Structural Changes in the BODIPY Dye PM567 Enhancing the Laser Action in Liquid and Solid Media

In the search for more efficient and photostable solid‐state dye lasers, newly synthesized analogs of the borondipyrromethene (BODIPY) dye PM567, bearing the polymerizable methacryloyloxypropyl group at position 2 (PMoMA) or at positions 2 and 6 (PDiMA), have been studied in the form of solid copolymers with methyl methacrylate (MMA). The parent dye PM567, as well as the model analogs bearing the acetoxypropyl group in the same positions, PMoAc and PDiAc, respectively, have been also studied both in liquid solvents and in solid poly(MMA) (PMMA) solution. Although in liquid solution PMoAc and PDiAc have the same photophysical properties as PM567, PDiAc exhibited a photostability up to 10 times higher than that of PM567 in ethanol under 310 nm‐irradiation. The possible stabilization factors of PDiAc have been analyzed and discussed on the basis of the redox potentials, the ability for singlet molecular oxygen [O₂(¹Δ_g)] generation, the reactivity with O₂(¹Δ_g), and quantum mechanical calculations. Both PMoAc and PDiAc, pumped transversally at 532 nm, lased in liquid solution with a high (up to 58 %), near solvent‐independent efficiency. This enhanced photostabilization has been also observed in solid polymeric and copolymeric media. While the solid solution of the model dye PDiAc in PMMA showed a lasing efficiency of 33 %, with a decrease in the laser output of ca. 50 % after 60 000 pump pulses (10 Hz repetition rate) in the same position of the sample, the solid copolymer with the double bonded chromophore, COP(PDiMA‐MMA), showed lasing efficiencies of up to 37 %, and no sign of degradation in the laser output after 100 000 similar pump pulses. Even under the more demanding repetition rate of 30 Hz, the laser emission from this material remained at 67 % of its initial laser output after 400 000 pump pulses, which is the highest laser photostability achieved to date for solid‐state lasers based on organic polymeric materials doped with laser dyes. This result indicates that the double covalent linkage of the BODIPY chromophore to a PMMA polymeric matrix is even more efficient than the simple linkage, for its photostabilization under laser operation.     

Properties and Printability of Inkjet and Screen-Printed Silver Patterns for RFID Antennas

We report the modeling, and geometrical and electrical characterization, of inkjet and screen-printed patterns on different polymeric substrates for use as antennas in radio-frequency identification (RFID) applications. We compared the physical and electrical characteristics of two silver nanoparticle-based commercial inkjet-printable inks and one screen-printable silver paste, when deposited on polyimide (PI), polyethylene terephthalate (PET), and polyetherimide (PEI) substrates. First, the thickness of the inkjet-printed patterns was predicted by use of an analytical model based on printing conditions and ink composition. The predicted thickness was confirmed experimentally, and geometrical characterization of the lines was completed by measuring the root-mean-square roughness of the patterns. Second, direct-current electrical characterization was performed to identify the printing conditions yielding the lowest resistivity and sheet resistance. The minimum resistivity for the inkjet-printing method was 8.6 ± 0.8 μΩ cm, obtained by printing four stacked layers of one of the commercial inks on PEI, whereas minimum resistivity of 44 ± 7 μΩ cm and 39 ± 4 μΩ cm were obtained for a single layer of screen-printed ink on polyimide (PI) with 140 threads/cm mesh and 90 threads/cm mesh, respectively. In every case, these minimum values of resistivity were obtained for the largest tested thickness. Coplanar waveguide transmission lines were then designed and characterized to analyze the radio-frequency (RF) performance of the printed patterns; minimum transmission losses of 0.0022 ± 0.0012 dB/mm and 0.0016 ± 0.0012 dB/mm measured at 13.56 MHz, in the high-frequency (HF) band, were achieved by inkjet printing on PEI and screen printing on PI, respectively. At 868 MHz, in the ultra-high-frequency band, the minimum values of transmission loss were 0.0130 ± 0.0014 dB/mm for inkjet printing on PEI and 0.0100 ± 0.0014 dB/mm for screen printing on PI. Although the resistivity achieved is lower for inkjet printing than for screen printing, RF losses for inkjetted patterns were larger than for screen-printed patterns, because thicker layers were obtained by screen printing. Finally, several coil inductors for the HF band were also fabricated by use of both printing techniques, and were used as antennas for semi-passive smart RFID tags on plastic foil capable of measuring temperature and humidity.     

A multiwinding modeling method for high frequency transformers and inductors

This paper presents a method to obtain an electric model for transformers and inductors, including both frequency and geometry effects in the windings, which can be linked with existing core models. One-dimensional distributions for magnetic and electric fields are assumed, and from Maxwell's equations an equivalent electric circuit is easily obtained. This equivalent circuit has been included in analog simulators (Spice, AnalogWorkBench, Saber ...), and comparisons between measured and simulated results are shown, both in time domain and in AC sweep, which verify the model accuracy. The model described in this paper allows designers to deal with key issues in the design of high-frequency magnetic components (copper losses, leakage inductance, skin and proximity effects) by using analog simulators, which are usually more familiar to them than finite-element analysis tools.     

Interfacing Renewable Energy Sources to the Utility Grid Using a Three-Level Inverter

This paper presents a novel approach for the connection of renewable energy sources to the utility grid. Due to the increasing power capability of the available generation systems, a three-level three-phase neutral-point-clamped voltage-source inverter is selected as the heart of the interfacing system. A multivariable control law is used for the regulator because of the intrinsic multivariable structure of the system. A current source (playing the role of a generic renewable energy source) is connected to the grid using a three-level inverter in order to verify the good performance of the proposed approach. Large- and small-signal d-q state-space averaged models of the system are obtained and used to calculate the multivariable controller based on the linear quadratic regulator technique. This controller simultaneously regulates the dc-link voltage (to operate at the maximum power point of the renewable energy source), the mains power factor (the power is delivered to the grid at unity power factor), and the dc-link neutral-point voltage balance. With the model and regulator presented, a specific switching strategy to control the dc-link neutral-point voltage is not required. The proposed controller can be used for any application, since its nature makes possible the control of any system variable. The good performance of the presented interfacing solution in both steady-state and transient operation is verified through simulation and experimentation using a 1-kW neutral-point-clamped voltage-source-inverter prototype, where a PC-embedded digital signal processor board is used for the controller implementation     

Thermal characterisation of power devices during transient operation

An experimental infrared method for the thermal characterisation of semiconductor devices during fast transient operation, in the range from a few microseconds and up to some milliseconds, is presented. The features which make it suitable and convenient, particularly for use with power electronics applications are pointed out; its time and space resolution are illustrated by means of properly chosen examples. The considered solution qualifies as a very versatile and powerful tool in many diverse lines of investigation.     

An On-Chip Spectrum Analyzer for Analog Built-In Testing

This paper presents an analog built-in testing (BIT) architecture and its implementation. It enables the frequency response and harmonic distortion characterizations of an integrated device-under-test (DUT) through a digital off-chip interface. External analog instrumentation is avoided, reducing test time and cost. The proposed on-chip testing scheme uses a digital frequency synthesizer and a simple signal generator synchronized with a switched capacitor bandpass filter. A general methodology for the use of this structure in the functional verification of a DUT is also provided. The circuit-level design and experimental results of an integrated prototype in standard CMOS 0.5 m technology are presented to demonstrate the feasibility of the proposed BIT technique.Marcia G. Mendez-Rivera was born in Irapuato, Mexico in 1972. She received the Communications and Electronics Engineering Degree from the Universidad de Guanajuato, Guanajuato, Mexico. in 1996, the M.Sc. degree from the Instituto Nacional de Astrofisica, Optica y Electronica (INAOE), Puebla, Mexico in 1998 and the M.Sc. from Texas A&M University, College Station in 2002. Her research interest is in the design and fabrication of analog and mixed-signal circuits.Alberto Valdes-Garcia born in 1978, grew up in San Mateo Atenco, Mexico. He received the B.S. in Electronic Systems Engineering degree from the Monterrey Institute of Technology (ITESM), Campus Toluca, Mexico in 1999 (with honors as the best score from all majors). Since the fall of 2000 he has been working towards the Ph.D. degree at Analog and Mixed-Signal Center (AMSC), Texas A&M University. During the spring and summer of 2000 he was a Design Engineer with Motorola Broadband Communications Sector. In the summer of 2002 he was with the Read Channel Design Group at Agere Systems where he investigated wide tuning range GHz LC VCOs for mass storage applications. During the summer of 2004 he was with the Mixed-Signal Communications IC Design Group at the IBM T. J. Watson Research Center, where worked on design and analysis of SiGe power amplifiers for millimeter wave radios. Since the fall of 2001 he has been a Semiconductor Research Corporation (SRC) research assistant at the AMSC working on the development of analog built-in testing techniques. Since the fall of 2000, Alberto has been the recipient of a scholarship from the Mexican National Council for Science and Technology (CONACYT). He represented Mexico in the 1994 Odyssey of the Mind World Creativity Contest and in the 1997 International Exposition for Young Scientists. His present research interests include built-in testing implementations for analog and RF circuits, system level design for wireless receivers and RF circuit design for UltraWideBand (UWB) communications.Jose Silva-Martinez was born in Tecamachalco, Puebla, México. He received the B.S. degree in electronics from the Universidad Autónoma de Puebla, México, in 1979, the M.Sc. degree from the Instituto Nacional de Astrofísica Optica y Electrónica (INAOE), Puebla, México, in 1981, and the Ph.D. degree from the Katholieke Univesiteit Leuven, Leuven Belgium in 1992. From 1981 to 1983, he was with the Electrical Engineering Department, INAOE, where he was involved with switched-capacitor circuit design. In 1983, he joined the Department of Electrical Engineering, Universidad Autonoma de Puebla, where he remained until 1993; He was a co-founder of the graduate program on Opto-Electronics in 1992. From 1985 to 1986, he was a Visiting Scholar in the Electrical Engineering Department, Texas A&M University. In 1993, he re-joined the Electronics Department, INAOE, and from May 1995 to December 1998, was the Head of the Electronics Department; He was a co-founder of the Ph.D. program on Electronics in 1993. He is currently with the Department of Electrical Engineering (Analog and Mixed Signal Center) Texas A&M University, at College Station, where He holds the position of Associate Professor. His current field of research is in the design and fabrication of integrated circuits for communication and biomedical application. Dr. Silva-Martinez has served as IEEE CASS Vice President Region-9 (1997–1998), and as Associate Editor for IEEE Transactions on Circuits and Systems part-II from 1997–1998 and May 2002–December 2003. Since January 2004 is serving as Associate Editor of IEEE TCAS Part-I. He was the main organizer of the 1998 and 1999 International IEEE-CAS Tour in region 9, and Chairman of the International Workshop on Mixed-Mode IC Design and Applications (1997–1999). He is the inaugural holder of the TI Professorship-I in Analog Engineering, Texas A&M University. He was a co-recipient of the 1990 European Solid-State Circuits Conference Best Paper Award.Edgar Sánchez-Sinencio was born in Mexico City, Mexico. He received the degree in communications and electronic engineering (Professional degree) from the National Polytechnic Institute of Mexico, Mexico City, the M.S.E.E. degree from Stanford University, CA, and the Ph.D. degree from the University of Illinois at Urbana-Champaign, in 1966, 1970, and 1973, respectively. In 1974 he held an industrial Post-Doctoral position with the Central Research Laboratories, Nippon Electric Company, Ltd., Kawasaki, Japan. From 1976 to 1983 he was the Head of the Department of Electronics at the Instituto Nacional de Astrofísica, Optica y Electrónica (INAOE), Puebla, Mexico. He was a Visiting Professor in the Department of Electrical Engineering at Texas A&M University, College Station, during the academic years of 1979–1980 and 1983-1984. He is currently the TI J Kilby Chair Professor and Director of the Analog and Mixed-Signal Center at Texas A&M University. He was the General Chairman of the 1983 26th Midwest Symposium on Circuits and Systems. He was an Associate Editor for IEEE Trans. on Circuits and Systems, (1985–1987), and an Associate Editor for the IEEE Trans. on Neural Networks. He is the former Editor-in-Chief of the Transactions on Circuits and Systems II. He is co-author of the book Switched Capacitor Circuits (Van Nostrand-Reinhold 1984), and co-editor of the book Low Voltage/Low-Power Integrated Circuits and Systems (IEEE Press 1999). In November 1995 he was awarded an Honoris Causa Doctorate by the National Institute for Astrophysics, Optics and Electronics, Mexico. The first honorary degree awarded for Microelectronic Circuit Design contributions. He is co-recipient of the 1995 Guillemin-Cauer for his work on Cellular Networks. He is a former IEEE CAS Vice President-Publications. He was also the co-recipient of the 1997 Darlington Award for his work on high-frequency filters He received the Circuits and Systems Society Golden Jubilee Medal in 1999. He was the IEEE Circuits and Systems Society, Representative to the Solid-State Circuits Society (2000–2002). He is presently a member of the IEEE Solid-State Circuits Fellow Award Committee. His present interests are in the area of RF-Communication circuits and analog and mixed-mode circuit design. He is an IEEE Fellow Member since 1992.     

Synthesis,size-dependent optoelectronic and charge transport properties of thieno(bis)imide end-substituted molecular semiconductors

The synthesis of two new thieno(bis)imide (TBI, N) end functionalized oligothiophene semiconductors is reported. In particular, trimer (NT3N) and pentamer (NT5N) have been synthesized and characterized. Two different synthetic approaches for their preparation were tested and compared namely conventional Stille cross coupling and direct arylation reaction via C–H activation. Theoretical calculations, optical and electrochemical characterization allowed us to assess the role of the π-conjugation extent, i.e., of the oligomer size on the optoelectronic properties of these materials. In both TBI ended compounds, due to the strong localization of the LUMO orbital on the TBI unit, the LUMO energy is almost insensitive to the oligomer size, this being crucial for the fine-tailoring of the energy and the distribution of the frontier orbitals. Surprisingly, despite its short size and contrarily to comparable TBI-free analogues, NT3N shows electron charge transport with mobility up to μ_N = 10⁻⁴ cm² V⁻¹ s⁻¹, while increasing the oligomer size to NT5N promotes ambipolar behavior and electroluminescence properties with mobility up to μ_N = 0.14 cm² V⁻¹ s⁻¹ and to μ_P = 10⁻⁵ cm² V⁻¹ s⁻¹.     

An intrinsic order criterion to evaluate large, complex fault trees

A new efficient algorithm is introduced to evaluate (non) coherent fault trees, obtaining exact lower & upper bounds on system unavailability, with a prespecified maximum error. The algorithm is based on the canonical normal form of the Boolean function, but overcomes the large number of terms needed, by using an intrinsic order criterion (IOC) to select the elementary states to evaluate. This intrinsic order implies lexicographic (truth table) order. The criterion guarantees a priori that the probability of a given elementary system state is always greater than or equal to the probability of another state, for any set of basic probabilities. IOC is exclusively based on the positions of 0 & 1 in the binary n-tuples defining the elementary states. The algorithm does not require any qualitative analysis of the fault tree. The computational cost mainly depends on the basic event probabilities, and is related to system complexity, only because the Boolean function must be evaluated.     

Hybrid Organic/Inorganic Nanostructures for Highly Sensitive Photoelectrochemical Detection of Dissolved Oxygen in Aqueous Media

Precise, reliable, and remote measurement of dissolved oxygen in aqueous media is of great importance for many industrial, environmental, and biological applications. In particular, photoelectrochemical sensors working in differential mode have recently demonstrated promising properties, in terms of stability, sensitivity, and application potential. Here, a new approach is presented, combining visible light sensitivity, efficient photocurrent generation, and solution‐processed fabrication methods of conjugated polymers, with charge carriers selectivity, energetic alignment favorable to efficient interfacial charge transfer and high surface area achievable by using metal oxide nanostructures. Extensive characterization and optimization of the hybrid organic/inorganic system are carried out, leading to the realization of an oxygen sensor device, based on nanostructured palladium oxide/poly[(9,9‐dioctylfluorenyl‐2,7‐diyl)‐alt‐5,5‐(4′,7′‐di‐2‐thienyl‐2′,1′,3′‐benzothiadiazole]/[6,6]phenyl‐C61‐butyric acid methyl ester (PdO/APFO‐3:PCBM) as materials of choice. State‐of‐the‐art sensitivity, amounting at ?5.87 μA cm^?2 ppm^?1, low background signal, in the order of ?4.85 μA cm^?2, good electrochemical stability for more than 2 h of continuous functioning and high reproducibility of the signal over the pH 1 to 10 range, are reported, making the hybrid device suitable for several practical uses. The results fully validate the mixed organic/inorganic approach for photoelectrochemical applications, and pave the way for its further exploitation in fields like waste water treatment, environmental monitoring, and water splitting.     

Boundary Element Modeling of the Realistic Human Body Exposed to Extremely-Low-Frequency (ELF) Electric Fields: Computational and Geometrical Aspects

This paper presents the human exposure assessment to high-voltage extremely-low-frequency (ELF) fields by the three-dimensional (3-D) boundary element method (BEM). The formulation is based on a realistic, anatomically based representation of the human body. The main objective is to analyze the influence of the relative position of the arms with respect to the body on the axial distribution of current density along the body and to determine the most vulnerable regions. Numerical results along head, neck, torso, abdomen, arms, legs, and ankles are presented and discussed in the case of grounded subject standing under power-distribution lines and in the vicinity of power transformer substations