Induction time,storage capacity,and rate of methane hydrate formation in the presence of SDS and silver nanoparticles

In this communication, the kinetic parameters of methane hydrate formation (induction time, quantity and rate of gas uptake, storage capacity (SC), and apparent rate constant) in the presence of sodium dodecyl sulfate (SDS), synthetized silver nanoparticles (SNPs), and mixture of SDS?+?SNPs have been studied. Experimental measurements were performed at temperature of 273.65?K and initial pressure of 7?MPa in a 460?cm³ stirred batch reactor. Our results show that adding SDS, SNPs and their mixture increases the quantity of gas uptake, water to hydrate conversion, and SC of methane hydrate formation, noticeably. Using 300?ppm SDS increases the SC and the quantity of methane uptake 615, and 770%, respectively, compared with pure water. Investigating the hydrate growth rate at the start of hydrate formation process shows that, using SNPs, SDS, and their mixture increases the initial apparent rate constant of hydrate rate, considerably. Our results show that the system of methane?+?water?+?SDS 500?ppm?+?SNPs 45?µM represents the maximum value of initial apparent rate constant, compared with other tested systems.     

Green synthesis of 5-arylidene-2,4-thiazolidinedione, 5-benzylidene rhodanine and dihydrothiophene derivatives catalyzed by hydrated ionic liquid tetrabutylammonium hydroxide in aqueous medium

An efficient synthesis of 5-arylidene-2,4-thiazolidinediones and 5-benzylidene rhodanines by the Knoevenagel condensation of 2,4-thiazolidinedione or rhodanine with aromatic aldehydes was studied. It proceeded smoothly in the presence of tetrabutylammonium hydroxide/H ₂O-EtOH to afford the corresponding products in high yields at 50°C. Also, a series of dihydrothiophene derivatives were synthesized via the four-component reaction of aldehyde, malonitrile, 2,4-thiazolidinedione, and piperidine in the presence of Bu₄NOH as a basic ionic liquid in aqueous medium. This new method offers several advantages, such as excellent yields, short reaction times, and simple procedure.     

Rehabilitation of Urban Drainage Systems Using a Resilience-Based Approach

Highly efficient methods are needed to mitigate negative impacts of urban storms such as flooded roads and damage to properties and infrastructures. A rehabilitation approach based on resiliency is proposed in this paper for urban drainage systems using structural improvement of bottlenecks. The resilience-based approach enhances system capability to act very flexible against exceptional loads such as bridge/culvert blockage during the floods. The approach integrates a multi-objective evolutionary algorithm (MOEA) and EPA-SWMM simulation model to find cost-effective rehabilitation measures under structural failure of critical elements in the network. It is applied to the western part of Tehran Stormwater Drainage System (TSDS) to attain optimal measures by minimizing the costs and flood volumes. The approach outperforms the conventional methods (particularly compared to a previous rehabilitation proposal for the study area) when the system encounters unexpected blockage conditions. Results show that the optimal design obtained by the proposed approach can decrease network flooding from 3.5 × 10⁶ m³ to near zero with at most 23% lower investment costs relative to the traditional design.     

Modeling dynamic viscosity of n-alkanes using LSSVM technique

One of the important thermophysical properties is viscosity which expresses the resistance of fluid to flow. The least squares support vector machine (LSSVM) algorithm is proposed as a novel method for prediction of dynamic viscosity of different normal alkanes in a wide range of pressure and temperature. As this study is purely computational, 228 experimental data points were gathered from literature for training and validation of the model. The outcomes of the LSSVM algorithm were compared with the actual data with acceptable average absolute relative deviation and the coefficient of determination (R²) of 1.014 and 0.9968, respectively. The comparisons showed that the predicting model has the potential of prediction of n-alkane dynamic viscosity in terms of pressure, temperature, and carbon number of n-alkane, so this strategy can be used as a simple tool for predicting the behavior of reservoir fluids.     

Sensitivity analysis of surface topography using the submerged non uniform piezoelectric micro cantilever in liquid by considering interatomic force interaction

Journal of Mechanical Science and Technology - The aim of this study is modeling and investigating the micro-cantilever (MC) vibration behavior of atomic force microscopy (AFM) more accurately by...     

A new manufacturable filter design approach for spectral reflectance estimation

Selection of the best possible filter set among a set of available filters is the obvious method of increasing dimension of camera signals for spectral reflectance reconstruction. There are also methods that are focusing on the filter design regardless of noticing to the constructability of the designed filters. This study shows that direct optimization of physical variables of filter manufacturing technique is more reliable than indirect approach of designing and then physical manufacturing of the designed filters. Direct optimization of the transmission‐controlling primaries in filter manufacturing process would guarantee having the designed filters in reality. Combination of some solvent dyes was used as the spectral transmission matching system for filter manufacturing. As a conventional technique, filters were designed and best possible dye concentrations that match the desired filters were calculated. As an alternative approach, filters were also designed using direct optimization of dyes concentrations. The results showed that direct optimization of dye concentrations exhibits better performance in comparison with the conventional technique. © 2016 Wiley Periodicals, Inc. Col Res Appl, 42, 316–326, 2017     

Fabrication and characterization of silk/forsterite composites for tissue engineering applications

In this research, novel composite scaffolds consisting of silk fibroin and forsterite powder were prepared by a freeze-drying method. In addition, the effects of forsterite powder contents on the structure of the scaffolds were investigated to provide an appropriate composite for bone tissue engineering applications. The morphology studies using scanning electron microscopy (SEM) and transmission electron microscopy (TEM) techniques showed that the forsterite ceramic was well distributed throughout the structures of SF/forsterite scaffolds. Furthermore, the forsterite powder (up to 40 wt%) was homogenously distributed within the silk fibroin as a matrix.     

Application of artificial neural network for vapor liquid equilibrium calculation of ternary system including ionic liquid: Water, ethanol and 1-butyl-3-methylimidazolium acetate

A feed forward three-layer artificial neural network (ANN) model was developed for VLE prediction of ternary systems including ionic liquid (IL) (water+ethanol+1-butyl-3- methyl-imidazolium acetate), in a relatively wide range of IL mass fractions up to 0.8, with the mole fractions of ethanol on IL-free basis fixed separately at 0.1, 0.2, 0.4, 0.6, 0.8, and 0.98. The output results of the ANN were the mole fraction of ethanol in vapor phase and the equilibrium temperature. The validity of the model was evaluated through a test data set, which were not employed in the training case of the network. The performance of the ANN model for estimating the mole fraction and temperature in the ternary system including IL was compared with the non-random-two-liquid (NRTL) and electrolyte non-random-two-liquid (eNRTL) models. The results of this comparison show that the ANN model has a superior performance in predicting the VLE of ternary systems including ionic liquid.     

Control of Hybrid Active Power Filter Based on Switching Function Coefficients

A pulse width modulation (PWM)-based control method for a three-level, four-wire neutral point clamped (NPC) inverter employed in a hybrid active power filter (HAPF) is proposed in this paper. The control method is based on switching function coefficients (SFCs) for harmonic compensation. An interior loop is also proposed for control and balancing of the DC-link voltages. In the proposed control system, one carrier signal is employed in the PWM unit in order to simplify its hardware as compared with traditional PWMs. Based on Fourier decomposition technique, mathematical analysis of the proposed control method is also presented. To decrease the NPC inverter rated power, passive power filters (PPFs) are designed to eliminate fifth and seventh order harmonic currents and to compensate source reactive currents. The proposed control system is implemented by a digital signal processing (DSP) in a laboratory prototype. The experimental results confirmed the validity of the proposed control method in compensation of harmonic currents under non-linear conditions