全文获取类型
收费全文 | 159篇 |
免费 | 4篇 |
专业分类
电工技术 | 2篇 |
化学工业 | 48篇 |
金属工艺 | 7篇 |
机械仪表 | 6篇 |
建筑科学 | 5篇 |
能源动力 | 19篇 |
轻工业 | 9篇 |
水利工程 | 1篇 |
无线电 | 7篇 |
一般工业技术 | 29篇 |
冶金工业 | 10篇 |
原子能技术 | 5篇 |
自动化技术 | 15篇 |
出版年
2023年 | 3篇 |
2022年 | 3篇 |
2021年 | 8篇 |
2020年 | 7篇 |
2019年 | 3篇 |
2018年 | 6篇 |
2017年 | 6篇 |
2016年 | 7篇 |
2014年 | 2篇 |
2013年 | 9篇 |
2012年 | 17篇 |
2011年 | 12篇 |
2010年 | 9篇 |
2009年 | 8篇 |
2008年 | 12篇 |
2007年 | 11篇 |
2006年 | 5篇 |
2005年 | 2篇 |
2004年 | 5篇 |
2003年 | 2篇 |
2002年 | 2篇 |
2001年 | 4篇 |
1999年 | 1篇 |
1998年 | 5篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1992年 | 1篇 |
1988年 | 1篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1982年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有163条查询结果,搜索用时 0 毫秒
31.
H. Ben youcef S. Alkan Gürsel A. Buisson L. Gubler A. Wokaun G. G. Scherer 《Fuel Cells》2010,10(3):401-410
The mechanical stability is, in addition to thermal and chemical stability, a primary requirement of polymer electrolyte membranes in fuel cells. In this study, the impact of grafting parameters and preparation steps on stress–strain properties of ETFE‐based proton conducting membranes, prepared by radiation‐induced grafting and subsequent sulphonation, was studied. No significant change in the mechanical properties of the ETFE base film was observed below an irradiation dose of 50 kGy. It was shown that the elongation at break decreases with increasing both the crosslinker concentration and graft level (GL). However, the tensile strength was positively affected by the crosslinker concentration. Yield strength and modulus of elasticity are almost unaffected by the introduction of crosslinker. Interestingly, yield strength and modulus of elasticity increase gradually with GL without noticeable change of the inherent crystallinity of grafted films. The most brittle membranes are obtained via the combination of high GL and crosslinker concentration. The optimised ETFE‐based membrane (GL of ∼25%, 5% DVB v/v), shows mechanical properties superior to those of Nafion® 112 membrane. The obtained results were correlated qualitatively to the other ex situ properties, including crystallinity, thermal properties and water uptake of the grafted membranes. 相似文献
32.
Richard Furter 《纺织导报》2010,(3)
<正>1介绍质量的许多定义之一是产品的某些属性满足客户或是用户的需要,对纺织工艺来说,质量常常通过纤维、纱线或是织物的不同属性来定义,这些属性必须得到系统的控制。 相似文献
33.
Adsorption of cationic polyacrylamide onto sepiolite 总被引:3,自引:0,他引:3
The adsorption of PAM onto sepiolite from aqueous solutions has been investigated systematically as a function of some parameters such as calcination temperature of sepiolite, pH, ionic strength and temperature. The adsorption of cationic polyacrylamide (PAM) increases with pH from 5.50 to 11.00, temperature from 25 to 55 degrees C and ionic strength from 0 to 0.1molL(-1). The sepiolite sample calcined at 200 degrees C has a higher adsorption capacity than the other calcined samples. Adsorption isotherms of PAM onto sepiolite have been determined and correlated with common isotherm equations such as Langmuir and Freundlich isotherm models. The Langmuir isotherm model appeared to fit the isotherm data better than the Freundlich isotherm model. The physical properties of this adsorbent are consistent with the parameters obtained from the isotherm equations. The zeta potentials of sepiolite suspensions have been measured in aqueous solutions of NaCl and different PAM concentrations and pH. From the experimental results: (i) pH strongly alters the zeta potential of sepiolite, (ii) sepiolite has an isoelectric point at about pH 6.6 in water and about pH 8 in 250mgL(-1) PAM concentration, (iii) PAM changes the interface charge from negative to positive for sepiolite. Effect of temperature on adsorption has been quantified by calculating various thermodynamic parameters such as Gibbs free energy, enthalpy and entropy. The dimensionless separation factor (R(L)) has shown that sepiolite can be used for adsorption of PAM from aqueous solutions. 相似文献
34.
Compatibility of acidic (H), Na, and Zn neutralized sulfonated polystyrene ionomer blends with Poly(2,6-dimethyl- 1,4-phenylene
oxide) (PPO) and Poly(2,6-dichloro- 1,4-phenylene oxide) (PDCIPO) was investigated by Dilute Solution Viscometry (DSV) and
Differential Scanning Calorimetry (DSC). The intrinsic viscosities of the blends, are measured in suitable solvents. The degree
of compatibility of the blends is characterized by Δb parameter. According to the results, PPO is completely miscible, except
for Na-neutralized 1.7 mol% sulfonated polystyrene (Na1.7SPS) which is completely immiscible with PPO and PDClPO. PDClPO is
completely miscible with Zn-neutralized sulfonated polystyrene (Zn4.8SPS) and partially miscible with acid sulfonated polystyrene
(4.8SPS).
Received: 12 August 2001/Revised version: 21 January 2002/Accepted: 11 March 2003
Correspondence to Leyla Aras 相似文献
35.
The removal of copper ions from aqueous solutions by kaolinite was investigated by using a batch-type method. Effects of factors such as pH, ionic strength, temperature, acid-activation and calcination on copper adsorption were investigated. The uptake of copper was determined from changes in concentration as measured by atomic absorption spectrometry. The extent of copper adsorption increased with increasing pH and temperature and with decreasing ionic strength, acid-activation and calcination temperature. The Langmuir and Freundlich adsorption models were used to determine the isotherm parameters associated with the adsorption process. The results provide support for the adsorption of copper ions onto kaolinite. Thermodynamic parameters indicated the endothermic nature of copper adsorption on kaolinite. The experimental results were applied a batch design. As a result, the kaolinite may be used for removal of copper ions from aqueous solutions. 相似文献
36.
Removal of copper ions from aqueous solutions by hazelnut shell 总被引:1,自引:0,他引:1
There is a great potential of woody hazelnut shell to use in some applications. Sorption studies are one of these. For this reason in this paper, batch adsorption of Cu(2+) ions onto hazelnut shells was studied. The capacity of the adsorption for the removal of copper ions from aqueous solution was investigated under different conditions such as solution contact time (1-360 min), particle size (0-75, 75-150 and 150-200 microm), temperature of solution (25-60 degrees ) and solution pH (3-7). Moreover, zeta potential of particles at different initial pHs (2-10) was measured. The equilibrium data were processed according to Langmuir and Freundlich's models and higher adsorption capacity values towards Cu(2+) ions were shown. The adsorption kinetics was investigated and the best fit was achieved by a second-order equation. 相似文献
37.
In another paper in this volume, it is demonstrated that the electrochemical interface in MEAs, and thus the polarization performance of the resulting fuel cells, can be improved by optimising the hot‐pressing procedure in the MEA preparation. In particular, the extent of drying of the membrane during MEA preparation was shown to be critical. In the present investigation, the effect of the drying process, and thus water content, on the hydrophilicity, wetting, and surface energies of some fuel cell membranes is examined. Wetting and surface energies are well known to influence the bonding behaviour of materials. Conclusions about how membrane drying and changes in water content influence membrane bonding and the relative importance of these surface effects are drawn. 相似文献
38.
Latent heat energy storage characteristics of building composites of bentonite clay and pumice sand with different organic PCMs 下载免费PDF全文
In the present work, six new kinds of building composite PCMs (BCPCMs), PS/octadecane, BC/octadecane, PS/CA–MA, BC/CA–MA, PS/PEG1000, and BC/PEG1000 composites, were prepared by using vacuum impregnation method. The maximum percent of PCM in the composites was assigned to be 12, 13, 18, 23, 30, and 42 wt%, respectively. The form‐stable BCPCMs were characterized using SEM, FT‐IR, DSC, and TG analysis techniques. The characterization results showed the existence of homogenous dispersion of the PCM into the PBM matrixes. The DSC measurements indicated that the melting temperatures of the form‐stable BCPCMs are in the range of 20–33°C while they have latent heats of melting in the range of about 28–55 J/g. These results make them promising BCPCMs for low temperature‐passive TES applications in buildings. Thermal cycling test indicated that the prepared BCPCMs have good thermal reliability and chemical stability. TG analysis proved that the prepared BCPCMs have good thermal durability. In addition, the thermal conductivity of BCPCMs was enhanced considerably by addition of expanded graphite (EG). The improvement in thermal conductivity of the BCPCMs caused appreciably reduction in their melting times. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
39.
40.
In this study, five silk fabrics were separately dyed with madder (Rubia tinctorium L.) and gallnut (Quercus infectoria Olivier) in different percentages and then tested for antifungal activity against Candida albicans DSMZ 1386. The one having highest antifungal activity was washed 5 times under same conditions and samples were taken after every wash. They retained nearly 99.98 % activity up to five launderings against Candida albicans. In addition, coloring compounds and their peak heights in dyed silk fabrics were detected by high performance liquid chromatography with diode array detection (HPLC-PDA). Color values of the dyed silk fabrics were measured by CIEL*a*b* spectrophotometer. 相似文献