State synchronization of linear and nonlinear agents in time‐varying networks

This paper studies state synchronization of homogeneous time‐varying networks with diffusive full‐state coupling or partial‐state coupling. In the case of full‐state coupling, linear agents as well as a class of nonlinear time‐varying agents are considered. In the case of partial‐state coupling, we only consider linear agents, but, in contrast with the literature, we do not require the agents in the network to be minimum phase or at most weakly unstable. In both cases, the network is time‐varying in the sense that the network graph switches within an infinite set of graphs with arbitrarily small dwell time. A purely decentralized linear static protocol is designed for agents in the network with full‐state coupling. For partial‐state coupling, a linear dynamic protocol is designed for agents in the network while using additional communication among controller variables using the same network. In both cases, the design is based on a high‐gain methodology. Copyright © 2017 John Wiley & Sons, Ltd.     

Improved hydrological projections and reservoir management in the Upper Indus Basin under the changing climate

The availability of water resources plays an important role for the economy of a country. The nexus of energy‐food‐water are interlinked and of particular importance in the uncertain environment of developing countries. In Pakistan, agriculture contributes 25% to the gross domestic product. The Indus River contributes 44% of the available water to irrigation of crops and the ecosystem, and currently produces 5,112 MW electricity, with the potential to produce 38,602 MW electricity. This makes it important to investigate the status of water availability in the Upper Indus Basin under existing emission scenarios. In this study, the future availability of water is projected for the Indus River under the A2, B2, RCP4.5 and RCP8.5 emission scenarios. A meta‐analysis has been conducted to present a combined picture by combining the results from the emission scenarios. Our meta‐analysis shows higher confidence in RCPs projections. The results show that suffcient water will be available in the Indus River that will meet the demands of water in future but there will be scarcity of water in some months under each scenario. However, by proper management and optimum utilisation of the available water, this scarcity can be resolved.     

Indoor mould growth prediction using coupled computational fluid dynamics and mould growth model

This study investigates, using in-situ and numerical simulation experiments, airflow and hygrothermal distribution in a mechanically ventilated academic research facility with known cases of microbial proliferations. Microclimate parameters were obtained from in-situ experiments and used as boundary conditions and validation of the numerical experiments with a commercial computational fluid dynamics (CFD) analysis tool using the standard k–ε model. Good agreements were obtained with less than 10% deviations between the measured and simulated results. Subsequent upon successful validation, the model was used to investigate hygrothermal and airflow profile within the shelves holding stored components in the facility. The predicted in-shelf hygrothermal profile was superimposed on mould growth limiting curve earlier documented in the literature. Results revealed the growth of xerophilic species in most parts of the shelves. The mould growth prediction was found in correlation with the microbial investigation in the case-studied room reported by the authors elsewhere. Satisfactory prediction of mould growth in the room successfully proved that the CFD simulation can be used to investigate the conditions that lead to microbial growth in the indoor environment.     

Cyclic behavior of concentrically braced frames with built-up braces composed of channel sections

Concentrically braced frames are earthquake resistant systems commonly used in buildings. Seismic behavior of this type of structures is affected by their configurations, brace properties, and brace to gusset plate connections. In this paper, the results of three experiments conducted to investigate the cyclic behavior of concentrically braced frames with braces built-up of double channels are reported. Significant damage was observed in beam to column connections. Large out of plane deformation of braces caused some cracks in the connector welds; however they did not result in fracture. Although large drift was applied to the frames, no brace fracture was observed. Furthermore, experiments showed that the majority of compressive strength in post-buckling state and a noticeable portion of tensile strength originated from frame action. By choosing connector spacing as the main parameter and using finite element models, a parametric study was performed to investigate the effect of this parameter on this type of frames with two different details of brace to gusset plate connections. It is observed that reducing the connector spacing increases the inelastic strain demand in braces and decreases it in gusset plates. However, gusset plates, which accommodate 2t linear clearance, are less dependent on connector spacing, compared to those accommodating 6t elliptical clearance. It seems that the limitations of slenderness ratio of individual section, stipulated in current seismic provisions, need further study.     

Sustainability of Groundwater Resources in the North-Eastern Region of Bangladesh

Water is essential for economic, social, and environmental development. Global water resources are vulnerable due to increasing demand related to population growth, pollution potential, and climate change. Competition for water between different sectors is increasing. To meet the increasing demand, the use of groundwater is increasing worldwide. In this paper, the water-table dynamics of the north-eastern region of Bangladesh were studied using the MEKESENS software. This study reveals that the depth to water-table (WT) of almost all the wells is declining slowly. In many cases, the depth will approximately double by the year 2040, and almost all will double by 2060, if the present trend continues. If the decline of the water-table is allowed to continue in the long run, the result could be a serious threat to the ecology and to the sustainability of food production, which is vital for the nation’s food security. Therefore, necessary measures should be taken to sustain water resources and thereby agricultural production. Demand-side management of water and the development of alternative surface water sources seem to be viable strategies for the area. These strategies could be employed to reduce pressure on groundwater and thus maintain the sustainability of the resource.     

万家寨引黄南干7~#洞碎屑岩区段水文地质问题

本文从万家寨引黄工程南干 7#隧洞碎屑岩区段的工程地质条件、水文地质特性、地下水类型、各含水层的富水性及其赋存、径流、补给、排泄等条件入手 ,分析了该洞段开挖过程中存在的主要水文地质问题 ,以指导隧洞施工和设计 ,减少工程风险     

Variation of the specific surface area and porosity of zinc oxide prepared in various atmospheres

Specific surface area and pore structure studies were carried out on zinc oxide samples prepared from zinc oxalate dihydrate by heating at 330 and 370°C and in various atmospheres of water vapour, oxygen and hydrogen. The variation of S_BET with water vapour pressure for the samples heated at 330°C was found to show a behaviour which can be compared with the Smith-Topley effect. For the samples prepared at 370°C, rapid sintering occurred, and the Smith-Topley effect was not followed in this case. Zinc oxide prepared in an oxygen atmosphere gave higher surface area values than that prepared in a hydrogen atmosphere, which is thought to be due to the oxidation of the carbon impurities on the surface. Analysis of nitrogen adsorption isotherms by the t-method revealed the existence of micropores in the sample prepared at 330°C in vacuo. The rest of the samples have wide pores.     

Synthesis and Processing Characteristics of Ba0.65Sr0.35TiO3 Powders from Catecholate Precursors

Powders of composition Ba_0.65Sr_0.35TiO₃ were prepared from catecholate precursor phases, BaTi(C₆H₄O₂)₃ and SrTi (C₆H₄O₂)₃. The physical and chemical properties of the base powders, and those doped with 0.2 wt% manganese, are reported in detail. The dimensions of the primary particles in the starting powders were of the order of 20–50 nm, but the occurrence of abnormal grain growth during sintering promoted grain sizes in the ceramic of up to ∼100 μm. In some microstructures, coarse grains coexisted with a ∼1-μm fraction to produce a characteristic bimodal grain size distribution. By contrast, under comparable sintering conditions, namely 1350° or 1400°C for 1 h, grain growth in Mn-doped samples was suppressed, leading to uniform microstructures with a grain size of only a few micrometers. The pellet densities were nevertheless similar, 97% of theoretical in both doped and undoped samples. No significant difference was observed in the dielectric permittivity of the two compositions: the peak relative permittivity occurred at ∼20°C, with a maximum value of ∼22 000.     

The effect of copolymer composition on the surface properties of perfluoroalkylethyl acrylates

The surface properties of two perfluoroalkylethyl acrylic copolymers—aqueous, Zonyl^®329 and solvent‐based, Zonyl^®225—were studied. Zonyl^®329 is a water‐based dispersion and Zonyl^®225 a solvent‐based copolymer solution; both polymers have the same perfluoroalkyethyl side chains [F(CF₂)_nCH₂CH₂? ] but have different comonomer compositions. Thin films, prepared by dip coating onto mica and quartz, with and without annealing, were characterized by contact angle and by X‐ray photoelectron spectroscopy (XPS). The contact angle measurements showed little variation with polymer and with substrate, consistent with the supposition that the perfluoroalkylethyl chains aggregate on the surface and thus dominate surface properties, irrespective of the composition of the rest of the polymer. XPS revealed only small variations in surface chemistry for studied films. Annealed films showed improved segregation for solvent‐based Zonyl^®225, which has both hydrocarbon alkyl and perfluoroalkylethyl side chains; the presence of hydrocarbon alkyl chains enables the perfluoroalkylethyl chains to reorganize after annealing. Depending on the external conditions, this thermal treatment can enable more perfluoroalkylethyl chains to reach the film surface (solid/air interface), leading to a reduction in the dispersive‐dominant surface and enhancement in perfluoroalkylethyl segregation. This suggested that perfluoroalkylethyl side chains dominate the surface properties, which are thus not dependent on substrate, backbone composition, or formulation. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

The synthesis and photophysicochemical behaviour of novel water-soluble cationic indium(III) phthalocyanine

The syntheses and characterization of 2,3-octakis-(3-pyridyloxyphthalocyaninato) indium(III) and quaternized 2,3-octakis-(3-pyridyloxyphthalocyaninato) indium(III) are described. The ground state electronic absorption spectra, photophysics and photochemistry of both dyes in DMSO as well as that of the quaternized compound in aqueous solution are also presented. A comparison of the photophysical and photochemical parameters of the two dyes revealed that quaternized 2,3-octakis-(3-pyridyloxyphthalocyaninato) indium(III) was a better photosensitizer than its unquaternized counterpart. The quantum yield values of fluorescence (Φ_F), triplet state formation (Φ_T) and singlet oxygen formation (Φ_Δ) for the cationic dye were found to be 0.03, 0.68 and 0.66 respectively in DMSO; these values were higher than those for 2,3-octakis-(3-pyridyloxyphthalocyaninato) indium(III), which exhibited values of 0.02, 0.66 and 0.63, respectively in DMSO. The values for the cationic dye in aq. solution were 0.02, 0.59 and 0.56 respectively, suggesting that the water-soluble quaternized 2,3-octakis-(3-pyridyloxyphthalocyaninato) indium(III) offers potential as a photosensitizer in photodynamic therapy treatment.