Wetting of oriented and etched ultrahigh molecular weight polyethylene

Highly oriented gel‐spun ultrahigh molecular weight polyethylene (UHMWPE) fibers possess many outstanding properties desirable for composite materials but their adhesion to such matrices as epoxy is poor. This article describes the combined effects of drawing and surface modification on the bulk and surface properties of gel‐cast UHMWPE films emphasizing the effects of etching on both undrawn and drawn films. Drawing the films yields a fibrillar structural hierarchy similar to UHMWPE fibers and a significant increase in orientation, melting point, modulus, and strength. The effects of drawing on bulk properties were more significant than those of etching. The poor adhesion of epoxy to the smooth, fibrillar, and relatively nonpolar drawn film surface improves significantly with oxidization and roughening on etching. The interlaminar shear failure occurred cohesively in the UHMWPE, and thus the interlaminar shear failure strength was greater for the drawn UHMWPE with its greater tensile strength. Nitrogen plasma etching yielded the best results, both removing any low molecular weight surface layer and etching the UHMWPE beneath. Oxygen plasma etching enhanced wetting but was too harsh, causing extensive surface degradation and a significant reduction in mechanical properties. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 72: 405–418, 1999     

An analysis of starburst defects in wrinkled powder coatings

Starbursts are defects in wrinkled powder coatings wherein the typical random orientation of the wrinkles is disrupted. Instead, wrinkles orient radially around a central point creating a star-like pattern. The origin of the starburst defect was investigated by mechanical profilometry and elemental analysis by energy dispersive X-ray spectroscopy (EDS). Topographical measurements demonstrated that the centers of the stars almost always are at a higher elevation compared to their surroundings, suggesting the presence of non-dispersed extender particles or external impurities at the center. EDS analysis of the center of the stars confirmed the presence of external particles or impurities. Radial orientation of the wrinkles around the external particles can be explained by preferential pattern orientation due to directional stress relief.     

Mechanistic and Adsorption Studies of Relevance to Photocatalysts on Titanium Grafted Mesoporous Silicalites

Abstract  

Ti-SBA-15 and Ti-MCM-41 were synthesized and evaluated as possible photocatalysts for the reduction of CO₂, and for the photo-Kolbe decomposition of acetic acid. UV-Raman was used to study the adsorption of carbon dioxide, water, formic acid, and acetic acid over Ti-MCM-41 by monitoring the UV enhanced resonance peak of the totally symmetric stretching band of the grafted Ti species at 1,085 cm⁻¹. Acetic and formic acid dissociate on Ti-SBA-15 and Ti-MCM-41 to form acetate and formate, respectively. The conjugate bases subsequently interact strongly with Ti sites. Water interacts with the Ti sites, while no change in the amplitude of the 1,085 cm⁻¹ band is observed in the presence of CO₂. Photocatalysis experiments indicate that these mesoporous silicalites are active in the photo-Kolbe decomposition of acetic acid. CO₂ is formed by reaction of a hole with the acetate carboxylate groups. The methyl radical co-products react with a surface proton and an electron to form methane. No products resulting from the dimerization of methyl radicals are observed, presumably because of the highly dispersed active sites.     

Principles of psychotherapeutic strategy.

Argues that strategy fills a real need in psychotherapeutic thinking. An attempt is made to define strategic rules for (1) choosing and defining goals, (2) locating strategic points, (3) actively searching for the client's responses, (4) dealing with resistance, (5) exploiting or creating propitious timings, (6) mobilizing allies, (7) concentrating the therapeutic influence, (8) stabilizing partial achievements, (9) dealing with competing demands, (10) retreating after failure, and (11) changing the therapeutic framework when needed. Each principle is illustrated by interventions from different therapeutic orientations. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Improved bit-stuffing bounds on two-dimensional constraints

We derive lower bounds on the capacity of certain two-dimensional (2-D) constraints by considering bounds on the entropy of measures induced by bit-stuffing encoders. A more detailed analysis of a previously proposed bit-stuffing encoder for (d,/spl infin/)-runlength-limited (RLL) constraints on the square lattice yields improved lower bounds on the capacity for all d /spl ges/ 2. This encoding approach is extended to (d,/spl infin/)-RLL constraints on the hexagonal lattice, and a similar analysis yields lower bounds on the capacity for d /spl ges/ 2. For the hexagonal (1,/spl infin/)-RLL constraint, the exact coding ratio of the bit-stuffing encoder is calculated and is shown to be within 0.5% of the (known) capacity. Finally, a lower bound is presented on the coding ratio of a bit-stuffing encoder for the constraint on the square lattice where each bit is equal to at least one of its four closest neighbors, thereby providing a lower bound on the capacity of this constraint.     

The dose-dependent effects of oral premedication with midazolam

OBJECTIVE: The aim of this study was to examine the psychological effects, well-being and side effects after various doses of oral midazolam medication. METHODS: After informed consent has been obtained and following the approval by the institutional ethical committee, 80 adult patients in the ASA physical status I and II were randomly assigned to one of five different premedication groups: 3.75, 7.5, 11.25, 15 mg midazolam, and placebo. The medication was given in a double-blind fashion 60 min before induction of general anaesthesia for various surgical procedures. At 3 definite stages (before premedication, 30 and 60 min after premedication), blood pressure, heart rate, transcutaneous oxygen saturation and respiratory rate were measured. Sedation and well-being were graded according to a 5-point scale, and the subjective anxiety level was assessed according a visual analogue scale (range 0-100 mm). Anterograde and retrograde amnesia were measured by recall of auditive and visual stimuli. Finally, patients were asked whether in case of future surgery they would prefer the same or a different medication. RESULTS: Demographic data were similar in all groups. There was no significant difference in respiratory rate, oxygen saturation, blood pressure or heart rate. Alertness declined only after 60 min in the groups treated with 7.5 mg and more midazolam. During the entire measurement period, anxiolysis was not different from placebo in any of the midazolam groups. In comparison to placebo, all midazolam groups showed a statistically significant and dose dependent anterograde amnesia for visual stimuli. Subjective well-being scores showed no differences between the groups. Only few side effects were seen following doses of 7.5 mg and higher, including ptosis, strabismus, diplopia, speech disorders, disorientation and vertigo. The majority of patients in all groups indicated a wish for the same medication in case of future anaesthesia for surgical interventions. CONCLUSIONS: Midazolam administered orally prior to surgical procedures showed marked interindividual variability. Sedation and amnesia were dose-dependent and were evaluated by the patients as acceptable. Anxiolysis was not significantly different from placebo. A dose of 7.5 mg midazolam showed the best relation between desirable and undesirable effects. Adequate attention given to the patient by the anaesthesiologist prior to surgery seems to be as important and beneficial as oral medication with midazolam.     

Improved parallel approximation of a class of integer programming problems

We present a method to derandomizeRNC algorithms, converting them toNC algorithms. Using it, we show how to approximate a class of NP-hard integer programming problems inNC, to within factors better than the current-bestNC algorithms (of Berger and Rompel and Motwaniet al.); in some cases, the approximation factors are as good as the best-known sequential algorithms, due to Raghavan. This class includes problems such as global wire-routing in VLSI gate arrays and a generalization of telephone network planning in SONET rings. Also for a subfamily of the “packing” integer programs, we provide the firstNC approximation algorithms; this includes problems such as maximum matchings in hypergraphs, and generalizations. The key to the utility of our method is that it involves sums ofsuperpolynomially many terms, which can however be computed inNC; this superpolynomiality is the bottleneck for some earlier approaches, due to Berger and Rompel and Motwaniet al. A preliminary version of this work appeared inProc. International Colloquim on Automata, Languages and Programming, 1996, pages 562–573. Work done in parts at DIMACS (supported in part by NSF-STC91-19999 and by support from the N.J. Commission on Science and Technology), at the Institute for Advanced Study, Princeton (supported in part by Grant 93-6-6 of the Alfred P. Sloan Foundation), and at the National University of Singapore.