/APFO‐3:PCBM) as materials of choice. State‐of‐the‐art sensitivity, amounting at ?5.87 μA cm^?2 ppm^?1, low background signal, in the order of ?4.85 μA cm^?2, good electrochemical stability for more than 2 h of continuous functioning and high reproducibility of the signal over the pH 1 to 10 range, are reported, making the hybrid device suitable for several practical uses. The results fully validate the mixed organic/inorganic approach for photoelectrochemical applications, and pave the way for its further exploitation in fields like waste water treatment, environmental monitoring, and water splitting.     

Dynamic modeling of tunable analog integrated filters for a stability study of on-chip automatic tuning loops

Continuous-time filters with automatic tuning loops are nonlinear feedback systems that are potentially unstable. To ensure stability, particularly if the design of the loop controllers is to be improved, the appropriate linear dynamic modeling of the tunable filter, including control inputs, should be attained. This work aims to present a general dynamic modeling of continuous-time analog filters with automatic tuning capability. The general analysis leads to an equivalent small-signal linearized incremental model, from which transfer functions between output variables and control voltages are obtained. Subsequent to the analysis, it is possible to design compensated loops with enhanced stability and dynamic performance. By way of example, the modeling of a particular band-pass CMOS continuous-time analog filter is presented in this paper. Two transfer functions are derived: the transfer function between the output phase shift and the central frequency control voltage, and that between the output amplitude and the quality factor control voltage. These functions are required to properly tune the central frequency and quality factor parameters. This modeling makes it possible to propose an adaptive controller with improved stability and a possible implementation for such a controller. Finally, experimental results are shown for a CMOS 0.8 μm technology.     

Thermal Aging Effects on Cu Ball Shear Strength and Cu/Al Intermetallic Growth

Intermetallic growth and ball shear behavior of annealed Cu wire bonds on Al have been studied. The shear strength of Cu ball bonds decreased with time, and ductile fracture was the dominant failure mode from 125°C to 150°C. Al pad peel-off occurred as the aging temperature was increased above 150°C. The overall Cu/Al intermetallic thickness exhibited parabolic behavior as a function of time. A linear correlation was established between ball shear strength, metal peel-off occurrence, and intermetallic growth. The Cu/Al intermetallic growth activation energy was 0.23 eV, and the intermetallics identified in the experiment were CuAl₂ and CuAl.     

License Plate Recognition for Parking Control System by Mathematical Morphology

Nowadays, license plate recognition for parking systems is a critical task to provide automatic control of customers and payment. This paper introduces a new method for automatic recognition of license plates of vehicles by mathematical morphology.The proposed method can provide the license plate number of the plates in different light conditions, colors,sizes, and inclination(angles). The algorithm can recognize the license plates of European Union vehicles quickly and correctly. The pattern learning of mathematical skeletons has high efficiency in the process. The performance of the algorithm is demonstrated well by the test in a parking control system.     

Design of Engineered Elastomeric Substrate for Stretchable Active Devices and Sensors

In the field of flexible electronics, emerging applications require biocompatible and unobtrusive devices, which can withstand different modes of mechanical deformation and achieve low complexity in the fabrication process. Here, the fabrication of a mesa‐shaped elastomeric substrate, supporting thin‐film transistors (TFTs) and logic circuits (inverters), is reported. High‐relief structures are designed to minimize the strain experienced by the electronics, which are fabricated directly on the pillars' surface. In this design configuration, devices based on amorphous indium‐gallium‐zinc‐oxide can withstand different modes of deformation. Bending, stretching, and twisting experiments up to 6 mm radius, 20% uniaxial strain, and 180° global twisting, respectively, are performed to show stable electrical performance of the TFTs. Similarly, a fully integrated digital inverter is tested while stretched up to 20% elongation. As a proof of the versatility of mesa‐shaped geometry, a biocompatible and stretchable sensor for temperature mapping is also realized. Using pectin, which is a temperature‐sensitive material present in plant cells, the response of the sensor shows current modulation from 13 to 28 °C and functionality up to 15% strain. These results demonstrate the performance of highly flexible electronics for a broad variety of applications, including smart skin and health monitoring.     

A highly efficient receiver for satellite‐based automatic identification system signal detection

An innovative receiver architecture for the satellite‐based automatic identification system has been recently proposed. In this paper, we describe a few modifications that can be introduced on the algorithms for synchronization and detection, which provide an impressive performance improvement. The receiver architecture has been designed for an on‐board implementation, and a prototype has been implemented by the University of Parma and CGS S.p.A. Compagnia Generale per lo Spazio under the European Space Agency project FENICE (Flexible innovative AIS receiver prototype). A few modifications are also here described that could allow a further performance improvement in case of processing moved to ground‐based stations, based on a priori information there available. Copyright © 2014 John Wiley & Sons, Ltd.     

Antioxidant activity of virgin olive oil phenolic compounds in a micellar system†

The antioxidant activity of two virgin olive oils, obtained from the same olive (Olea europaea sativa) batch but processed with different hammer crushing conditions, was evaluated by measuring their protective action towards linoleic acid peroxidation in a micellar system. The antioxidant efficiency (AE) of the oil phenolic fraction was higher when the olives were processed with a higher hammer crusher rotation rate. HPLC analysis demonstrated that one of the main derivatives of oleuropein, indicated as 3,4-DHPEA-EDA (the dialdehydic form of elenolic acid linked with 3,4-dihydroxyphenylethanol), is present only in the oil with higher AE. 3,4-DHPEA-EDA showed the greatest antioxidant ability among virgin olive oil phenols. Its greater efficiency in the micellar system in comparison with 3,4-dihydroxyphenylethanol (3,4-DHPEA) is related to its greater lipophilicity. It is suggested that the behaviour in the water–micellar environment is representative of that in a real system such as tomato-based sauce with added virgin olive oil. © 1999 Society of Chemical Industry     

Melanin films on Au(1 1 1): Adsorption and molecular conductance

We have studied the adsorption and electronic properties of thin melanin films on Au(1 1 1) by scanning tunneling microscopy (STM), scanning tunneling spectroscopy (STS), and density functional (DF) calculations. We have found that the minimum melanin unit detected under different adsorption conditions is consistent with the structural model for eumelanin protomolecules based on tetramer macrocycles formed by four monomer units (hydroquinone, indolequinone and its tautomers) with an inner porphyrin ring. DF calculations reveal that the entire π structure of the tetramers is implied in the chemisorption process through its frontier orbitals (HOMO and LUMO), a fact that is reflected in the change of intramolecular bonds. Also van der Waals interactions give an important contribution to the adsorption energy (≈0.02 eV/Ų). Dried thin melanin films (1 monolayer in thickness) exhibit good electronic conductance due to the presence of localized states near the Fermi level while dried thicker films exhibit a semiconductor-like behavior. Illumination of the thicker films with white light results in significant photo-induced tunneling currents when the melanin-covered Au is made negative with respect to the tip.     

Thermal Stability of Ge<Subscript>2</Subscript>Sb<Subscript>2</Subscript>Te<Subscript>5</Subscript> in Contact with Ti and TiN

The thermal stability of a Ge₂Sb₂Te₅ chalcogenide layer in contact with titanium and titanium nitride metallic thin films has been investigated mainly using x-ray diffraction and elastic nuclear backscattering techniques. Without breaking vacuum, Ti and TiN have been deposited on Ge₂Sb₂Te₅ material using magnetron sputtering. Thermal treatments have been performed in a 10⁻⁷ mbar vacuum furnace. On annealing up to 450°C, the TiN metallic film does not interact with the chalcogenide film, but at the same time adhesion problems and instabilities in contact resistance arise. To improve the adhesion and eventually stabilize the contact resistance, an interfacial Ti layer has been considered. At 300°C, a TiTe₂ compound is formed by interacting with Te segregated from the Ge₂Sb₂Te₅ layer. At higher temperatures, the Ti layer decomposes the chalcogenide film, forming several compounds tentatively identified as GeTe, Ge₃Ti₅, Ge₅Ti₆, TiTe_2,, and Sb₂Te₃. It has been found that the properties of the Ge₂Sb₂Te₅ film can be retained by controlling the decomposition rate of the chalcogenide layer, which is achieved by providing a limited supply of Ti and/or by depositing a Te-rich Ge₂Sb₂Te₅ film.