Preparation and antibacterial activity of novel fluoroalkyl end-capped oligomers/silica nanocomposites-encapsulated low molecular biocides

Fluoroalkyl end-capped N-(1,1-dimethyl-3-oxobutyl)acrylamide oligomer [R_F-(DOBAA) _n -R_F] reacted with tetraethoxysilane (TEOS) and silica nanoparticles in the presence of low-molecular weight biocides such as hibitane, hinokitiol, and hinokioil under alkaline conditions to afford R_F-(DOBAA) _n -R_F/silica nanocomposites-encapsulated these biocides in excellent to moderate isolated yields. Fluoroalkyl end-capped N,N-dimethylacrylamide oligomer [R_F-(DMAA) _n -R_F] and acrylic acid oligomer [R_F-(ACA) _n -R_F]/silica nanocomposites-encapsulated hibitane were obtained under similar conditions. Dynamic light scattering measurements showed that the size of these fluorinated nanocomposites-encapsulated biocides thus obtained is nanometer size-controlled. Additionally, these fluorinated nanocomposites were shown to have a good dispersibility and stability in methanol and water. Of particular interest, these fluorinated nanocomposites-encapsulated biocides were found to have a good antibacterial activity against Staphylococcus aureus, and these nanocomposites were applied to the surface modification of traditional organic polymers such as poly(methyl methacrylate).     

Prediction of ultrasonic wave velocity in particleboard and fiberboard

Ultrasonic wave velocities were determined at parallel and perpendicular to manufacturing direction and at the interval angles of 15° in clockwise and counterclockwise directions of particleboard and fiberboard. The experimental results were compared with the predicted values using some empirical formulae such as Hankinson and Jacoby equations. The results showed that the ultrasonic wave velocity were the highest in parallel direction in particleboard and fiberboard and decreases with increase of angle and the lowest values occurred in perpendicular direction. The predicted ultrasonic velocity using Hankinson and Jacoby equations are in close agreement with the measured values. Relationship between ultrasonic wave velocities and particles and fibers angle could be successfully presented by cubic and quadratic regression equations as well.     

Preparation of gold nanoparticles (GNP) aqueous suspensions by a new method involving Tiron

A new method is proposed to produce gold nanoparticles (GNP) by in situ reduction of a gold salt dissolved in water. The reducing agent used is Tiron instead of the citrate anion most often mentioned in literature. The influence of various parameters has been investigated, such as the content of Tiron with respect to that of the precursor of gold HAuCl₄, or the initial pH of the solution after mixing of reactants. It is shown that Tiron also exerts a positive influence as a dispersant, which impedes agglomeration of gold nanoparticles. The typical average size of GNP synthesized in the present work is close to 7 nm.     

Ugtracold Alkali Atoms in Optical Lattices: A New Type of Quantum Crystals?

Similarities between alkali gases in optical lattices with non-integer occupation of the lattice sites and quantum crystals are explored. The analogy with the vacancy liquid provides an agternative explanation to the Mott transition for the recent experiment on the phase transition in the lattice. The vacancy liquid can undergo BEC with T _c within experimental reach. Direct and vacancy-assisted mechanisms of the band motion for hyperfine impurities are discussed. The presence of vacancies can resugt in the spatial decomposition of the system into pure hyperfine components. Below BEC for the vacancies, the impurity component resembles ³He in ³He-Hell mixtures.     

Conference diary

A variational higher-order theory for bending and stretching of linearly elastic orthotropic beams including the deformations due to transverse shearing and stretching of the transverse normal fibre is presented. The theory assumes a linear distribution for the longitudinal displacement and a parabolic variation of the transverse displacement across the thickness. Additionally, independent expansions are introduced for the through-thickness displacement gradients with the requirement of a least-square compatibility for the transverse strains and the satisfaction of exact stress boundary conditions at the top/bottom beam surfaces. The theory is shown to be well suited for finite element development requiring simple C⁰- and C^?1- continuous displacement interpolation fields. To demonstrate the computational utility of the theory, a simple two-node stretching-bending finite element is formulated. The analytic and finite element results are obtained for a simple bending problem for which an exact elasticity solution is available. It is shown that the inclusion of the transverse normal deformation in the present theory enables improved displacement, strain and stress predictions, particularly, in the analysis of deep beams.     

Stimulation of negative magnetoresistance by an electric field and light in silicon doped with boron and manganese

It is experimentally ascertained that light stimulates the negative magnetoresistance observed in a high electric field in silicon doped with boron and manganese. The optimum conditions (the electric field, temperature, illumination, and resistivity of the material) for observation of the largest magnitude of negative magnetoresistance in (Si:B):Mn are determined. The dependence of the negative magnetoresistance on the concentration of compensating impurity is established.