Retrieval of the ultraviolet aerosol optical depth during a spring campaign in the Bavarian Alps

A measurement campaign was organized in March 1999 in the Bavarian Alps as part of the European project, Characteristics of the UV Radiation Field in the Alps (CUVRA), to analyze the effect of altitude, aerosols, and snow cover on ground-level UV spectral irradiance. We present the results of simultaneous measurements of aerosol optical depth (AOD) made at various sites on two cloudless days in March 1999. The two days exhibited different aerosol conditions. Results derived from spectral measurements of UV irradiance are compared with data from filter radiometer measurements made at discrete wavelengths extending from the UV to the near IR. The different methods generated values for the AOD that were in good agreement. This result confirms that one can use either method to retrieve the AOD with an uncertainty of approximately 0.03-0.05. On 18 March, high turbidity was observed at low altitude (400-nm AOD approximately 0.5 at 700 m above sea level), and the AOD decreased regularly with altitude; on 24 March, the turbidity was much less (0.11 at 700 m above sea level). On both days very low AODs (0.05-0.09) were measured at 3000 m above sea level. The spectral dependence of the AOD is often parameterized by the angstrom relationship; the alpha parameter is generally difficult or impossible to retrieve from spectral measurements because of the relatively narrow wavelength range (320-400 nm), and only one of the spectro-radiometers used during the campaign permits this retrieval. In most cases, during this field campaign, alpha was found by filter sunphotometers to be 1.1-1.5.     

Flying over the reality gap: From simulated to real indoor airships

Because of their ability to naturally float in the air, indoor airships (often called blimps) constitute an appealing platform for research in aerial robotics. However, when confronted to long lasting experiments such as those involving learning or evolutionary techniques, blimps present the disadvantage that they cannot be linked to external power sources and tend to have little mechanical resistance due to their low weight budget. One solution to this problem is to use a realistic flight simulator, which can also significantly reduce experimental duration by running faster than real time. This requires an efficient physical dynamic modelling and parameter identification procedure, which are complicated to develop and usually rely on costly facilities such as wind tunnels. In this paper, we present a simple and efficient physics-based dynamic modelling of indoor airships including a pragmatic methodology for parameter identification without the need for complex or costly test facilities. Our approach is tested with an existing blimp in a vision-based navigation task. Neuronal controllers are evolved in simulation to map visual input into motor commands in order to steer the flying robot forward as fast as possible while avoiding collisions. After evolution, the best individuals are successfully transferred to the physical blimp, which experimentally demonstrates the efficiency of the proposed approach. Jean-Christophe Zufferey and Alexis Guanella contributed equally to this work.     

Plasma corticosterone fluctuations in an infant-learning paradigm.

Plasma corticosterone fluctuations of infant rats were examined in a learning task. A blood sample for analysis of plasma corticosterone was collected from groups of 10- and 15-day-old pups following either no disturbance, standard maternal deprivation only, or deprivation and training in an established approach-mother, avoid-shock conflict task. In the latter condition, pups remained in the goalbox either alone or with an anesthetized dam for either 15 or 60 min before blood sample collection. Plasma corticosterone levels were elevated following deprivation plus training in pups of both ages and following deprivation only in the 15-day-old pups. Further, the presence of the dam in the goalbox reduced plasma corticosterone elevations, particularly among 15-day-old pups and at 60 min. These findings suggest that the mother's capacity to moderate the pup's plasma corticosterone response may contribute to her reinforcement value in infant-learning paradigms. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Identification of a phosphopantetheinyl transferase for erythromycin biosynthesis in Saccharopolyspora erythraea

Phosphopantetheinyl transferases (PPTases) catalyze the essential post-translational activation of carrier proteins (CPs) from fatty acid synthases (FASs) (primary metabolism), polyketide synthases (PKSs), and non-ribosomal polypeptide synthetases (NRPSs) (secondary metabolism). Bacteria typically harbor one PPTase specific for CPs of primary metabolism ("ACPS-type" PPTases) and at least one capable of modifying carrier proteins involved in secondary metabolism ("Sfp-type" PPTases). In order to identify the PPTase(s) associated with erythromycin biosynthesis in Saccharopolyspora erythraea, we have used the genome sequence of this organism to identify, clone, and express (in Escherichia coli) three candidate PPTases: an ACPS-type PPTase (S. erythraea ACPS) and two Sfp-type PPTases (a discrete enzyme (SePptII) and another that is integrated into a modular PKS subunit (SePptI)). In vitro analysis of these recombinant PPTases, with an acyl carrier protein-thioesterase (ACP-TE) didomain from the erythromycin PKS as substrate, revealed that only SePptII is active in phosphopantetheinyl transfer with this substrate. SePptII was also shown to provide complete modification of ACP-TE and of an entire multienzyme subunit from the erythromycin PKS in E. coli. The efficiency of the SePptII in phosphopantetheinyl transfer in E. coli makes it an attractive alternative to other Sfp-type PPTases for co-expression experiments with PKS proteins.     

On the designing of densely dispersion-managed optical fiber systems for ultrafast optical communication

We present some theoretical and experimental results which suggest the possibility of constructing a non-empirical methodology of designing optical transmission systems with ultra high bit-rate per channel. Theoretically, we present an average dispersion decreasing densely dispersion-managed (A4dm) fiber system, which exhibits many advantages over the densely dispersion-managed fiber system, such as the possibility of transmitting chirp-free Gaussian pulses at 160 Gbit/s per channel over transoceanic distances, with a reduced energy and minimal intra-channel interaction. Experimentally we present generation of a 160-GHz picosecond pulse train at 1550 nm using multiple four-wave mixing temporal compression of an initial dual frequency beat signal in the anomalous-dispersion regime of a non-zero dispersion shifted fiber. A complete intensity and phase characterization of the pulse train by means of a frequency-resolved optical gating technique is achieved, showing generation of transform-limited pedestal-free Gaussian pulses.     

Recommendations of RILEM TC 127-MS: Tests for masonry materials and structures

RILEM Technical CommitteesRILEM TC 127-MS: Non Destructive Tests for Masonry Materials and Structures

Recommendations of RILEM TC 127-MS: Tests for masonry materials and structures     

Silicon shadow mask fabrication for patterned metal deposition with microscale dimensions using a novel corner compensation scheme

Pattern deposition of metals with controlled and microscale dimensions can be a challenging task if traditional photolithography is not a practical option. This is a particularly valid concern for the case of certain polymer substrates, which are gaining in importance in the microelectronics and related industries. Therefore, a novel design and process flow for batch fabricating low cost reusable silicon shadow masks was developed. Of note was the corner compensation scheme employed to avoid over-etching of the convex corners in the design. These shadow masks enabled deposition of metals or other suitable materials with feature sizes ranging from approximately 3 to 250 μm and were successfully utilized to form patterned metal heater lines and pads on various samples. The heaters, required for conducting thermal conductivity measurements of the underlying films/substrates using the three omega (3ω) method, showed resistance–temperature linearity, confirming theoretical estimates to within 0.2%. Moreover, the room temperature thermal conductivity of an amorphous SiO₂ film as well as a polyaniline thick film were measured, further validating the deposition through shadow mask technique.     

Application of a new algorithm using Doppler information to retrieve complex wind fields over the Black Sea from ENVISAT SAR images

Several algorithms have been proposed to retrieve near-surface wind fields from C-band synthetic aperture radar (SAR) images acquired over the ocean. They mainly differ in the way they retrieve the wind direction. Conventionally, the wind direction is taken from atmospheric models or is extracted from the linear features sometimes visible in SAR images. Recently, a new wind retrieval algorithm has been proposed, which also includes the Doppler shift induced by motions of the sea surface. In this article, we apply three wind retrieval algorithms, including the one using Doppler information, to three complex wind events encountered over the Black Sea and compare the SAR-derived wind fields with model wind fields calculated using the high-resolution weather research and forecasting (WRF) model. It is shown that the new algorithm is very efficient in resolving the 180° ambiguity in the wind direction, which is often a problem in the streak-based wind retrieval algorithms. However, the Doppler-based algorithm only yields good results for wind directions that have a significant component in the look direction of the SAR antenna. Furthermore, it is dependent on good separation of the contributions to the Doppler shift induced by surface currents and wind-related effects (wind drift and wind-sea components of the ocean wave spectrum). We conclude that an optimum wind retrieval algorithm should consist of a combination of the algorithms based on linear features and Doppler information.     

综合性公园公共交通可达性及规划配置均衡性

公共交通出行方式下,综合性公园的可达性及配置的均衡性是评价城市公园绿地配置和本地居民享有公共服务设施权利的重要指标。以南京市为例,建立公共交通复合网络,以时间成本距离分析综合性公园服务的区域水平和基于站点位置的可达性;以基尼系数判断全局和15分钟生活圈下综合性公园分布的均衡性及贡献度;建立新公园选址采样点,分析增加新公园选址后的基尼系数变化的空间分布。结果表明：以可达性为前提,以基尼系数为衡量指标,可以量化分析公园分布均衡性,通过基尼系数更新变化的空间分布,可以明确新规划公园对综合性公园分布均衡性的影响,能够确定优化选址区域。为城市新综合性公园规划提供量化的区域范围参考,优化城市公园布局并提高城市公园可达性和分布均衡性。     

Mastering Surface Reconstruction of Metastable Spinel Oxides for Better Water Oxidation

Developing highly active electrocatalysts for oxygen evolution reaction (OER) is critical for the effectiveness of water splitting. Low‐cost spinel oxides have attracted increasing interest as alternatives to noble metal–based OER catalysts. A rational design of spinel catalysts can be guided by studying the structural/elemental properties that determine the reaction mechanism and activity. Here, using density functional theory (DFT) calculations, it is found that the relative position of O p‐band and M_Oh (Co and Ni in octahedron) d‐band center in ZnCo_2?xNi_xO₄ (x = 0–2) correlates with its stability as well as the possibility for lattice oxygen to participate in OER. Therefore, it is testified by synthesizing ZnCo_2?xNi_xO₄ spinel oxides, investigating their OER performance and surface evolution. Stable ZnCo_2?xNi_xO₄ (x = 0–0.4) follows adsorbate evolving mechanism under OER conditions. Lattice oxygen participates in the OER of metastable ZnCo_2?xNi_xO₄ (x = 0.6, 0.8) which gives rise to continuously formed oxyhydroxide as surface‐active species and consequently enhances activity. ZnCo_1.2Ni_0.8O₄ exhibits performance superior to the benchmarked IrO₂. This work illuminates the design of highly active metastable spinel electrocatalysts through the prediction of the reaction mechanism and OER activity by determining the relative positions of the O p‐band and the M_Oh d‐band center.