Behaviour of sand–clay mixtures for road pavement subgrade

Materials forming sand grains and colluvial soil deposits have a distinct structure, consisting of a composite matrix of coarse and fine soil grains. The influence of sand grains content on the behaviour of sand–clay mixtures was investigated by a series of intensive laboratory experiments. The California bearing ratio (CBR), unconfined compression strength (UCS) and compaction tests were carried out on various contents of sand and clay mixtures. The sand–clay mixtures were prepared with sand contents of 0, 10, 20, 30, 40, and 50% by weight. The laboratory tests on these mixtures have indicated that their behaviour will depend on the relative concentration of the sand and clay samples. The results of the tests showed a decrease in the UCS, and an increase the CBR values with an increase in the amount of sand. An increase in dry unit weight and a decrease in respective moisture content by an increase in the amount of sand were observed in the compaction tests.     

Sorption of uranium from waste effluent solutions by mesoporous carbon impregnated with trioctylamine

A new mesoporous adsorbent for uranium removal from waste effluents was prepared, characterized, and impregnated with trioctylamine. The adsorption efficiency was investigated as a function of pH, contact time, initial uranium concentration, competing ions, solid/liquid ratio, and temperature using batch sorption techniques. The maximum adsorption capacity was 21.9 mg g^–1 at pH 5. The equilibrium data fit well with the Langmuir adsorption isotherm. Kinetic study showed that the process was fast and reached equilibrium within 60 min. The kinetic data fit well with the pseudo-second-order law. Thermodynamic data show that the process is spontaneous and exothermic.     

Preparation and Characterization of Magnetite–Chitosan Nanoparticles and Evaluation of Their Cytotoxicity Effects on MCF7 and Fibroblast Cells

Nowadays, magnetic nanoparticles play a key role in drug treatment. However, if they are uncoated, they might aggregate and cause embolism in drug delivery. To avoid this, they are generally coated with polymers. In this investigation, magnetic nanoparticles (MNPs) were coated with chitosan through in situ co-precipitation process and their properties in addition to their cytotoxicity in MCF7 and fibroblast cells were analyzed. The results showed MNPs–chitosan nanoparticles would contain an average mean diameter of 32 nm and a saturation magnetization (M _S) value of 38.87 emu/g. To characterize the synthesized nanoparticles in terms of structural, morphological and magnetic properties, Fourier transform infrared (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermal gravimetric analysis (TGA) and vibrating sample magnetometry (VSM) studies were used. Toxicity test was also done to investigate whether their presence would cause any toxicity in the body; in addition, antibacterial assay was done to analyze if nanoparticles could be used as an antimicrobial agent.     

Investigation of deep drawing concept of multi-point forming process in terms of prevalent defects

Multi-point forming is a novel flexible process that is economically suitable for both rapid prototyping and batch production of sheet metal parts. This technique is established based on altering rigid dies by matrices of adjustable punch elements. In this paper, the basic principle of this technique is implemented on deep drawing process. A reconfigurable die was constructed to investigate the multi-point deep drawing process. AA 2024-O Aluminum alloy was designated as test material. The formed specimens were evaluated in terms of dimpling defect, rupture, thickness distribution and dimensional accuracy. The onset of rupture was predicted by integrating the forming limit diagram of employed material with finite element Code. The predicted results were in a reasonable agreement with the experimental tests. It was found that for complete elimination of dimpling defect and acquiring maximum drawing depth, the proper allocation of elastic layer parameters such as thickness and hardness was crucial. The conducted investigations indicated that, in general, dimensional accuracy of formed parts was acceptable. However, for areas with sharp changes in geometry such as corners and side walls, deviation from desired geometry was evident. This phenomenon was remarkably dominant for manufactured parts utilizing softer elastic layer.     

Fabrication of biopolymer based nanocomposite wound dressing: evaluation of wound healing properties and wound microbial load

The aim of this study is to introduce natural‐based polymers, chitosan and starch, to design a remedial nanocomposite, comprising of cerium oxide nanoparticles and silver nanoparticles, to investigate their effects in accelerating wound healing and in wound microbial load. Cerium oxide nanoparticles synthesized in starch solution added to the colloidal dispersion of synthesized silver nanoparticles in chitosan to make a three‐component nanomaterial. Mice were anaesthetized and two parallel full‐thickness round wounds were excised under aseptic conditions with the help of sterile dermal biopsy punch. Furthermore, effects of silver‐chitosan and silver‐cerium‐chitosan nanocomposite had evaluated on rate of wound closure and collagen density and on microbial load of wound in full‐thickness model. Results showed that both silver chitosan and silver‐cerium‐chitosan had significant impact on acceleration of wound closure and collagen content and on reduction of wound microbial load in comparison with control group, which was, received no treatments. However, the silver‐cerium‐chitosan nanocomposite is more potent than silver‐chitosan group and control group in wound closure. The wound healing effects of silver‐cerium‐chitosan nanocomposite are due to unique features of its three components and this nanocomposite promises impressive remedies for clinical application.Inspec keywords: wounds, nanocomposites, nanomedicine, nanoparticles, proteins, cerium, silver, polymers, colloids, patient treatmentOther keywords: biopolymer‐based nanocomposite wound dressing, wound healing properties, wound microbial load, natural‐based polymers, chitosan, remedial nanocomposite, cerium oxide nanoparticles, nanoceria, silver nanoparticles, starch solution, three‐component nanomaterial, synthesised silver nanoparticles, ketamine intraperitoneal injection, silver‐cerium‐chitosan nanocomposite, wound closure, collagen density, wound healing effects, wound care, aseptic conditions, sterile dermal biopsy punch, Ag‐Ce     

Eco‐friendly synthesis of silver nanoparticles and its larvicidal property against fourth instar larvae of Aedes aegypti

In this study, larvicidal activity of silver nanoparticles (AgNPs) synthesised using apple extract against fourth instar larvae of Aedes aegypti was determined. As a result, the AgNPs showed moderate larvicidal effects against Ae. aegypti larvae (LC₅₀  = 15.76 ppm and LC₉₀  = 27.7 ppm). In addition, comparison of larvicidal activity performance of AgNPs at high concentration prepared using two different methods showed that Ae. aegypti larvae was fully eliminated within the duration of 2.5 h. From X‐ray diffraction, the AgNP crystallites were found to exhibit face centred cubic structure. The average size of these AgNPs as estimated by particle size distribution was in the range of 50–120 nm. The absorption maxima of the synthesised Ag showed characteristic Ag surface plasmon resonance peak. This green synthesis provides an economic, eco‐friendly and clean synthesis route to Ag.Inspec keywords: silver, nanofabrication, X‐ray diffraction, zoology, particle size, nanoparticles, biomedical materials, nanomedicineOther keywords: time 2.5 h, size 50 nm to 120 nm, silver nanoparticle, larvicidal property, instar larvae, Aedes aegypti, larvicidal effect, larvicidal activity performance, X‐ray diffraction, nanoparticle particle size distribution, absorption maxima, silver surface plasmon resonance peak     

Nanowire encapsulation with polymer for electrical isolation and enhanced optical properties

Light management and electrical isolation are essential for the majority of optoelectronic nanowire (NW) devices.Here,we present a cost-effective technique,based on vapor-phase deposition of parylene-C and subsequent annealing,that provides conformal encapsulation,anti-reflective coating,improved optical properties,and electrical insulation for GaAs nanowires.The process presented allows facile encapsulation and insulation that is suitable for any nanowire structure.In particular,the parylene-C encapsulation functions as an efficient antireflection coating for the nanowires,with reflectivity down to ＜1％ in the visible spectrum.Furthermore,the parylene-C coating increases photoluminescence intensity,suggesting improved light guiding to the NWs.Finally,based on this process,a NW LED was fabricated,which showed good diode performance and a clear electroluminescence signal.We believe the process can expand the fabrication possibilities and improve the performance of optoelectronic nanowire devices.