Direct <Emphasis Type="SmallCaps">d</Emphasis>-Glucose Oxidation over Noble Metal Nanoparticles Introduced on Polymer and Inorganic Supports

In the present work, nanocatalysts prepared on inorganic supports (zeolites) were investigated in d-glucose oxidation and compared to systems supported on polymer (hypercrosslinked polystyrene (HPS)) previously described. Catalytic activities and selectivities were measured under various reaction conditions. The selectivity of d-glucose oxidation and activity of both Pd-containing zeolites and HPS-Ru were similar (99.7% and TOF 0.013–0.014 mol/(mol Me s)). Physicochemical analysis X-ray photoelectron spectroscopy, liquid nitrogen physisorption, diffuse reflectance infrared Fourier transform spectroscopy of adsorbed CO for metal sites evaluation, CD₃CN for acid sites evaluation showed that Pd species were in oxidic form, while Ru species were in oxidic and reduced form. The catalytic activity decreased when acidic sites were present in Pd-containing zeolites.     

Calcium pulstrodes with 10-fold enhanced sensitivity for measurements in the physiological concentration range

Ion-selective electrodes ideally operate on the basis of the Nernst equation, which predicts less than 60- and 30-mV potential change for a 10-fold activity change of monovalent and divalent ions measured at room temperature, respectively. Typical concentration ranges in extracellular fluids are quite narrow for the electrolytes of key importance. A range of 2.2-2.6 mM for calcium ions, for instance, translates into just a 2.2-mV potential change. The direct potentiometric measurement of physiological electrolytes is certainly possible with direct potentiometry and is done routinely in clinical analyzers and handheld measuring devices. It places, however, strong demands on the precision of the reference electrode and requires careful temperature control and frequent calibration runs. In this paper, a robust 10-20-fold sensitivity enhancement for calcium measurements is attained by departing from the classical response mechanism and operating in a non-Nernstian response mode. Stable and reproducible super-Nernstian responses of these so-called pulstrodes in a narrow calcium activity range can be controlled by instrumental means in good agreement with theory. The potentials may be measured during a galvanostatic excitation pulse (mode I) or immediately after it (mode II), under open-circuit conditions. Subtraction of the potentials, sampled at different times during a single pulse, allows one to obtain a sensitive differential peak-shaped signal at a critical and fully adjustable analyte activity range. Calcium pulstrodes based on the diamide ionophore AU-1 were characterized and applied to the measurement in model physiological liquids. Super-Nernstian responses exceeding 700 mV/decade were observed in a physiological range of calcium concentration. Such remarkable sensitivity of the pulstrodes, complemented with the well-documented high selectivity of these potentiometric sensors, may provide a significant increase in the accuracy and precision of electrolyte measurements in clinical analysis.     

Kinetics of ion-exchange-induced vitrification of glass-ceramics

Micro-Raman spectroscopy was applied to characterize the ion-exchange-induced vitrification of silicate glass-ceramics with lithium metasilicate crystalline phase. In parallel, the glass-ceramics vitrification was simulated on the base of the theory developed. Comparison of the data obtained with micro-Raman spectroscopy with the results of the simulation allowed revealing the kinetic parameters of vitrification process and evaluating the corresponding activation energies. These experimental approach and theory can be applied to other types of glass-ceramics.     

Optimal Cyclic Exploitation of Renewable Resources

The paper contributes to the topic of optimal utilization of spatially distributed renewable resources. Namely, a problem of “sustainable” optimal cyclic exploitation of a renewable resource with logistic law of recovery is investigated. The resource is distributed on a circle and is collected by a single harvester moving along the circle. The recovering and harvesting rates are position dependent, and the latter depends also on the velocity of the harvester, which is considered as a control. The existence of an optimal solution is proved, as well as necessary optimality conditions for the velocity of the harvester. On this base, a numerical approach is proposed, and some qualitative properties of the optimal solutions are established. The results are illustrated by numerical examples, which reveal some economically meaningful features of the optimal harvesting.     

On the role of dealing with quantum coherence in amplitude amplification

Amplitude amplification is one of primary tools in building algorithms for quantum computers. This technique generalizes key ideas of the Grover search algorithm. Potentially useful modifications are connected with changing phases in the rotation operations and replacing the intermediate Hadamard transform with arbitrary unitary one. In addition, arbitrary initial distribution of the amplitudes may be prepared. We examine trade-off relations between measures of quantum coherence and the success probability in amplitude amplification processes. As measures of coherence, the geometric coherence and the relative entropy of coherence are considered. In terms of the relative entropy of coherence, complementarity relations with the success probability seem to be the most expository. The general relations presented are illustrated within several model scenarios of amplitude amplification processes.     

Ferromagnet/Superconductor Hybridization for Magnonic Applications

In this work, a new hybridization of superconducting and ferromagnetic orders is demonstrated, promising for magnonics. By measuring the ferromagnetic and spin wave resonance absorption spectra of a magnetostatically coupled permalloy/niobium bilayer at different temperatures, magnetostatic spin wave resonances with unconventional dispersion are observed. The mechanism behind the modified dispersion, confirmed with micromagnetic simulations, implies screening of the alternating magnetostatic stray fields of precessing magnetic moments in the ferromagnetic layer by the superconducting surface in the Meissner state.     

Circumnavigation of a speedy unpredictable target by a group of speed‐ and acceleration‐limited robots

An unpredictably maneuvering speedy target travels in a plane, which also hosts a team of fully actuated robots whose velocities and accelerations are upper‐bounded in magnitude. The robots should approach the target and then follow it at a prespecified distance. They also should achieve an even self‐distribution around the target and a given angular velocity of rotation about the target. Every robot has access to the relative position of the target and other robots (in the latter case, within a finite “visibility” range) and to the angular speed of its own pure rotation; access to the coordinates of its own linear velocity in its own local frame is also employed in some cases. The robots are not equipped with communication facilities and cannot distinguish among one another; assignment of different roles to various robots is infeasible. Necessary conditions for the mission feasibility are first obtained. A distributed control law is then presented, and its global convergence and collision avoidance property are rigorously justified under slight enhancement of the just mentioned necessary conditions. The performance of the control law is illustrated by computer simulations.     

Active Control of Thermal Convection in a Rectangular Loop by Changing its Spatial Orientation

The problem of the automatic control of the fluid flow in a rectangular convective loop heated from below is studied theoretically and experimentally. The control is performed by using a feedback subsystem which changes the convection regimes by introducing small discrete changes in the spatial orientation of the loop with respect to gravity. We focus on effects that arise when the feedback controller operates with an unavoidable time delay, which is cause by the thermal inertia of the medium. The mathematical model of the phenomenon is developed. The dynamic regimes of the convection in the thermosyphon loop under control are studied. It is shown that the proposed control method can successfully stabilize not only a no-motion state of the fluid, but also time-dependent modes of convection including the irregular fluid flow at high values of the Rayleigh number. It is shown that the excessive gain of the proportional feedback can result in oscillations in the loop orientation exciting the unsteady convection modes. The comparison of the experimental data obtained for dielectric oil and dodecane with theory is given, and their good agreement is demonstrated.     

A combined technique for amplifier oriented small‐signal noise model extraction

Based on the earlier experimental investigation of the existing GaAs pHEMT small‐signal modeling approaches and their applicability to different manufacturing processes, a combined automatic small‐signal noise model extraction technique, suitable for design of low‐noise and buffer amplifiers is proposed. The technique is based on the usage of measured S‐parameters of passive test structures and S‐parameters of the transistor in cold modes. Expressions are given for extraction of the intrinsic parameters of an equivalent circuit using linear regression. It is shown that the application of the proposed method allows extracting a small‐signal GaAs pHEMT model both in the probe‐tip reference planes and at on‐wafer calibration planes. The moving average algorithm was applied for preprocessing the results of measurements of the 50 Ohm noise figure during extraction of the noise model. The results of S‐parameters and noise figure simulation agree well with the measurements. The new technique was implemented as a plugin in a commercial EDA tool and enables to derive a ready‐to use small‐signal noise model from measured S‐parameters and 50 Ohm noise figure of a 0.15 μm GaAs pHEMT.