“Collapsible” lightweight aggregate concrete. Part II: characterization under static and dynamic loadings

In this work a granular cementitious composite has been developed, tailoring its performance to a low compressive strength and high deformation and energy dissipation capacity, which can be required to the material when employed in post-installed screeds for protection of structures and infrastructures against accidental actions such as impact and blast. The required level of performance can be achieved by uniform grain size distribution, paste content as low as minimum theoretical void ratio and low paste strength: it is believed that the synergy between the aforementioned three requirements can allow for energy dissipation capacity after paste cracking due to both rearrangement of grain meso-structure and, in case, grain crushing. After the mix design concept and optimization of the material composition, illustrated in the first part of this companion paper study, the mechanical performance of the composite under static and impact compressive loadings has been thoroughly characterized, as affected by mix-design variables, such as paste volume fraction, water to cement ratio and aggregate size. The reliability will thus be thoroughly checked, of the employed material concept, and the influence will also be investigated, if any, of specimen shape, size and boundary conditions.     

Quantised control of nonlinear systems: analysis of robustness to parameter uncertainty,measurement errors,and exogenous disturbances

We propose a variant of the recently introduced strategy for stabilisation with limited information by D. Liberzon and J.P. Hespanha and analyse its robustness properties. We show that, if the nominal plant can be made input-to-state stable with respect to measurement errors, parameter uncertainty and exogenous disturbances, then this robustness is preserved with this quantised feedback. More precisely, if a sufficient bandwidth is available on the communication network, then the resulting closed loop is shown to be semiglobally input-to-state practically stable.     

Ionic liquids as diathermic fluids for solar trough collectors’ technology: A corrosion study

The AISI 304 and AISI 1018 steels (frequently used in solar collectors’ plants) in contact with four different ionic liquids (ILs) suitable as diathermic fluids, were studied. Immersion tests were performed at 220 °C (the working temperature in such plants) for 10 days. The corrosion morphologies of the steels were investigated by scanning electron microscopy coupled with energy dispersive X-ray (EDX) microanalysis and the content of metals in the solution were detected via ICP-OES. The tests showed that the most performing IL is the ethyl-dimethyl-propyl-ammonium-bis(trifluoromethylsulphonyl)imide. The corrosion properties of the two alloys in contact with such IL were investigated by means of Tafel plots and resistance polarization at room temperature in open-to-air vessels.     

Effective wind actions on ideal and real structures

Gust buffeting of structures is analyzed by Double Modal Transformation, a method consisting in the joint transformation into principal components of structural displacements (modal analysis) and of wind loading (proper orthogonal decomposition). It commonly occurs that modal truncation applies to both the series of structural and loading modes; besides, many loading modes are almost orthogonal respect the dominant structural modes, so they do not contribute to structural response. This set of conditions allows the introduction of an effective action, defined as the loading process reconstructed retaining only those loading modes that excite the structure. This paper discusses this method and the related concepts by analyzing a set of simple ideal structures in closed form; this approach allows the formulation of general criteria aimed at defining the effective wind action as a function of non-dimensional structural and wind parameters. The numerical analysis of a real structure confirms the tendencies pointed out by the analytical solutions.     

Soft-Seeded Pomegranate (<Emphasis Type="Italic">Punica granatum</Emphasis> L.) Varieties: Preliminary Characterization and Quality Changes of Minimally Processed Arils During Storage

A preliminary characterization of two new soft-seeded pomegranate varieties (MR-100® and KINGDOM®) based on their main physico-chemical and nutritional parameters was reported. The two varieties showed significant differences (p ≤ 0.05) in polyphenols, anthocyanins and antioxidant activity. Kingdom pomegranate had higher polyphenols (2524.73 mg GAE/L), anthocyanins (752.49 mg C₃gE/L) and antioxidant activity (EC₅₀ 13.58 μL/mL) than MR-100 (1792.74 mg GAE/L, 141.29 mg C₃gE/L and EC₅₀ 47.53 μL/mL, respectively). Moreover, minimally processed arils of the two varieties were packaged in semipermeable and micro-perforated film at 5 °C, and the quality changes that occurred during storage condition (15 days) were investigated. During storage, Kingdom arils exhibited a better performance in terms of antioxidant activity, polyphenols and anthocyanin content with respect to MR-100. Furthermore, the packaging systems did not affect the estimated quality parameters for both varieties. Based on the sensory evaluation and microbial counts, both aril varieties reached, at 15-day storage, suitable values for commercial purpose.     

An experimental and kinetic modeling study of cyclopentadiene pyrolysis: First growth of polycyclic aromatic hydrocarbons

The importance of 1,3-cyclopentadiene (CPD) and cyclopentadienyl (CPDyl) moieties in the growth of polycyclic aromatic hydrocarbons (PAHs) was studied using new experimental data and ab initio calculations. The experimental investigation was performed in a tubular continuous flow pyrolysis reactor under both high (24molN₂/molCPD)$(24{\text{mol}}_{{\text{N}}_2}/{\text{mol}}_{\text{CPD}})$ and low (5molN₂/molCPD)$(5{\text{mol}}_{{\text{N}}_2}/{\text{mol}}_{\text{CPD}})$ nitrogen dilutions, covering a temperature range of 873–1123 K, at a fixed pressure of 1.7 bara. At the most severe conditions up to 84% of CPD is converted, and the amount of PAHs is more than 65 wt%. Major products observed during CPD pyrolysis were benzene, indene, methyl-indenes and naphthalene, in line with previous studies. On-line GC × GC-FID/(TOF-MS) also allowed to quantify minor species (methane, toluene, styrene, phenanthrene, anthracene, etc.), never reported before at this level of accuracy. The new experimental data have been used to further analyze the role of the successive interactions of CPD, indene, and naphthalene as well as the recombination and addition reactions of their resonantly stabilized radicals and refine their kinetics. The results of the modeling study are in good agreement with existing and new experimental observations.     

Generation of continuous variable squeezing and entanglement of trapped ions in time-varying potentials

We investigate the generation of squeezing and entanglement for the motional degrees of freedom of ions in linear traps, confined by time-varying and oscillating potentials, comprised of a DC and an AC component. We show that high degrees of squeezing and entanglement can be obtained by controlling either the DC or the AC trapping component (or both), and by exploiting transient dynamics in regions where the ions’ motion is unstable, without any added optical control. Furthermore, we investigate the time-scales over which the potentials should be switched in order for the manipulations to be most effective.